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US4097350A
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Actinic radiation curable compositions
Assignee: Ingredion Inc
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Filing: 1975-06-19
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Granted: 1978-06-27
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Expires: 1995-06-19
Abstract
Abstract Actinic radiation curable compositions comprise chemically bonded portions of at least one free radical polymerizable hydroxyalkyl ester of an alpha, beta unsaturated carboxylic acid, at least one non-halogenated cyclic anhydride, at least one epoxide and a halogenated free radical initiator which is activatable by actinic radiation. Upon exposure to actinic radiation, these compositions are cured with very little or no inhibition by atmospheric oxygen.
Inventors
- 👤 Stephen D. Pastor
- 👤 Martin M. Skoultchi
- 👤 Henry R. Hernandez
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-24 20:02
CPC Classifications
C; C08; C08F; C08F267/00; C08F267/04; C08F2/00; C08F2/46; C08F2/48; C08F265/00; C08F265/04; C09; C09D; C09D4/00; C09D4/06; Y; Y10; Y10T; Y10T428/00; Y10T428/31504; Y10T428/31551; Y10T428/31645; Y10T428/31649; Y10T428/31678; Y10T428/31692; Y10T428/31699; Y10T428/31786; Y10T428/31797; Y10T428/31855; Y10T428/31935
Claims Analysis
Total Claims: 10
Claim 1
Independent Claim
163 words
An actinic radiation curable prepolymeric composition of matter characterized by the presence of terminal unsaturation consisting essentially of the reaction product of: (a) from about 1.0 to about 48.0 mole percent of a hydroxyalkyl ester of an alpha, beta unsaturated carboxylic acid, wherein the alkyl group of the ester moiety contains from 2 to 20 carbon atoms, and the acid moiety contains from 3 to 4 carbon atoms; (b) from about 1.0 to about 48.0 mole percent of at least one polymerizable free-radical initiator activatable by actinic radiation and selected from the group consisting of tetrachlorophthalic anhydride, tetrabromophthalic anhydride and 1,4,5,6,7,7-hexachloro-5-norbornene-2,3-dicarboxylic anhydride and mixtures thereof; (c) from about 1.0 to about 48.0 mole percent of at least one nonhalogenated cyclic anhydride containing from 4 to 10 carbon atoms; and (d) from about 1.0 to about 48.0 mole percent of at least one epoxide containing 2 to 8 carbon atoms and selected from the group consisting of epoxyalkyl acrylates and methacrylates and alkylene oxides.
Claim 2
Dependent Claim
163 words
An actinic radiation curable prepolymeric composition of matter characterized by the presence of terminal unsaturation consisting essentially of the reaction product of: (a) from about 1.0 to about 48.0 mole percent of a hydroxyalkyl ester of an alpha, beta unsaturated carboxylic acid, wherein the alkyl group of the ester moiety contains from 2 to 20 carbon atoms, and the acid moiety contains from 3 to 4 carbon atoms; (b) from about 1.0 to about 48.0 mole percent of at least one polymerizable free-radical initiator activatable by actinic radiation and selected from the group consisting of tetrachlorophthalic anhydride, tetrabromophthalic anhydride and 1,4,5,6,7,7-hexachloro-5-norbornene-2,3-dicarboxylic anhydride and mixtures thereof; (c) from about 1.0 to about 48.0 mole percent of at least one nonhalogenated cyclic anhydride containing from 4 to 10 carbon atoms; and (d) from about 1.0 to about 48.0 mole percent of at least one epoxide containing 2 to 8 carbon atoms and selected from the group consisting of epoxyalkyl acrylates and methacrylates and alkylene oxides.
Claim 3
Dependent Claim
119 words
The actinic radiation curable composition of claim 1 wherein there is additionally present up to an equimolar amount of at least one nonchemically bonded, copolymerizable acrylic diluent monomer selected from the group consisting of acrylic and methacrylic acids; the hydroxyalkyl esters of said acids, wherein the alkyl chains contain from 2 to 20 carbon atoms; the glycidyl ester derivatives of said acids; the non-gem alkanediol ester derivatives of said acids, wherein the alkyl groups contain from 2 to 20 carbon atoms; the ethylene glycol and polyethylene glycol ester derivatives of said acids; the polyhydric alcohol ester derivatives of said acids; and the cycloalkyl ester derivatives of said acids, wherein the cycloalkyl groups contain from 5 to 14 carbon atoms.
Claim 4
Dependent Claim
15 words
The actinic radiation curable composition of claim 1 wherein said component (a) is 2-hydroxyethyl acrylate.
Claim 5
Dependent Claim
15 words
The actinic radiation curable composition of claim 1 wherein said component (a) is 2-hydroxyethyl methacrylate.
Claim 6
Dependent Claim
28 words
The actinic radiation curable composition of claim 1 wherein said component (c) is selected from the group consisting of succinic anhydride, maleic anhydride, phthalic anhydride and mixtures thereof.
Claim 7
Dependent Claim
27 words
The actinic radiation curable composition of claim 1 wherein said component (d) is selected from the group consisting of glycidyl acrylate, glycidyl methacrylate, epichlorohydrin and mixtures thereof.
Claim 8
Dependent Claim
107 words
The actinic radiation curable composition of claim 1 comprising (a) from 6.0 to 15.0 mole percent of a member of the group consisting of 2-hydroxyethyl acrylate, 2-hydroxyethyl methacrylate, 2-hydroxypropyl methacrylate and mixtures thereof; (b) from 6.0 to 15.0 mole percent of a photoinitiator selected from the group consisting of tetrachlorophthalic anhydride, tetrabromophthalic anhydride and 1,4,5,6,7,7-hexachloro-3-norbornene-2,3-dicarboxylic anhydride and mixtures thereof; (c) from 28.0 to 40.0 mole percent of a member of the group consisting of succinic anhydride, phthalic anhydride, maleic anhydride and mixtures thereof; and (d) from 42.0 to 47.0 mole percent of a member of the group consisting of epichlorohydrin, glycidyl methacrylate, glycidyl acrylate and mixtures thereof.
Claim 9
Dependent Claim
21 words
A cured composition of matter prepared by exposing the composition of claim 1 to actinic radiation of 2000 to 4000 A.
Claim 10
Dependent Claim
20 words
A coated article comprising a substrate and on said substrate a coating of a cured composition according to claim 8.
References Cited (Backward Citations)
US3840390A
Cited
US3770602A
Cited
US3754054A
Cited
US3785849A
Cited
US3690927A
Cited
US4042645A
Cited
US3661614A
Cited
US3720592A
Cited
US3793293A
Cited
US3926639A
Cited
US3804735A
Cited
US3878076A
Cited
US4010289A
Cited
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1981-06-26 | 1981-12-26 | 1982-06-27 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1985-06-26 | 1985-12-26 | 1986-06-27 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1989-06-26 | 1989-12-26 | 1990-06-27 | $7700.00 | Window Closed / Lapsed |