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US4097350A Expired / Lapsed US ⏱️ 0.0 years remaining

Actinic radiation curable compositions

Assignee: Ingredion Inc
•
Filing: 1975-06-19
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Granted: 1978-06-27
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Expires: 1995-06-19
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Abstract

Abstract Actinic radiation curable compositions comprise chemically bonded portions of at least one free radical polymerizable hydroxyalkyl ester of an alpha, beta unsaturated carboxylic acid, at least one non-halogenated cyclic anhydride, at least one epoxide and a halogenated free radical initiator which is activatable by actinic radiation. Upon exposure to actinic radiation, these compositions are cured with very little or no inhibition by atmospheric oxygen.

Inventors

  • 👤 Stephen D. Pastor
  • 👤 Martin M. Skoultchi
  • 👤 Henry R. Hernandez

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-24 03:56
CPC Classifications
C; C08; C08F; C08F267/00; C08F267/04; C08F2/00; C08F2/46; C08F2/48; C08F265/00; C08F265/04; C09; C09D; C09D4/00; C09D4/06; Y; Y10; Y10T; Y10T428/00; Y10T428/31504; Y10T428/31551; Y10T428/31645; Y10T428/31649; Y10T428/31678; Y10T428/31692; Y10T428/31699; Y10T428/31786; Y10T428/31797; Y10T428/31855; Y10T428/31935

Claims Analysis

Total Claims: 10
Claim 1
Independent Claim 163 words
An actinic radiation curable prepolymeric composition of matter characterized by the presence of terminal unsaturation consisting essentially of the reaction product of: (a) from about 1.0 to about 48.0 mole percent of a hydroxyalkyl ester of an alpha, beta unsaturated carboxylic acid, wherein the alkyl group of the ester moiety contains from 2 to 20 carbon atoms, and the acid moiety contains from 3 to 4 carbon atoms; (b) from about 1.0 to about 48.0 mole percent of at least one polymerizable free-radical initiator activatable by actinic radiation and selected from the group consisting of tetrachlorophthalic anhydride, tetrabromophthalic anhydride and 1,4,5,6,7,7-hexachloro-5-norbornene-2,3-dicarboxylic anhydride and mixtures thereof; (c) from about 1.0 to about 48.0 mole percent of at least one nonhalogenated cyclic anhydride containing from 4 to 10 carbon atoms; and (d) from about 1.0 to about 48.0 mole percent of at least one epoxide containing 2 to 8 carbon atoms and selected from the group consisting of epoxyalkyl acrylates and methacrylates and alkylene oxides.
Claim 2
Dependent Claim 163 words
An actinic radiation curable prepolymeric composition of matter characterized by the presence of terminal unsaturation consisting essentially of the reaction product of: (a) from about 1.0 to about 48.0 mole percent of a hydroxyalkyl ester of an alpha, beta unsaturated carboxylic acid, wherein the alkyl group of the ester moiety contains from 2 to 20 carbon atoms, and the acid moiety contains from 3 to 4 carbon atoms; (b) from about 1.0 to about 48.0 mole percent of at least one polymerizable free-radical initiator activatable by actinic radiation and selected from the group consisting of tetrachlorophthalic anhydride, tetrabromophthalic anhydride and 1,4,5,6,7,7-hexachloro-5-norbornene-2,3-dicarboxylic anhydride and mixtures thereof; (c) from about 1.0 to about 48.0 mole percent of at least one nonhalogenated cyclic anhydride containing from 4 to 10 carbon atoms; and (d) from about 1.0 to about 48.0 mole percent of at least one epoxide containing 2 to 8 carbon atoms and selected from the group consisting of epoxyalkyl acrylates and methacrylates and alkylene oxides.
Claim 3
Dependent Claim 119 words
The actinic radiation curable composition of claim 1 wherein there is additionally present up to an equimolar amount of at least one nonchemically bonded, copolymerizable acrylic diluent monomer selected from the group consisting of acrylic and methacrylic acids; the hydroxyalkyl esters of said acids, wherein the alkyl chains contain from 2 to 20 carbon atoms; the glycidyl ester derivatives of said acids; the non-gem alkanediol ester derivatives of said acids, wherein the alkyl groups contain from 2 to 20 carbon atoms; the ethylene glycol and polyethylene glycol ester derivatives of said acids; the polyhydric alcohol ester derivatives of said acids; and the cycloalkyl ester derivatives of said acids, wherein the cycloalkyl groups contain from 5 to 14 carbon atoms.
Claim 4
Dependent Claim 15 words
The actinic radiation curable composition of claim 1 wherein said component (a) is 2-hydroxyethyl acrylate.
Claim 5
Dependent Claim 15 words
The actinic radiation curable composition of claim 1 wherein said component (a) is 2-hydroxyethyl methacrylate.
Claim 6
Dependent Claim 28 words
The actinic radiation curable composition of claim 1 wherein said component (c) is selected from the group consisting of succinic anhydride, maleic anhydride, phthalic anhydride and mixtures thereof.
Claim 7
Dependent Claim 27 words
The actinic radiation curable composition of claim 1 wherein said component (d) is selected from the group consisting of glycidyl acrylate, glycidyl methacrylate, epichlorohydrin and mixtures thereof.
Claim 8
Dependent Claim 107 words
The actinic radiation curable composition of claim 1 comprising (a) from 6.0 to 15.0 mole percent of a member of the group consisting of 2-hydroxyethyl acrylate, 2-hydroxyethyl methacrylate, 2-hydroxypropyl methacrylate and mixtures thereof; (b) from 6.0 to 15.0 mole percent of a photoinitiator selected from the group consisting of tetrachlorophthalic anhydride, tetrabromophthalic anhydride and 1,4,5,6,7,7-hexachloro-3-norbornene-2,3-dicarboxylic anhydride and mixtures thereof; (c) from 28.0 to 40.0 mole percent of a member of the group consisting of succinic anhydride, phthalic anhydride, maleic anhydride and mixtures thereof; and (d) from 42.0 to 47.0 mole percent of a member of the group consisting of epichlorohydrin, glycidyl methacrylate, glycidyl acrylate and mixtures thereof.
Claim 9
Dependent Claim 21 words
A cured composition of matter prepared by exposing the composition of claim 1 to actinic radiation of 2000 to 4000 A.
Claim 10
Dependent Claim 20 words
A coated article comprising a substrate and on said substrate a coating of a cured composition according to claim 8.

References Cited (Backward Citations)

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USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1981-06-26 1981-12-26 1982-06-27 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1985-06-26 1985-12-26 1986-06-27 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1989-06-26 1989-12-26 1990-06-27 $7700.00 Window Closed / Lapsed

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