US3936419A
Expired / Lapsed
US
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Multichromophoric ultraviolet stabilizers and their use in organic compositions
Assignee: Eastman Kodak Co
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Filing: 1974-10-02
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Granted: 1976-02-03
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Expires: 1994-10-02
Abstract
Abstract The invention relates to multichromophoric compounds which have been found to be effective ultraviolet stabilizers. The invention also relates to ultraviolet degradable organic compositions containing a stabilizing amount of the multichromophoric composition to prevent such degradation. These stabilizers are effective in the presence of other additives commonly employed in polymeric compositions including, for example, pigments, colorants, fillers, reinforcing agents and the like. These ultraviolet stabilizers may also be incorporated into the organic compositions in the polymer melt or dissolved in the polymer dope, coated on the exterior of the molded article, film or extruded fiber.
Inventors
- 👤 Richard H. S. Wang
- 👤 Gether Irick, Jr.
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-03 20:45
CPC Classifications
C; C07; C07D; C07D249/00; C07D249/02; C07D249/08; C07C; C07C243/00; C07C243/24; C07C243/38; C07D263/00; C07D263/02; C07D263/30; C07D263/32; C07D271/00; C07D271/02; C07D271/10; C07D271/107; C08; C08K; C08K5/00; C08K5/0008; C08K5/005; C09; C09K; C09K15/00; C09K15/04; C09K15/32
Claims Analysis
Total Claims: 29
Claim 1
Independent Claim
98 words
An organic composition susceptible to ultraviolet degradation stabilized against such degradation with a stabilizing amount of a composition of matter comprising a compound having the formula (A-B n -C wherein A is a heterocyclic group having the structure ##SPC20## wherein X and Y are a carbon atom or a nitrogen atom; Z is an oxygen atom, a sulfur atom, a nitrogen atom, or a nitrogen atom containing a hydrogen atom or an unsubstituted or substituted lower alkyl group having 1 to 12 carbon atoms or an aryl group or substituted aryl group having 6 to 18 carbon atoms;
Claim 2
Dependent Claim
98 words
An organic composition susceptible to ultraviolet degradation stabilized against such degradation with a stabilizing amount of a composition of matter comprising a compound having the formula (A-B n -C wherein A is a heterocyclic group having the structure ##SPC20## wherein X and Y are a carbon atom or a nitrogen atom; Z is an oxygen atom, a sulfur atom, a nitrogen atom, or a nitrogen atom containing a hydrogen atom or an unsubstituted or substituted lower alkyl group having 1 to 12 carbon atoms or an aryl group or substituted aryl group having 6 to 18 carbon atoms;
Claim 3
Dependent Claim
102 words
R 1 , R 2 , R 3 and R 4 are hydrogen, fluoro, chloro, bromo, lower alkyl, substituted lower alkyl, cycloalkyl, substituted cycloalkyl, aryl, substituted aryl, lower alkylaryl, alkoxy, aryloxy, substituted amino, cyano, carboalkoxy and the substituents R 1 and R 2 , R 2 and R 3 , R 3 and R 4 , combined with the carbon atoms to which they are attached, are joined alkylene groups completing a carbocyclic ring, which ring can also be substituted with one or more of the substituents listed above for R 1 , R 2 , R 3 and R 4 ;
Claim 4
Dependent Claim
102 words
R 1 , R 2 , R 3 and R 4 are hydrogen, fluoro, chloro, bromo, lower alkyl, substituted lower alkyl, cycloalkyl, substituted cycloalkyl, aryl, substituted aryl, lower alkylaryl, alkoxy, aryloxy, substituted amino, cyano, carboalkoxy and the substituents R 1 and R 2 , R 2 and R 3 , R 3 and R 4 , combined with the carbon atoms to which they are attached, are joined alkylene groups completing a carbocyclic ring, which ring can also be substituted with one or more of the substituents listed above for R 1 , R 2 , R 3 and R 4 ;
Claim 5
Dependent Claim
97 words
I is the same as R 1 , R 2 , R 3 and R 4 and is present on all positions of the benzenoid ring, except the carbon atom attached to the Y substituent and the carbon atom attached to the B group connecting the heterocyclic aromatic A group with the aromatic C group, said B connecting group is attached to the benzenoid ring in the ortho, meta or para positions from the carbon atom connected to the Y substituent, said I substituents can all be one of the substituents listed above or different listed substituents;
Claim 6
Dependent Claim
97 words
I is the same as R 1 , R 2 , R 3 and R 4 and is present on all positions of the benzenoid ring, except the carbon atom attached to the Y substituent and the carbon atom attached to the B group connecting the heterocyclic aromatic A group with the aromatic C group, said B connecting group is attached to the benzenoid ring in the ortho, meta or para positions from the carbon atom connected to the Y substituent, said I substituents can all be one of the substituents listed above or different listed substituents;
Claim 7
Dependent Claim
26 words
B is a linking group connecting A and C and can have the structure ##EQU2## and --OEO-- where E is lower alkylene or substituted lower alkylene;
Claim 8
Dependent Claim
26 words
B is a linking group connecting A and C and can have the structure ##EQU2## and --OEO-- where E is lower alkylene or substituted lower alkylene;
Claim 9
Dependent Claim
12 words
The C group is a heterocyclic group having the structures ##SPC21## wherein
Claim 10
Dependent Claim
12 words
The C group is a heterocyclic group having the structures ##SPC21## wherein
Claim 11
Dependent Claim
129 words
X and Y are a carbon atom or a nitrogen atom; Z is an oxygen atom, a sulfur atom, a nitrogen atom, or a nitrogen atom containing a hydrogen atom or a substituted or unsubstituted lower alkyl group having 1 to 12 carbon atoms; I is hydrogen, fluoro, chloro, bromo, lower alkyl, substituted lower alkyl, cycloalkyl, substituted cycloalkyl, aryl, substituted aryl, lower alkylaryl, aryl-substituted-aryl, alkoxy, aryloxy, substituted amino and cyano; I is present on all positions of the benzenoid ring, except the carbon atom attached to the Y substituent and the carbon atom attached to B group; E is a substituted or unsubstituted, branched or unbranched alkylene containing 1 to 12 carbon atoms or arylene containing 6 to 18 carbon atoms; n is an integer from 1 to 6.
Claim 12
Dependent Claim
129 words
X and Y are a carbon atom or a nitrogen atom; Z is an oxygen atom, a sulfur atom, a nitrogen atom, or a nitrogen atom containing a hydrogen atom or a substituted or unsubstituted lower alkyl group having 1 to 12 carbon atoms; I is hydrogen, fluoro, chloro, bromo, lower alkyl, substituted lower alkyl, cycloalkyl, substituted cycloalkyl, aryl, substituted aryl, lower alkylaryl, aryl-substituted-aryl, alkoxy, aryloxy, substituted amino and cyano; I is present on all positions of the benzenoid ring, except the carbon atom attached to the Y substituent and the carbon atom attached to B group; E is a substituted or unsubstituted, branched or unbranched alkylene containing 1 to 12 carbon atoms or arylene containing 6 to 18 carbon atoms; n is an integer from 1 to 6.
Claim 13
Dependent Claim
20 words
An organic composition according to claim 1 containing a stabilizing amount of a composition of matter having the formula: ##SPC22##
Claim 14
Dependent Claim
20 words
An organic composition according to claim 1 containing a stabilizing amount of a composition of matter having the formula: ##SPC23##
Claim 15
Dependent Claim
20 words
An organic composition according to claim 1 containing a stabilizing amount of a composition of matter having the formula: ##SPC24##
Claim 16
Dependent Claim
20 words
An organic composition according to claim 1 containing a stabilizing amount of a composition of matter having the formula: ##SPC25##
Claim 17
Dependent Claim
20 words
An organic composition according to claim 1 containing a stabilizing amount of a composition of matter having the formula: ##SPC26##
Claim 18
Dependent Claim
20 words
An organic composition according to claim 1 containing a stabilizing amount of a composition of matter having the formula: ##SPC27##
Claim 19
Dependent Claim
20 words
An organic composition according to claim 1 containing a stabilizing amount of a composition of matter having the formula: ##SPC28##
Claim 20
Dependent Claim
20 words
An organic composition according to claim 1 containing a stabilizing amount of a composition of matter having the formula: ##SPC29##
Claim 21
Dependent Claim
20 words
An organic composition according to claim 1 containing a stabilizing amount of a composition of matter having the formula: ##SPC30##
Claim 22
Dependent Claim
20 words
An organic composition according to claim 1 containing a stabilizing amount of a composition of matter having the formula: ##SPC31##
Claim 23
Dependent Claim
20 words
An organic composition according to claim 1 containing a stabilizing amount of a composition of matter having the formula: ##SPC32##
Claim 24
Dependent Claim
20 words
An organic composition according to claim 1 containing a stabilizing amount of a composition of matter having the formula: ##SPC33##
Claim 25
Dependent Claim
20 words
An organic composition according to claim 1 containing a stabilizing amount of a composition of matter having the formula: ##SPC34##
Claim 26
Dependent Claim
24 words
An organic composition susceptible to ultraviolet degradation stabilized against such degradation with a stabilizing amount of a composition of matter having the formula: ##SPC35##
Claim 27
Dependent Claim
24 words
An organic composition susceptible to ultraviolet degradation stabilized against such degradation with a stabilizing amount of a composition of matter having the formula: ##SPC35##
Claim 28
Dependent Claim
16 words
An organic composition containing a stabilizing amount of a composition of matter having the formula: ##SPC36##
Claim 29
Dependent Claim
16 words
An organic composition containing a stabilizing amount of a composition of matter having the formula: ##SPC36##
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1979-02-02 | 1979-08-04 | 1980-02-03 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1983-02-02 | 1983-08-04 | 1984-02-03 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1987-02-02 | 1987-08-04 | 1988-02-03 | $7700.00 | Window Closed / Lapsed |