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US4252888A Expired / Lapsed US ⏱️ 0.0 years remaining

Solder mask composition

Assignee: 3M Co
•
Filing: 1980-02-26
•
Granted: 1981-02-24
•
Expires: 2000-02-26
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Abstract

Abstract A photopolymerizable composition which is screen-printable and has utility as a solder mask, the composition comprising aryloxyalkyl acrylate monomers or prepolymers, a diacrylate diluent, a monofunctional monomer and a free-radical initiating system.

Inventors

  • 👤 Robert R. Rohloff

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-01 05:26
CPC Classifications
G; G03; G03F; G03F7/00; G03F7/004; G03F7/027; H; H05; H05K; H05K3/00; H05K3/22; H05K3/28; H05K3/285; H05K3/287

Claims Analysis

Total Claims: 8
Claim 1
Independent Claim 165 words
A screen-printable photopolymerizable composition comprising from about 15 to about 85 percent by weight of an aryloxyalkyl acrylate having the general formula: ##STR2## wherein X is a methylene, an alkyl-substituted methylene group, a dialkyl-substituted methylene group, a carbonyl group, a sulfide, a sulfoxide, a sulfone, an amine, an alkyl-substituted amine, an ethylene ether, a propylene ether, a 2-hydroxypropylene ether, wherein each alkyl group may have from 1 to 8 carbon atoms, or any combination thereof; Y is ethyl, propyl, 2-hydroxypropyl, or other lower alkyl or hydroxyalkyl groups having up to 8 carbon atoms; A is an unsaturated acryloxy group having from 3 to 18 carbons, preferably acryloxy or methacryloxy; and n is 0 through 20, m is 0 or 1, and p is 0 or 1; from about 15 to about 85 percent by weight of a diacrylate diluent; an effective amount of a monofunctional monomer selected from the group consisting of styrene and its monofunctional analogs; and a free-radical generating addition polymerizing initiating system.
Claim 2
Dependent Claim 165 words
A screen-printable photopolymerizable composition comprising from about 15 to about 85 percent by weight of an aryloxyalkyl acrylate having the general formula: ##STR2## wherein X is a methylene, an alkyl-substituted methylene group, a dialkyl-substituted methylene group, a carbonyl group, a sulfide, a sulfoxide, a sulfone, an amine, an alkyl-substituted amine, an ethylene ether, a propylene ether, a 2-hydroxypropylene ether, wherein each alkyl group may have from 1 to 8 carbon atoms, or any combination thereof; Y is ethyl, propyl, 2-hydroxypropyl, or other lower alkyl or hydroxyalkyl groups having up to 8 carbon atoms; A is an unsaturated acryloxy group having from 3 to 18 carbons, preferably acryloxy or methacryloxy; and n is 0 through 20, m is 0 or 1, and p is 0 or 1; from about 15 to about 85 percent by weight of a diacrylate diluent; an effective amount of a monofunctional monomer selected from the group consisting of styrene and its monofunctional analogs; and a free-radical generating addition polymerizing initiating system.
Claim 3
Dependent Claim 23 words
The photopolymerizable composition of claim 1 wherein said aryloxyalkyl acrylate constitutes from about 15 to about 40 percent by weight of said composition.
Claim 4
Dependent Claim 23 words
The photopolymerizable composition of claim 1 wherein said diacrylate diluent constitutes from about 40 to about 70 percent by weight of said composition.
Claim 5
Dependent Claim 41 words
The photopolymerizable composition of claim 1 wherein the weight ratio of said diacrylate diluent to said aryloxyalkyl acrylate is about 1 to 3, and wherein said monofunctional monomer constitutes from about 1 to about 50 percent by weight of said composition.
Claim 6
Dependent Claim 44 words
The photopolymerizable composition of claim 1 wherein the ratio of said diacrylate diluent to said aryloxyalkyl acrylate is from about 1 to 1 to 3 to 1, and said monofunctional monomer constitutes from about 1 to about 30 percent by weight of said composition.
Claim 7
Dependent Claim 27 words
The photopolymerizable composition of claim 1 wherein said diacrylate diluent is selected from the group consisting of 1,3-butylene glycol diacrylate, triethylene glycol diacrylate and tetraethylene glycol diacrylate.
Claim 8
Dependent Claim 13 words
The photopolymerizable composition of claim 1 wherein said monofunctional monomer is vinyl toluene.

References Cited (Backward Citations)

US3661576A Cited
US4003877A Cited
US4064287A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1984-02-24 1984-08-25 1985-02-24 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1988-02-24 1988-08-25 1989-02-24 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1992-02-24 1992-08-25 1993-02-24 $7700.00 Window Closed / Lapsed

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