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US6689695B1 Expired / Lapsed US ⏱️ 0.0 years remaining

Multi-purpose composite mask for dual damascene patterning

Assignee: Taiwan Semiconductor Manufacturing Co TSMC Ltd
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Filing: 2002-06-28
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Granted: 2004-02-10
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Expires: 2022-06-28
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Abstract

Abstract A method is disclosed for forming dual damascene structures with a multi-purpose composite mask. The composite mask serves not only to prevent via poisoning, but also to improve the lithographic characteristics of forming a dual damascene structure. This is accomplished by using a mask comprising silicon-based as well as polymeric dielectric layers. Thus, one of the components of the composite mask, namely, the polymeric dielectric, makes it possible to protect the via openings by conformally covering the sidewalls of the via and, at the same time, by bringing controllability to the height of the protective dielectric in the via opening. In addition, because the polymeric dielectric also serves as the main plasma resisting layer during the trench etch, the required photoresist is much thinner; therefore, the lithography process window can be extended beneficially.

Inventors

  • 👤 Meng-Huei Lui
  • 👤 Mei-Hui Sung

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-30 08:38
CPC Classifications
H; H10; H10W; H10W20/00; H10W20/01; H10W20/071; H10W20/081; H10W20/084; H10W20/085; H10P; H10P50/00; H10P50/73; H10P76/00; H10P76/20; H10P76/40; H10P76/405; H10P76/408; H10P76/4088

Claims Analysis

Total Claims: 36
Claim 1
Independent Claim 156 words
A method of forming a multi-purpose composite mask for dual damascene patterning comprising the steps of: providing a substrate having a stack of dielectric layers comprising a barrier layer, a first dielectric layer, an etch-stop layer, a second dielectric layer and a cap layer formed thereon in said order wherein said first dielectric layer comprises a low-k material including black diamond; forming a via opening in said stack of dielectric layers; forming a polymeric dielectric layer over said substrate, including over said via opening; forming a silicon based dielectric layer over said polymeric dielectric layer; patterning said silicon based and polymeric dielectric layers to define a trench opening, and partially removing said polymeric dielectric layer from said via opening; using said polymeric dielectric as a via protector, etching further said trench opening until said etch-stop layer is reached; and cleaning any remaining polymeric dielectric in said via to complete the forming of said dual damascene structure.
Claim 2
Independent Claim 156 words
A method of forming a multi-purpose composite mask for dual damascene patterning comprising the steps of: providing a substrate having a stack of dielectric layers comprising a barrier layer, a first dielectric layer, an etch-stop layer, a second dielectric layer and a cap layer formed thereon in said order wherein said first dielectric layer comprises a low-k material including black diamond; forming a via opening in said stack of dielectric layers; forming a polymeric dielectric layer over said substrate, including over said via opening; forming a silicon based dielectric layer over said polymeric dielectric layer; patterning said silicon based and polymeric dielectric layers to define a trench opening, and partially removing said polymeric dielectric layer from said via opening; using said polymeric dielectric as a via protector, etching further said trench opening until said etch-stop layer is reached; and cleaning any remaining polymeric dielectric in said via to complete the forming of said dual damascene structure.
Claim 3
Dependent Claim 16 words
The method according to claim 1 , wherein said barrier layer comprises nitride or a carbide.
Claim 4
Dependent Claim 20 words
The method according to claim 1 , wherein said barrier layer has a thickness between about 200 to 1000 Å.
Claim 5
Dependent Claim 20 words
The method according to claim 1 , wherein said first dielectric has a thickness between about 2000 to 6000 Å.
Claim 6
Dependent Claim 15 words
The method according to claim 1 , wherein said etch-stop layer comprises nitride or carbide.
Claim 7
Dependent Claim 20 words
The method according to claim 1 , wherein said etch-stop layer has a thickness between about 200 to 6000 Å.
Claim 8
Dependent Claim 19 words
The method according to claim 1 , wherein said second dielectric layer comprises a low-k material including black diamond.
Claim 9
Dependent Claim 20 words
The method according to claim 1 , wherein said second dielectric has a thickness between about 2000 to 6000 Å.
Claim 10
Dependent Claim 15 words
The method according to claim 1 , wherein said cap layer comprises nitride or carbide.
Claim 11
Dependent Claim 20 words
The method according to claim 1 , wherein said cap layer has a thickness between about 200 to 1000 Å.
Claim 12
Dependent Claim 22 words
The method according to claim 1 , wherein said via opening is accomplished with an etch recipe comprising CxFy, N2, and O2.
Claim 13
Dependent Claim 21 words
The method according to claim 1 , wherein said polymeric dielectric layer has a thickness between about 1000 to 5000 Å.
Claim 14
Dependent Claim 18 words
The method according to claim 1 , wherein said silicon based dielectric layer comprises SiON, SiN, or siOx.
Claim 15
Dependent Claim 22 words
The method according to claim 1 , wherein said silicon based dielectric layer has a thickness between about 200 to 1000 Å.
Claim 16
Dependent Claim 26 words
The method according to claim 1 , wherein said patterning to define said trench opening is accomplished with a recipe comprising O2 or N2/H2 based plasma.
Claim 17
Dependent Claim 30 words
The method according to claim 1 , wherein said etching further said trench opening until said etch-stop layer is reached is accomplished with a recipe comprising CxFy, N2, and O2.
Claim 18
Dependent Claim 20 words
The method according to claim 1 , wherein said cleaning said remaining polymeric dielectric is accomplished by oxygen plasma ashing.
Claim 19
Independent Claim 244 words
A method of forming a multi-purpose composite mask for dual damascene patterning comprising the steps of: providing a substrate having a first metal layer formed thereon; forming a first dielectric layer over said first metal layer; forming a second dielectric layer over said first dielectric layer wherein said second dielectric layer comprises a low-k material including black diamond; forming a third dielectric layer over said second dielectric layer; forming a fourth dielectric layer over said third dielectric layer; forming a fifth dielectric layer over said fourth dielectric layer; forming a via opening starting from said fifth dielectric layer until reaching to and stopping on said first dielectric layer on said substrate; forming a polymeric dielectric layer over said substrate, including over said via opening; forming a silicon based dielectric layer over said polymeric dielectric layer; patterning said silicon based dielectric layer to define a hard mask for trench opening; using said silicon based dielectric layer as a hard mask, etching to transfer said trench opening into said polymeric dielectric layer, while at the same time leaving a portion of said polymeric dielectric in said via opening; using said silicon based and polymeric dielectric layers as a mask, further trench etching the underlying said fifth and fourth dielectric layers until stopping on said third dielectric layer; and removing said portion of said polymeric dielectric from the bottom of said via opening until said first dielectric via is reached, and said dual damascene structure is formed.
Claim 20
Independent Claim 244 words
A method of forming a multi-purpose composite mask for dual damascene patterning comprising the steps of: providing a substrate having a first metal layer formed thereon; forming a first dielectric layer over said first metal layer; forming a second dielectric layer over said first dielectric layer wherein said second dielectric layer comprises a low-k material including black diamond; forming a third dielectric layer over said second dielectric layer; forming a fourth dielectric layer over said third dielectric layer; forming a fifth dielectric layer over said fourth dielectric layer; forming a via opening starting from said fifth dielectric layer until reaching to and stopping on said first dielectric layer on said substrate; forming a polymeric dielectric layer over said substrate, including over said via opening; forming a silicon based dielectric layer over said polymeric dielectric layer; patterning said silicon based dielectric layer to define a hard mask for trench opening; using said silicon based dielectric layer as a hard mask, etching to transfer said trench opening into said polymeric dielectric layer, while at the same time leaving a portion of said polymeric dielectric in said via opening; using said silicon based and polymeric dielectric layers as a mask, further trench etching the underlying said fifth and fourth dielectric layers until stopping on said third dielectric layer; and removing said portion of said polymeric dielectric from the bottom of said via opening until said first dielectric via is reached, and said dual damascene structure is formed.
Claim 21
Dependent Claim 21 words
The method according to claim 18 , wherein said first dielectric layer is a barrier layer comprising nitride or a carbide.
Claim 22
Dependent Claim 21 words
The method according to claim 18 , wherein said first dielectric layer has a thickness between about 200 to 1000 Å.
Claim 23
Dependent Claim 20 words
The method according to claim 18 , wherein said second dielectric has a thickness between about 2000 to 6000 Å.
Claim 24
Dependent Claim 20 words
The method according to claim 18 , wherein said third dielectric layer is an etch-stop layer comprising nitride or carbide.
Claim 25
Dependent Claim 21 words
The method according to claim 18 , wherein said third dielectric layer has a thickness between about 200 to 1000 Å.
Claim 26
Dependent Claim 19 words
The method according to claim 18 , wherein said fourth dielectric layer comprises a low-k material including black diamond.
Claim 27
Dependent Claim 20 words
The method according to claim 18 , wherein said fourth dielectric has a thickness between about 2000 to 6000 Å.
Claim 28
Dependent Claim 20 words
The method according to claim 18 , wherein said fifth dielectric layer is a cap layer comprising nitride or carbide.
Claim 29
Dependent Claim 21 words
The method according to claim 18 , wherein said fifth dielectric layer has a thickness between about 200 to 1000 Å.
Claim 30
Dependent Claim 22 words
The method according to claim 18 , wherein said via opening is accomplished with an etch recipe comprising CxFy, N2, and O2.
Claim 31
Dependent Claim 21 words
The method according to claim 18 , wherein said polymeric dielectric layer has a thickness between about 1000 to 5000 Å.
Claim 32
Dependent Claim 18 words
The method according to claim 18 , wherein said silicon based dielectric layer comprises SiON, SiN, or SiOx.
Claim 33
Dependent Claim 22 words
The method according to claim 18 , wherein said silicon based dielectric layer has a thickness between about 200 to 1000 Å.
Claim 34
Dependent Claim 27 words
The method according to claim 18 , wherein said patterning to define for said trench opening is accomplished with a recipe comprising O2 or N2/H2 based plasma.
Claim 35
Dependent Claim 29 words
The method according to claim 18 , wherein said further trench etching until stopping on said third dielectric layer is accomplished with a recipe comprising CxFy, N2, and O2.
Claim 36
Dependent Claim 22 words
The method according to claim 18 , wherein said removing said portion of said polymeric dielectric is accomplished by oxygen plasma ashing.

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