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US4062800A Expired / Lapsed US ⏱️ 0.0 years remaining

Bichromophoric benzoxazole-styrene ester and amide ultraviolet stabilizers and their use in organic compositions

Assignee: Eastman Chemical Co
•
Filing: 1976-08-16
•
Granted: 1977-12-13
•
Expires: 1996-08-16
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Abstract

Abstract The invention relates to bichromophoric benzoxazole-styrene ester and amide compounds which have been found to be effective ultraviolet stabilizers. The invention also relates to ultraviolet degradable organic compositions containing a stabilizing amount of the bichromophoric composition to prevent such degradation. These stabilizers are effective in the presence of other additives commonly employed in polymeric compositions including, for example, pigments, colorants, fillers, reinforcing agents and the like. These ultraviolet stabilizers may also be incorporated into the organic compositions in the polymer melt or dissolved in the polymer dope, coated on the exterior of the molded article, film or extruded fiber.

Inventors

  • 👤 Gether Irick, Jr.
  • 👤 Charles A. Kelly
  • 👤 James C. Martin

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-07 16:03
CPC Classifications
C; C07; C07D; C07D263/00; C07D263/52; C07D263/54; C07D263/56; C07D263/57; C08; C08K; C08K5/00; C08K5/16; C08K5/34; C08K5/35

Claims Analysis

Total Claims: 42
Claim 1
Independent Claim 280 words
An organic composition susceptible to ultraviolet light degradation stabilized against such degradation with a stabilizing amount of at least one bichromophoric compound having the formula: A--B--C wherein A is a group having the structure ##STR7## wherein R 1 , R 2 , R 3 and R 4 are hydrogen, chloro, bromo, lower alkyl, substituted lower alkyl, cycloalkyl, substituted cycloalkyl, aryl, substituted aryl, lower alkylaryl, aryl-substituted-aryl, alkoxy, substituted amino, cyano, carboalkoxy and the substituents R 1 and R 2 , R 2 and R 3 , and R 3 and R 4 , combined with the carbon atoms to which they are attached, are joined alkylene groups completing a carbocyclic ring, which ring can also be substituted with one or more of the substituents listed above for R 1 , R 2 , R 3 and R 4 ; I is the same as R 1 , R 2 , R 3 and R 4 and is present on all positions of the benzenoid ring, except the carbon atom attached to the heterocyclic ring and the carbon atom attached to the B group connecting the heterocyclic aromatic A group with the aromatic C group, wherein B is a linking group connecting A and C and can be oxy, oxycarbonylalkyleneoxy, alkyleneoxy, alkyleneoxyalkyleneoxy, oxyalkylenearylenealkyleneoxy, thio, thioalkyleneoxy, aminocarbonylalkyleneoxy, N-alkylaminocarbonylalkyleneoxy, N-arylaminocarbonylalkyleneoxy, N-alkylamino, N-arylamino, N-arylaminoalkyleneoxy, N-alkyleneaminoalkyleneoxy, oxyalkyleneoxy, oxyaryleneoxy; and wherein C is a group having the formula ##STR8## where I is the same substituent as listed above and said I substituents can all be one of the substituents listed above or different listed substituents and R 5 is an alkyl group containing 1 to 20 carbon atoms and R 6 is cyano, carboxamido, alkanoyl or alkylsulfonyl.
Claim 2
Dependent Claim 280 words
An organic composition susceptible to ultraviolet light degradation stabilized against such degradation with a stabilizing amount of at least one bichromophoric compound having the formula: A--B--C wherein A is a group having the structure ##STR7## wherein R 1 , R 2 , R 3 and R 4 are hydrogen, chloro, bromo, lower alkyl, substituted lower alkyl, cycloalkyl, substituted cycloalkyl, aryl, substituted aryl, lower alkylaryl, aryl-substituted-aryl, alkoxy, substituted amino, cyano, carboalkoxy and the substituents R 1 and R 2 , R 2 and R 3 , and R 3 and R 4 , combined with the carbon atoms to which they are attached, are joined alkylene groups completing a carbocyclic ring, which ring can also be substituted with one or more of the substituents listed above for R 1 , R 2 , R 3 and R 4 ; I is the same as R 1 , R 2 , R 3 and R 4 and is present on all positions of the benzenoid ring, except the carbon atom attached to the heterocyclic ring and the carbon atom attached to the B group connecting the heterocyclic aromatic A group with the aromatic C group, wherein B is a linking group connecting A and C and can be oxy, oxycarbonylalkyleneoxy, alkyleneoxy, alkyleneoxyalkyleneoxy, oxyalkylenearylenealkyleneoxy, thio, thioalkyleneoxy, aminocarbonylalkyleneoxy, N-alkylaminocarbonylalkyleneoxy, N-arylaminocarbonylalkyleneoxy, N-alkylamino, N-arylamino, N-arylaminoalkyleneoxy, N-alkyleneaminoalkyleneoxy, oxyalkyleneoxy, oxyaryleneoxy; and wherein C is a group having the formula ##STR8## where I is the same substituent as listed above and said I substituents can all be one of the substituents listed above or different listed substituents and R 5 is an alkyl group containing 1 to 20 carbon atoms and R 6 is cyano, carboxamido, alkanoyl or alkylsulfonyl.
Claim 3
Dependent Claim 14 words
An organic composition according to claim 1 wherein said B linking group is oxycarbonylalkyleneoxy.
Claim 4
Dependent Claim 14 words
An organic composition according to claim 1 wherein said B linking group is alkyleneoxy.
Claim 5
Dependent Claim 14 words
An organic composition according to claim 1 wherein said B linking group is alkyleneoxyalkyleneoxy.
Claim 6
Dependent Claim 14 words
An organic composition according to claim 1 wherein said B linking group is oxyalkylenearylenealkyleneoxy.
Claim 7
Dependent Claim 14 words
An organic composition according to claim 1 wherein said B linking group is thio.
Claim 8
Dependent Claim 14 words
An organic composition according to claim 1 wherein said B linking group is thioalkyleneoxy.
Claim 9
Dependent Claim 14 words
An organic composition according to claim 1 wherein said B linking group is aminocarbonylalkyleneoxy.
Claim 10
Dependent Claim 14 words
An organic composition according to claim 1 wherein said B linking group is N-alkylaminocarbonylalkyleneoxy.
Claim 11
Dependent Claim 14 words
An organic composition according to claim 1 wherein said B linking group is N-arylaminocarbonylalkyleneoxy.
Claim 12
Dependent Claim 14 words
An organic composition according to claim 1 wherein said B linking group is N-alkylamino.
Claim 13
Dependent Claim 14 words
An organic composition according to claim 1 wherein said B linking group is N-arylamino.
Claim 14
Dependent Claim 14 words
An organic composition according to claim 1 wherein said B linking group is N-alkylaminoalkyleneoxy.
Claim 15
Dependent Claim 14 words
An organic composition according to claim 1 wherein said B linking group is N-arylaminoalkyleneoxy.
Claim 16
Dependent Claim 13 words
An organic composition to claim 1 wherein said B linking group is oxyalkyleneoxy.
Claim 17
Dependent Claim 14 words
An organic composition according to claim 1 wherein said B linking group is oxyaryleneoxy.
Claim 18
Dependent Claim 14 words
An organic composition according to claim 1 wherein said B linking group is oxymethylene.
Claim 19
Dependent Claim 14 words
An organic composition according to claim 1 wherein said B linking group is methyleneoxy.
Claim 20
Dependent Claim 14 words
An organic composition according to claim 1 wherein said B linking group is oxymethyleneoxy.
Claim 21
Dependent Claim 14 words
An organic composition according to claim 1 wherein said B linking group is oxyethyleneoxy.
Claim 22
Dependent Claim 15 words
An organic composition according to claim 1 wherein said bichromophoric compound has the formula: ##STR9##
Claim 23
Dependent Claim 15 words
An organic composition according to claim 1 wherein said bichromophoric compound has the formula: ##STR10##
Claim 24
Dependent Claim 15 words
An organic composition according to claim 1 wherein said bichromophoric compound has the formula: ##STR11##
Claim 25
Dependent Claim 15 words
An organic composition according to claim 1 wherein said bichromophoric compound has the formula: ##STR12##
Claim 26
Dependent Claim 15 words
An organic composition according to claim 1 wherein said bichromophoric compound has the formula: ##STR13##
Claim 27
Dependent Claim 15 words
An organic composition according to claim 1 wherein said bichromophoric compound has the formula: ##STR14##
Claim 28
Dependent Claim 15 words
An organic composition according to claim 1 wherein said bichromophoric compound has the formula: ##STR15##
Claim 29
Dependent Claim 15 words
An organic composition according to claim 1 wherein said bichromophoric compound has the formula: ##STR16##
Claim 30
Dependent Claim 15 words
An organic composition according to claim 1 wherein said bichromophoric compound has the formula: ##STR17##
Claim 31
Dependent Claim 15 words
An organic composition according to claim 1 wherein said bichromophoric compound has the formula: ##STR18##
Claim 32
Dependent Claim 15 words
An organic composition according to claim 1 wherein said bichromophoric compound has the formula: ##STR19##
Claim 33
Dependent Claim 15 words
An organic composition according to claim 1 wherein said bichromophoric compound has the formula: ##STR20##
Claim 34
Dependent Claim 15 words
An organic composition according to claim 1 wherein said bichromophoric compound has the formula: ##STR21##
Claim 35
Dependent Claim 15 words
An organic composition according to claim 1 wherein said bichromophoric compound has the formula: ##STR22##
Claim 36
Dependent Claim 15 words
An organic composition according to claim 1 wherein said bichromophoric compound has the formula: ##STR23##
Claim 37
Dependent Claim 15 words
An organic composition according to claim 1 wherein said bichromophoric compound has the formula: ##STR24##
Claim 38
Dependent Claim 15 words
An organic composition according to claim 1 wherein said bichromophoric compound has the formula: ##STR25##
Claim 39
Dependent Claim 15 words
An organic composition according to claim 1 wherein said bichromophoric compound has the formula: ##STR26##
Claim 40
Dependent Claim 15 words
An organic composition according to claim 1 wherein said bichromophoric compound has the formula: ##STR27##
Claim 41
Dependent Claim 15 words
An organic composition according to claim 1 wherein said bichromophoric compound has the formula: ##STR28##
Claim 42
Dependent Claim 15 words
An organic composition according to claim 1 wherein said bichromophoric compound has the formula: ##STR29##

References Cited (Backward Citations)

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USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1980-12-12 1981-06-13 1981-12-13 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1984-12-12 1985-06-13 1985-12-13 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1988-12-12 1989-06-13 1989-12-13 $7700.00 Window Closed / Lapsed

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