US4081475A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Trialkylsubstituted hydroxybenzyl malonates and stabilized compositions
Assignee: Novartis Corp
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Filing: 1975-07-17
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Granted: 1978-03-28
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Expires: 1995-07-17
Abstract
Abstract Compounds having the formula ##STR1## wherein R 1 , R 2 and R 3 are alkyl or cycloalkyl; R 4 and R 5 are alkyl or phenyl; and R is hydrogen, alkyl or a trialkylhydroxybenzyl, Are good antioxidants and thermal stabilizers. These compounds are prepared by reacting the corresponding alkylated 4-hydroxybenzyl-tert-amine with a malonate ester in the presence of an alkali metal alkoxide.
Inventors
- 👤 John d. Spivack
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-03 15:08
CPC Classifications
C; C10; C10L; C10L1/00; C10L1/10; C10L1/14; C10L1/18; C10L1/19; C10L1/1905; C07; C07C; C07C37/00; C07C37/62; C07C69/00; C07C69/66; C07C69/73; C07C69/732; C08; C08K; C08K5/00; C08K5/04; C08K5/10; C08K5/11
Claims Analysis
Total Claims: 8
Claim 1
Independent Claim
60 words
Compounds having the formula ##STR11## wherein R 1 , R 2 and R 3 are independently alkyl groups of 1 to 8 carbons, R 4 and R 5 are alkyl of 1 to 30 carbons, phenyl, alkyl substituted phenyl having up to 24 carbons, or cyclohexyl, and R is hydrogen, alkyl of 1 to 8 carbons or a group ##STR12##
Claim 2
Dependent Claim
60 words
Compounds having the formula ##STR11## wherein R 1 , R 2 and R 3 are independently alkyl groups of 1 to 8 carbons, R 4 and R 5 are alkyl of 1 to 30 carbons, phenyl, alkyl substituted phenyl having up to 24 carbons, or cyclohexyl, and R is hydrogen, alkyl of 1 to 8 carbons or a group ##STR12##
Claim 3
Dependent Claim
43 words
A compound of claim 1 wherein R 1 is branched alkyl, R 2 and R 3 are alkyl of 1 to 3 carbons, R 4 and R 5 are alkyl of 1 to 18 carbons, and R is hydrogen or the group ##STR13##
Claim 4
Dependent Claim
18 words
A compound of claim 2 wherein R 1 is tert-butyl, and R 2 and R 3 are methyl.
Claim 5
Dependent Claim
9 words
The compound of claim 1 which is di-n-octadecyl(5-tert.-butyl-2,3-dimethylhydroxybenzyl) malonate.
Claim 6
Dependent Claim
9 words
The compound of claim 1 which is di-n-octadecyl bis(5-tert.-butyl-2,3-dimethyl-4-hydroxybenzyl)malonate.
Claim 7
Dependent Claim
9 words
The compound of claim 1 which is dimethyl (5-tert.-butyl-2,3-dimethyl-4-hydroxybenzyl)malonate.
Claim 8
Dependent Claim
9 words
The compound of claim 1 which is dimethyl bis(5-tert.-butyl-2,3-dimethyl-4-hydroxybenzyl)malonate.
References Cited (Backward Citations)
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1981-03-27 | 1981-09-26 | 1982-03-28 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1985-03-27 | 1985-09-26 | 1986-03-28 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1989-03-27 | 1989-09-26 | 1990-03-28 | $7700.00 | Window Closed / Lapsed |