Patent US3766986A successfully refreshed from Google Patents.
US3766986A
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Method of treating a well using a volatile hydrocarbon liquid
Assignee: ExxonMobil Upstream Research Co
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Filing: 1972-08-18
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Granted: 1973-10-23
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Expires: 1992-08-18
Abstract
Abstract A method for treating a subterranean formation surrounding a wellbore wherein a viscous aqueous liquid containing an emulsifying agent and suspended propping agent particles is mixed with a volatile hydrocarbon liquid at a pressure higher than the vapor pressure of the volatile hydrocarbon liquid, and thereafter the mixture is injected through the wellbore and into the formation under conditions to open a fracture in the formation.
Inventors
- 👤 O Kiel
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-08 22:29
CPC Classifications
C; C09; C09K; C09K8/00; C09K8/60; C09K8/62; C09K8/64; E; E21; E21B; E21B43/00; E21B43/25; E21B43/26; E21B43/2607
Claims Analysis
Total Claims: 18
Claim 1
Independent Claim
21 words
A method as defined in claim 1 wherein the particulate material is blended into said viscous aqueous liquid at atmospheric pressure.
Claim 2
Dependent Claim
42 words
A method as defined in claim 1 wherein the amount of particulate material blended into said viscous aqueous liquid is sufficient to provide a concentration of between about 1 and about 6 pounds of said particulate material per gallon of said emulsion.
Claim 3
Dependent Claim
14 words
A method as defined in claim 1 wherein said volatile hydrocarbon liquid is propane.
Claim 4
Dependent Claim
14 words
A method as defined in claim 1 wherein said volatile hydrocarbon liquid is butane.
Claim 5
Dependent Claim
16 words
A method as defined in claim 1 wherein said volatile hydrocarbon liquid is liquid petroleum gas.
Claim 6
Dependent Claim
34 words
A method as defined in claim 1 wherein said viscous aqueous liquid has an apparent viscosity between about 10 and about 200 centipoises at 70*F and a shear rate of about 511 reciprocal seconds.
Claim 7
Dependent Claim
20 words
A method as defined in claim 7 wherein said viscous aqueous liquid comprises water containing a water-soluble polymeric thickening agent.
Claim 8
Dependent Claim
14 words
A method as defined in claim 8 wherein the polymeric thickening agent is polyacrylamide.
Claim 9
Dependent Claim
15 words
A method as defined in claim 8 wherein the polymeric thickening agent is guar gum.
Claim 10
Dependent Claim
29 words
A method as defined in claim 1 wherein the concentration of the volatile hydrocarbon liquid in the emulsion is between about 50 volume percent and about 80 volume percent.
Claim 11
Independent Claim
123 words
A method of treating a well which comprises blending together a nonvolatile hydrocarbon liquid and a viscous aqueous liquid containing an emulsifying agent to form an emulsion wherein the viscous aqueous liquid comprises the external phase and the nonvolatile hydrocarbon liquid comprises the internal phase; blending into said emulsion particulate material having a particle size between about 8 and about 100 mesh to form a slurry; mixing said slurry and a volatile hydrocarbon liquid together at a pressure above the vapor pressure of said volatile hydrocarbon liquid to increase the concentration of said hydrocarbon phase of said emulsion to between about 50 and about 80 volume percent; and thereafter injecting said emulsion containing said volatile hydrocarbon and said particulate material into said well.
Claim 12
Dependent Claim
33 words
A method as defined in claim 12 wherein said nonvolatile hydrocarbon liquid comprises not more than about 50 volume percent of the emulsion of said viscous aqueous liquid and said nonvolatile hydrocarbon liquid.
Claim 13
Dependent Claim
22 words
A method as defined in claim 12 wherein said volatile hydrocarbon liquid comprises at least 50 volume percent of said hydrocarbon phase.
Claim 14
Dependent Claim
16 words
A method as defined in claim 12 wherein said nonvolatile hydrocarbon liquid is a gas condensate.
Claim 15
Independent Claim
143 words
A method for the hydraulic fracturing of a subterranean formation surrounding a wellbore using a volatile hydrocarbon liquid which comprIses blending into a viscous aqueous liquid containing an emulsifying agent capable of forming an oil-in-water emulsion, propping agent particles having a particle size between about 8 and about 100 mesh to form a slurry; flowing said slurry at a pressure above the vapor pressure of said hydrocarbon liquid through a conduit; commingling said volatile hydrocarbon liquid with said slurry in said conduit to form an emulsion wherein the viscous aqueous liquid comprises the external phase and constitutes at least 20 volume percent of the emulsion and the volatile hydrocarbon liquid comprises the internal phase and constitutes no more than 80 volume percent of the emulsion; and injecting said emulsion into said wellbore at a pressure sufficient to open a fracture in said formation.
Claim 16
Independent Claim
140 words
A method for the hydraulic fracturing of a subterranean formation surrounding a wellbore using a volatile hydrocarbon liquid which comprises forming an emulsion which includes a viscous aqueous liquid as the external phase and a nonvolatile hydrocarbon as the internal phase; suspending in said emulsion propping agent particles having a particle size between about 8 and 100 mesh, flowing said emulsion containing the suspended propping agent particles through a conduit at a pressure above the vapor pressure of said volatile hydrocarbon liquid; introducing into said conduit said volatile hydrocarbon liquid to increase the concentration of said hydrocarbon phase of said emulsion to between about 50 and about 80 volume percent, and thereafter injecting said emulsion containing said volatile hydrocarbon liquid and said suspended propping agent particles into said formation at a pressure sufficient to open a fracture in said formation.
Claim 17
Independent Claim
132 words
A method for the hydraulic fracturing of a subterranean formation surrounding a wellbore using a volatile hydrocarbon liquid which comprises blending into a viscous aqueous liquid containing an emulsifying agent capable of forming an oil-in-water emulsion propping agent particles to form a slurry, pumping said slurry through a conduit and into said wellbore at a pressure above the vapor pressure of said volatile hydrocarbon liquid, said pressure being sufficient to open a fracture in said formation; and commingling with said slurry flowing through said conduit said volatile hydrocarbon liquid to form an emulsion wherein the viscous aqueous liquid comprises the external phase and constitutes at least 20 volume percent of the emulsion and said volatile hydrocarbon liquid comprises the internal phase and constitutes no more than 80 volume percent of the emulsion.
Claim 18
Independent Claim
122 words
A method for the hydraulic fracturing of a subterranean formation surrounding a wellbore using a volatile hydrocarbon liquid which comprises forming an emulsion which includes a viscous aqueous liquid as the external phase and a nonvolatile hydrocarbon liquid as the internal hydrocarbon phase; blending propping agent particles into said emulsion to form a slurry; pumping said slurry through a conduit and into said wellbore at a pressure sufficient to open a fracture in said formation, said pressure being above the vapor pressure of said volatile hydrocarbon liquid; introducing said volatile hydrocarbon liquid into said conduit to mix with said emulsion and thereby increase the concentration of said internal hydrocarbon phase of said emulsion to between about 50 and about 80 volume percent.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1976-10-22 | 1977-04-23 | 1977-10-23 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1980-10-22 | 1981-04-23 | 1981-10-23 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1984-10-22 | 1985-04-23 | 1985-10-23 | $7700.00 | Window Closed / Lapsed |