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US3678095A Expired / Lapsed US ⏱️ 0.0 years remaining

Substituted derivatives of malonic acid useful as stabilizers

Assignee: Novartis Corp
•
Filing: 1970-07-17
•
Granted: 1972-07-18
•
Expires: 1990-07-17
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Abstract

Abstract Derivatives of malonic acid substituted with groups containing a hindered phenol are disclosed. The compounds are stabilizers suitable for stabilizing numerous substrates of organic material subject to oxidative deterioration, in particular polypropylene. Synergistic combinations of these compounds and dialkyl thiodipropionates are disclosed.

Inventors

  • 👤 Martin Dexter
  • 👤 John Denon Spivack

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-04 03:52
CPC Classifications
C; C07; C07C; C07C255/00; C07C45/00; C07C45/61; C07C45/67; C07C45/68; C08; C08K; C08K5/00; C08K5/04; C08K5/10; C08K5/11; C08K5/13; C08K5/134; C08K5/1345; C09; C09K; C09K15/00; C09K15/04; C09K15/06; C09K15/08; C10; C10M; C10M3/00; C10M2207/00; C10M2207/28; C10M2207/281; C10M2207/282; C10M2207/283; C10M2207/286; C10M2207/287; C10M2207/34; C10M2209/00; C10M2209/10; C10M2209/103; C10M2209/105; C10M2211/00; C10M2211/02; C10M2211/022; C10M2211/06; C10M2215/00; C10M2215/08; C10M2215/082; C10M2215/16; C10M2215/24; C10M2215/28; C10M2219/00; C10M2219/08; C10M2219/082; C10M2219/085; C10M2223/00; C10M2223/02; C10M2223/04; C10M2223/042; C10M2227/00; C10M2227/02; C10M2229/00; C10M2229/04; C10M2229/041; C10M2229/043; C10M2229/044

Claims Analysis

Total Claims: 7
Claim 1
Independent Claim 9 words
A compound claimed in claim 1 wherein R5 is
Claim 2
Dependent Claim 13 words
A compound claimed in claim 1 wherein R1 and R2 are tertiary butyl.
Claim 3
Dependent Claim 13 words
A compound claimed in claim 2 where R1 and R2 are tertiary butyl.
Claim 4
Dependent Claim 53 words
A compound selected from the group consisting of di-m-methylphenyl-2,2,bis(3'' ,5''-di-t-butyl-4''-hydroxybenzyl) malonate; di-4''-sec-butylphenyl-2,2-bis-(3'''' ,5''''-di-t-butyl-4''''-hydroxybenzyl) malonate; di-4''-isoamylphenyl-2,2-bis (3'''' ,5''''-di-t-butyl-4'''' -hydroxybenzyl)malonate; di-4''-t-hexylbenzyl-2,2,-bis(3'''' ,5''''-di-t-butyl-4''''-hydroxybenzyl) malonate; di-2''-methyl-4''-t-hexylbenzyl-2,2-bis (3'''' ,5''''-di-t-butyl-4''''-hydroxybenzyl) malonate; di-4''-cyclohexylbenzyl-2,2-bis(3'''' ,5''''-di-t-butyl-4''''-hydroxybenzyl) malonate; di-4''-phenylphenyl-2,2-bis (3'''' ,5''''-di-t-butyl-4''''-hydroxybenzyl) malonate; di-4''-t-octylphenyl-2,2-bis(3''''t-butyl-5''''-methyl-4''''-hydroxybenzyl) malonate; di-4''-t-octylphenyl-2,2,bis (3'''' ,5'''' dimethyl-4''''-hydroxybenzyl) malonate; di-4''-t-octylphenyl-2,2-bis (3'''' ,5''''-di-t-butyl-4'''' -hydroxybenzyl) malonate; diphenyl-2,2-bis (3'' 5''-di-t-butyl-4''-hydroxybenzyl) malonate; di-4''di-t-butylphenyl-2,2-bis (3'''' ,5'''' -di-t-butyl-4''''-hydroxybenzyl) malonate.
Claim 5
Dependent Claim 4 words
Di-4'' -t-octylphenyl-2,2-bis-(3'''' ,5''''-di-t-butyl-4''-hydroxybenzyl) malonate.
Claim 6
Dependent Claim 2 words
Diphenyl-2,2-bis(3'',5''-di-t-butyl-4''-hydroxybenzyl) malonate.
Claim 7
Dependent Claim 3 words
Di-4''-t-butylphenyl-2,2-bis-(3'''' ,5''''-di-t-butyl-4''''-hydroxybenzyl) malonate.

References Cited (Backward Citations)

US3112338A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1975-07-18 1976-01-17 1976-07-18 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1979-07-18 1980-01-17 1980-07-18 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1983-07-18 1984-01-17 1984-07-18 $7700.00 Window Closed / Lapsed

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