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US3721704A Expired / Lapsed US ⏱️ 0.0 years remaining

Esters of (dialkyl-4-hydroxy-phenyl)malonic acid and related compounds

Assignee: Novartis Corp
•
Filing: 1967-02-17
•
Granted: 1973-03-20
•
Expires: 1987-02-17
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Abstract

Abstract Derivatives of malonic acid substituted with groups containing a hindered phenol are disclosed. A preferred compound is di-noctadecyl-2,2-bis-(3'',5''-di-t-butyl-4''-hydroxybenzyl) malonate. The compounds are stabilizers suitable for stabilizing numerous substrates of organic material subject to oxidative deterioration, in particular polypropylene. Synergistic combinations of these compounds and dialkyl thiodipropionates are disclosed.

Inventors

  • 👤 M Dexter

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-26 04:09
CPC Classifications
C; C07; C07C; C07C255/00; C07C45/00; C07C45/61; C07C45/67; C07C45/68; C08; C08K; C08K5/00; C08K5/04; C08K5/13; C08K5/134; C08K5/1345; C08K5/16; Y; Y10; Y10S; Y10S524/00; Y10S524/925; Y10S524/929

Claims Analysis

Total Claims: 11
Claim 1
Independent Claim 17 words
A Compound as claimed in claim 1 wherein A is alkylene of one to six carbon atoms.
Claim 2
Dependent Claim 19 words
A compound as claimed in claim 1 wherein R1 and R2 are alkyl or one to eight carbon atoms.
Claim 3
Dependent Claim 37 words
A bis(3,5-dialkyl-4-hydroxybenzyl) malonic ester of the formula wherein R1 and R2 are alkyl radicals having from one to 18 carbon atoms and R'', R'''', R'''''', and R are alkyl radicals having from one to nine carbon atoms.
Claim 4
Dependent Claim 18 words
A compound as claimed in claim 3 wherein R5 is alkyl of one to four carbon atoms or
Claim 5
Dependent Claim 14 words
A compound as claimed in claim 5 wherein R1 and R2 are tertiary butyl.
Claim 6
Dependent Claim 36 words
A compound as claimed in claim 5 wherein n is O; Y and Y1 are and R3 and R4 independently are alkyl of one to 24 carbon atoms and alkylthioalkyl; R5 is and A is methylene.
Claim 7
Dependent Claim 11 words
A compound as claimed in claim 1 which is diethyl-2,2-bis-(3'',5''di-t-butyl-4-hydroxybenzyl) malonate.
Claim 8
Dependent Claim 11 words
A compound as claimed in claim 1 which is dimethyl-2,2-bis-(3'',5''di-t-butyl-4-hydroxybenzyl) malonate.
Claim 9
Dependent Claim 12 words
A compound as claimed in claim 1 which is di-n-octadecyl-2, 2-bis-(3'',5''-di-t-butyl-4''-hydroxybenzyl) malonate.
Claim 10
Dependent Claim 12 words
A compound as claimed in claim 1 which is diethyl-2-butyl-2, 2-bis-(3'',5''-di-t-butyl-4-hydroxybenzyl) malonate.
Claim 11
Dependent Claim 12 words
A compound as claimed in claim 1 which is ethyl-2,2-bis-(3'', 5''-di-t-butyl-4-hydroxybenzyl) acetoacetate.

References Cited (Backward Citations)

No citation records indexed.

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1976-03-19 1976-09-18 1977-03-20 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1980-03-19 1980-09-18 1981-03-20 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1984-03-19 1984-09-18 1985-03-20 $7700.00 Window Closed / Lapsed

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