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US4061584A Expired / Lapsed US ⏱️ 0.0 years remaining

High dielectric constant ink for thick film capacitors

Assignee: General Electric Co
•
Filing: 1976-01-22
•
Granted: 1977-12-06
•
Expires: 1996-01-22
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Abstract

Abstract An improved high dielectric constant ink useful in making thick film capacitors is disclosed in which a dielectric material is combined with a glass bonding agent having at least one electropositive element therein which is common with the powdered, high dielectric material which is one selected from the group consisting of chemically pure barium titanate and chemically pure barium titanate modified with from about 0.125% to about 5.0% by weight of a metal oxide additive. The glass bonding agent is an alkali-free binder comprising from 3 percent to 7 percent by total weight of the dielectric and binder materials.

Inventors

  • 👤 Roland T. Girard
  • 👤 George A. Rice

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-27 15:41
CPC Classifications
H; H01; H01G; H01G4/00; H01G4/002; H01G4/018; H01G4/06; H01G4/08; H01G4/12; H01G4/1209; H01G4/1218; H01G4/1227; H01G4/129

Claims Analysis

Total Claims: 12
Claim 1
Independent Claim 132 words
An improved dielectric ink for thick film printing consisting of: a powdered, high dielectric constant material which includes a barium titanate material which is one selected from the group consisting of chemically pure barium titanate and chemically pure barium titanate modified with from about 0.125% to about 5.0% by weight of a metal oxide additive; an alkali-free glass binder comprising from 3 percent to 7 percent by total weight of the dielectric and binder materials, the binder having at least the electropositive element barium present therein, the alkali-free glass has the following formulation: ______________________________________ Ingredient % by weight ______________________________________ BaO 38 to 46 ZnO 7 to 11 SiO.sub.2 35 to 45 B.sub.2 O.sub.3 6 to 8 Al.sub.2 O.sub.3 2 to 5 ______________________________________ and a liquid vehicle for said dielectric and binder materials.
Claim 2
Dependent Claim 132 words
An improved dielectric ink for thick film printing consisting of: a powdered, high dielectric constant material which includes a barium titanate material which is one selected from the group consisting of chemically pure barium titanate and chemically pure barium titanate modified with from about 0.125% to about 5.0% by weight of a metal oxide additive; an alkali-free glass binder comprising from 3 percent to 7 percent by total weight of the dielectric and binder materials, the binder having at least the electropositive element barium present therein, the alkali-free glass has the following formulation: ______________________________________ Ingredient % by weight ______________________________________ BaO 38 to 46 ZnO 7 to 11 SiO.sub.2 35 to 45 B.sub.2 O.sub.3 6 to 8 Al.sub.2 O.sub.3 2 to 5 ______________________________________ and a liquid vehicle for said dielectric and binder materials.
Claim 3
Dependent Claim 20 words
An improved dielectric ink as set forth in claim 1 wherein said powdered, high dielectric constant material comprises barium titanate.
Claim 4
Dependent Claim 30 words
An improved dielectric ink as set forth in claim 1 wherein said dielectric material is modified barium titanate, comprising from 82% to 86% by weight barium titanate, balance barium stannate.
Claim 5
Dependent Claim 39 words
An improved dielectric ink as set forth in claim 1 wherein the alkali-free glass binder has the following formation: ______________________________________ Ingredient % by weight ______________________________________ BaO 42 ZnO 9 SiO.sub.2 40 B.sub.2 O.sub. 3 6 Al.sub.2 O.sub.3 3. ______________________________________
Claim 6
Dependent Claim 46 words
An improved dielectric ink as set forth in claim 1 wherein the dielectric material composition is a modified barium titanate and the metal oxide additive is one selected from the class of materials consisting of lanthanum oxide, cerium compounds, stannates, zirconates, neodymium oxide and bismuth compounds.
Claim 7
Dependent Claim 22 words
An improved dielectric ink as set forth in claim 1 wherein the alkali-free glass binder includes titanium dioxide as an additive material.
Claim 8
Dependent Claim 41 words
An improved dielectric ink as set forth in claim 6 wherein the alkali-free glass binder has the following formulation: ______________________________________ Ingredient % by weight ______________________________________ BaO 38-46 ZnO 7-11 SiO.sub.2 35-45 B.sub.2 O.sub.3 6-8 Al.sub.2 O.sub. 3 2-5 TiO.sub.2 3-10. ______________________________________
Claim 9
Dependent Claim 40 words
The improved dielectric ink as set forth in claim 7 wherein the alkali-free glass binder has the following formulation: ______________________________________ Ingredient % by weight ______________________________________ BaO 42.05 ZnO 9.00 SiO.sub.2 35.59 B.sub.2 O.sub.3 5.96 Al.sub.2 O.sub.3 2.67 TiO.sub.2 4.73. ______________________________________
Claim 10
Dependent Claim 29 words
An improved dielectric ink as set forth in claim 8 wherein the dielectric material comprises from 82% to 86% by weight barium titanate and the remainder is barium stannate.
Claim 11
Dependent Claim 29 words
An improved dielectric ink as set forth in claim 6 wherein the dielectric material comprises from 82% to 86% by weight barium titanate and the remainder is barium stannate.
Claim 12
Dependent Claim 21 words
An improved dielectric ink as set forth in claim 10 wherein said glass binder comprises 3% by weight of said ink.

References Cited (Backward Citations)

US3293077A Cited
US3394290A Cited
US3582729A Cited
US3816172A Cited
US3778285A Cited
US3787219A Cited
US3878443A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1980-12-05 1981-06-06 1981-12-06 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1984-12-05 1985-06-06 1985-12-06 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1988-12-05 1989-06-06 1989-12-06 $7700.00 Window Closed / Lapsed

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