Phthalocyanine pigment compositions

Claim 2

A phthalocyanine pigment composition comprising (A) 100 parts by weight of phthalocyanine pigment, (B) a phthalocyanine derivative selected from the group consisting of compounds (I) and (II) represented by the following general formulae, respectively, ##STR41## wherein P c is the n-valent residue of a metal-free or metal phthalocyanine, X is --(CH 2 ) m --, --CH 2 NH(CH 2 ) l --, --CH 2 NHCO(CH 2 ) l -- or --SO 2 NH(CH 2 ) l --, R 1 is a hydrogen atom, alkyl group or hydroxyalkyl group, R 2 is an alkyl group, cycloalkyl group, hydroxyalkyl group, aminoalkyl group or aralkyl group, R 1 and R 2 may be combined together in this case, ##STR42## may be substituted by a saturated five-, six- or seven-membered heterocyclic ring having oxygen, nitrogen and/or sulfur atoms as other members of the ring, R 3 is a substituted or unsubstituted ortho-phenylene group, and l, m and n are an integer of 1-4, 1-2 and 1-8 respectively, and (C) a polyvalent metal salt of an anionic surface-active agent wherein the polyvalent metal is barium, calcium, zinc, strontium or manganese, the compounds (B) and (C) being comprised in a molar ratio of 1:0.1-5 and totalling 0.5-30 parts by weight, said composition being formed by mixing said phthalocyanine derivative with said polyvalent metal salt of an anionic surface-active agent and thereafter mixing the resulting blend with said phthalocyanine pigment.

Claim 3

A phthalocyanine pigment composition according to claim 1, wherein the P c in the formulae (I) and (II) contains at least one of a chlorine atom, bromine atom and sulfonic group.

Claim 4

A phthalocyanine pigment composition according to claim 1, wherein the phthalocyanine derivative (B) and the polyvalent metal salt (C) of an anionic surface-active agent are present in a molar ratio of 1:0.1-0.8.

Claim 5

A phthalocyanine pigment composition according to claim 1, 2 or 3, wherein the anionic surface-active agent is an ester of a higher alcohol and sulfuric acid.

Claim 6

A phthalocyanine pigment composition according to claim 1, 2 or 3, wherein the anionic surface-active agent is a dialkylsulfosuccinate.

Claim 7

A phthalocyanine pigment composition according to claim 1, 2 or 3, wherein the anionic surface-active agent is an alkylbenzenesulfonate.

Claim 8

A phthalocyanine pigment composition according to claim 1, 2 or 3, wherein the anionic surface-active agent is an alkylnaphthalenesulfonate.

Claim 9

A phthalocyanine pigment composition comprising (A) 100 parts by weight of phthalocyanine pigment, (B) a phthalocyanine derivative selected from the group consisting of compounds (I) and (II) represented by the following general formulae, respectively, ##STR43## wherein P c is the n-valent residue of a metal-free or metal phthalocyanine, X is --(CH 2 ) m --, --CH 2 NH(CH 2 ) l --, --CH 2 NHCO(CH 2 ) l -- or --SO 2 NH(CH 2 ) l --, R 1 is a hydrogen atom, alkyl group or hydroxyalkyl group, R 2 is an alkyl group, cycloalkyl group, hydroxyalkyl group, aminoalkyl group or aralkyl group, R 1 and R 2 may be combined together in this case, ##STR44## may be substituted by a saturated five-, six- or seven-membered heterocyclic ring having oxygen, nitrogen and/or sulfur atoms as other members of the ring, R 3 is a substituted or unsubstituted ortho-phenylene group, and l, m and n are an integer of 1-4, 1-2, and 1-8 respectively, and (C) a polyvalent metal salt of an anionic surface-active agent wherein the polyvalent metal is barium, calcium, zinc, strontium or manganese, the compounds (B) and (C) being comprised in a molar ratio of 1:0.1-5 and totalling 0.5-30 parts by weight, said composition being formed by mixing said phthalocyanine derivative with said anionic surface-active agent in an aqueous slurry, adding an inorganic polyvalent metal salt thereto with agitation, and thereafter mixing the resulting blend with said phthalocyanine pigment.

Claim 10

A phthalocyanine pigment composition comprising (A) 100 parts by weight of phthalocyanine pigment, (B) a phthalocyanine derivative selected from the group consisting of compounds (I) and (II) represented by the following general formulae, respectively, ##STR43## wherein P c is the n-valent residue of a metal-free or metal phthalocyanine, X is --(CH 2 ) m --, --CH 2 NH(CH 2 ) l --, --CH 2 NHCO(CH 2 ) l -- or --SO 2 NH(CH 2 ) l --, R 1 is a hydrogen atom, alkyl group or hydroxyalkyl group, R 2 is an alkyl group, cycloalkyl group, hydroxyalkyl group, aminoalkyl group or aralkyl group, R 1 and R 2 may be combined together in this case, ##STR44## may be substituted by a saturated five-, six- or seven-membered heterocyclic ring having oxygen, nitrogen and/or sulfur atoms as other members of the ring, R 3 is a substituted or unsubstituted ortho-phenylene group, and l, m and n are an integer of 1-4, 1-2, and 1-8 respectively, and (C) a polyvalent metal salt of an anionic surface-active agent wherein the polyvalent metal is barium, calcium, zinc, strontium or manganese, the compounds (B) and (C) being comprised in a molar ratio of 1:0.1-5 and totalling 0.5-30 parts by weight, said composition being formed by mixing said phthalocyanine derivative with said anionic surface-active agent in an aqueous slurry, adding an inorganic polyvalent metal salt thereto with agitation, and thereafter mixing the resulting blend with said phthalocyanine pigment.