Patent US4225631A successfully refreshed from Google Patents.
US4225631A
Expired / Lapsed
US
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Abrasion resistant coatings for unsaturated polymeric substrates
Assignee: BMC Industries Inc
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Filing: 1976-04-19
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Granted: 1980-09-30
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Expires: 1996-04-19
Abstract
Abstract A process is disclosed for applying an adherent, optically clear, abrasion resistant coating to polymeric substrates formed from unsaturated monomers. Typical substrates are lenses formed from either acrylic or allylic polymers, such as CR-39 lenses. This process includes (a) forming a solution of a partially hydrolyzed vinyltri (lower alkoxy) silane, such as vinyltriethoxysilane, in a water-miscible, volatile, organic solvent, the silane being present from 25-75% by weight; (b) applying this solution to a clean surface of the substrate; (c) dehydrating the coated substrate under low humidity conditions at an elevated temperature below the temperature at which the substrate degrades; and, (d) then submitting the dehydrated coated substrate to irradiation with ultraviolet light or other high energy radiation until an adherent, abrasion resistant coating is formed.
Inventors
- 👤 Michael J. Berger
- 👤 Hollis E. French
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-24 07:54
CPC Classifications
B; B29; B29D; B29D11/00; B29D11/00865; C; C08; C08J; C08J7/00; C08J7/12; C08J7/16; C08J7/18
Claims Analysis
Total Claims: 20
Claim 1
Independent Claim
95 words
A process for forming an abrasion-resistant, adherent coating on a polymeric substrate formed from monomers which contain unsaturated groups, comprising: a. forming a solution of hydrolyzed vinyltri(lower alkoxy)silane in a water-miscible, volatile, organic solvent wherein said vinyltri(lower alkoxy)silane is present from about 25 to about 75 weight percent; b. applying a coating of said solution to a clean surface of the polymeric substrate; c. dehydrating the coated substrate at an elevated temperature; and, d. subsequently subjecting the dehydrated coated substrate to high energy radiation until an adherent, coating having significantly improved abrasion-resistance is formed thereon.
Claim 2
Dependent Claim
95 words
A process for forming an abrasion-resistant, adherent coating on a polymeric substrate formed from monomers which contain unsaturated groups, comprising: a. forming a solution of hydrolyzed vinyltri(lower alkoxy)silane in a water-miscible, volatile, organic solvent wherein said vinyltri(lower alkoxy)silane is present from about 25 to about 75 weight percent; b. applying a coating of said solution to a clean surface of the polymeric substrate; c. dehydrating the coated substrate at an elevated temperature; and, d. subsequently subjecting the dehydrated coated substrate to high energy radiation until an adherent, coating having significantly improved abrasion-resistance is formed thereon.
Claim 3
Dependent Claim
23 words
A process of claim 1 wherein said substrate is formed from a polymeric material containing a major amount of diethylene glycol bis(allyl carbonate).
Claim 4
Dependent Claim
12 words
A process of claim 2 wherein said substrate is an ophthalmic lens.
Claim 5
Dependent Claim
11 words
A process of claim 3 wherein said vinyltri(lower alkoxy)silane comprises vinyltriethoxysilane.
Claim 6
Dependent Claim
32 words
A process of claim 4 wherein said coated lens is dehydrated in an atmosphere having a relative humidity below about 10% and a temperature between about 80° C. and about 100° C.
Claim 7
Dependent Claim
13 words
A process of claim 5 wherein said water-miscible, volatile, organic solvent is ethanol.
Claim 8
Dependent Claim
19 words
A process of claim 6 wherein said vinyltriethoxysilane is present in said solution in an amount of about 50%.
Claim 9
Dependent Claim
25 words
A process of claim 1 wherein said solution of hydrolyzed vinyltri(lower alkoxy)silane contains from about 1 to about 20 weight percent of an abrasion-resistance enhancer.
Claim 10
Dependent Claim
21 words
A process of claim 8 wherein said abrasion-resistance enhancer comprises an amino(C 1 -C 8 alkyl) tri(C 1 -C 3 alkoxy)silane.
Claim 11
Dependent Claim
11 words
A process of claim 9 wherein said abrasion-resistance enhancer comprises gamma-aminopropyltriethoxysilane.
Claim 12
Dependent Claim
22 words
A process of claim 8 also containing at least about 0.05 parts of a stabilizing weak acid per part of abrasion-resistance enhancer.
Claim 13
Dependent Claim
13 words
A process of claim 11 wherein said stabilizing weak acid is acetic acid.
Claim 14
Dependent Claim
11 words
A process of claim 12 wherein said abrasion-resistance enhancer is gamma-aminoproplytriethoxysilane.
Claim 15
Dependent Claim
11 words
A process of claim 13 wherein said vinyltri(lower alkoxy)silane comprises vinyltriethoxysilane.
Claim 16
Dependent Claim
24 words
A process of claim 14 wherein said polymeric substrate is formed from a polymer material containing a major amount of diethylene glycol bis(allyl carbonate).
Claim 17
Dependent Claim
13 words
A process of claim 15 wherein said polymeric substrate is an ophthalmic lens.
Claim 18
Dependent Claim
166 words
A process for producing an abrasion-resistant, adherent, optically clear coating on an ophthalmic lens formed from diethylene glycol bis(allyl carbonate), comprising: a. forming a coating solution containing from about 25 to about 75 percent by weight of a hydrolyzed vinyltri(lower alkoxy)silane in a water-miscible, volatile, organic solvent, said coating solution also containing from about 1 to about 20 percent by weight of an amino (C 1 -C 8 alkyl)tri(C 1 -C 3 )alkoxysilane and from about 0.1 to about 0.5 parts of a stabilizing weak acid having a pKa of between about 5×10 -3 and about 5×10 -5 per part of amino(C 1 -C 8 alkyl) tri(C 1 -C 3 )alkoxysilane, by weight; b. applying a coating of said solution to a clean surface of said lens; c. dehydrating the coated lens at a temperature of between about 70° C. and 100° C; and, d. subsequently irradiating the dehydrated, coated lens with ultraviolet light until an adherent, optically clear coating having significantly improved abrasion-resistance is formed.
Claim 19
Dependent Claim
166 words
A process for producing an abrasion-resistant, adherent, optically clear coating on an ophthalmic lens formed from diethylene glycol bis(allyl carbonate), comprising: a. forming a coating solution containing from about 25 to about 75 percent by weight of a hydrolyzed vinyltri(lower alkoxy)silane in a water-miscible, volatile, organic solvent, said coating solution also containing from about 1 to about 20 percent by weight of an amino (C 1 -C 8 alkyl)tri(C 1 -C 3 )alkoxysilane and from about 0.1 to about 0.5 parts of a stabilizing weak acid having a pKa of between about 5×10 -3 and about 5×10 -5 per part of amino(C 1 -C 8 alkyl) tri(C 1 -C 3 )alkoxysilane, by weight; b. applying a coating of said solution to a clean surface of said lens; c. dehydrating the coated lens at a temperature of between about 70° C. and 100° C; and, d. subsequently irradiating the dehydrated, coated lens with ultraviolet light until an adherent, optically clear coating having significantly improved abrasion-resistance is formed.
Claim 20
Dependent Claim
17 words
A process of claim 17 wherein said vinyltri-(lower alkoxy)silane is vinyltriethoxysilane and wherein said solvent is ethanol.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1983-09-30 | 1984-03-31 | 1984-09-30 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1987-09-30 | 1988-03-31 | 1988-09-30 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1991-09-30 | 1992-03-31 | 1992-09-30 | $7700.00 | Window Closed / Lapsed |