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US6524908B2 Expired / Lapsed US ⏱️ 0.0 years remaining

Method for forming refractory metal-silicon-nitrogen capacitors and structures formed

Assignee: GlobalFoundries Inc
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Filing: 2001-06-01
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Granted: 2003-02-25
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Expires: 2021-06-01
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Abstract

Abstract A method forforming a refractory metal-silicon-nitrogen capacitor in a semiconductor structure and the structure formed are described. In the method, a pre-processed semiconductor substrate is first positioned in a sputtering chamber. Ar gas is then flown into the sputtering chamber to sputter deposit a first refractory metal-silicon-nitrogen layer on the substrate from a refractory metal silicide target, or from two targets of a refractory metal and a silicon. N2 gas is then flown into the sputtering chamber until that the concentration of N2 gas in the chamber is at least 35% to sputter deposit a second refractory metal-silicon-nitrogen layer on top of the first refractory metal-silicon-nitrogen layer. The N2 gas flow is then stopped to sputter deposit a third refractory metal-silicon-nitrogen layer on top of the second refractory metal-silicon-nitrogen layer. The multi-layer stack of the refractory metal-silicon-nitrogen is then photolithographically formed into a capacitor.

Inventors

  • 👤 Cyril Cabral, Jr.
  • 👤 Lawrence Clevenger
  • 👤 Louis Hsu
  • 👤 Keith Kwong Hon Wong

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-09 02:26
CPC Classifications
H; H10; H10D; H10D1/00; H10D1/60; H10D1/68; H10D1/692; H10D1/696; C; C23; C23C; C23C14/00; C23C14/0021; C23C14/0036; C23C14/0073; C23C14/06; C23C14/0641; H10P; H10P14/00; H10P14/40; H10P14/418; H10P14/42; H10P14/44

Claims Analysis

Total Claims: 12
Claim 1
Independent Claim 132 words
A method for forming a refractory metal-silicon-nitrogen capacitor in a semiconductor structure comprising the steps of: positioning a preprocessed semiconductor substrate in a sputtering chamber; flowing Ar gas into said sputtering chamber; sputter depositing a first refractory metal-silicon nitrogen layer on said substrate; flowing N 2 gas into said sputtering chamber such that concentration of said N 2 gas in said chamber is at least 35% by adjusting the flow or partial pressure of N 2 ; sputter depositing a second refractory metal-silicon-nitrogen layer on top of said first refractory metal-silicon nitrogen layer; stopping said N 2 gas flow into said sputter chamber; sputter depositing a third refractory metal-silicon-nitrogen layer on top of said second refractory metal-silicon-nitrogen layer; and photolithographically forming said first, second and third refractory metal-silicon-nitrogen layers into a capacitor.
Claim 2
Independent Claim 132 words
A method for forming a refractory metal-silicon-nitrogen capacitor in a semiconductor structure comprising the steps of: positioning a preprocessed semiconductor substrate in a sputtering chamber; flowing Ar gas into said sputtering chamber; sputter depositing a first refractory metal-silicon nitrogen layer on said substrate; flowing N 2 gas into said sputtering chamber such that concentration of said N 2 gas in said chamber is at least 35% by adjusting the flow or partial pressure of N 2 ; sputter depositing a second refractory metal-silicon-nitrogen layer on top of said first refractory metal-silicon nitrogen layer; stopping said N 2 gas flow into said sputter chamber; sputter depositing a third refractory metal-silicon-nitrogen layer on top of said second refractory metal-silicon-nitrogen layer; and photolithographically forming said first, second and third refractory metal-silicon-nitrogen layers into a capacitor.
Claim 3
Dependent Claim 33 words
A method for forming a refractory metal-silicon-nitrogen capacitor in a semiconductor structure according to claim 1 further comprising the step of in-situ annealing said capacitor at a temperature of at least 80° C.
Claim 4
Dependent Claim 41 words
A method for forming a refractory metal-silicon-nitrogen capacitor in a semiconductor structure according to claim 1 further comprising the step of flowing said Ar gas into said sputter chamber at a flow rate between about 10 sccm and about 200 sccm.
Claim 5
Dependent Claim 42 words
A method for forming a refractory metal-silicon-nitrogen capacitor in a semiconductor structure according to claim 1 further comprising the step of flowing said N 2 gas into said sputter chamber at a flow rate between about 1 sccm and about 100 sccm.
Claim 6
Dependent Claim 43 words
A method for forming a refractory metal-silicon-nitrogen capacitor in a semiconductor structure according to claim 1 further comprising the step of sputter depositing said first and said third refractory metal-silicon-nitrogen layer to a thickness of between about 100 Å and about 5000 Å.
Claim 7
Dependent Claim 40 words
A method for forming a refractory metal-silicon-nitrogen capacitor in a semiconductor structure according to claim 1 further comprising the step of sputter depositing said second refractory metal-silicon-nitrogen layer to a thickness of between about 100 Å and about 5000 Å.
Claim 8
Dependent Claim 42 words
A method for forming a refractory metal-silicon-nitrogen capacitor in a semiconductor structure according to claim 1 further comprising the step of sputter depositing said first and said third refractory metal-silicon-nitrogen layer each having a sheet resistance of not higher than 50 ohm/sq.
Claim 9
Dependent Claim 36 words
A method for forming a refractory metal-silicon-nitrogen capacitor in a semiconductor structure according to claim 1 further comprising the step of sputter depositing said second refractory metal-silicon-nitrogen layer which has a dielectric constant greater than 7.5.
Claim 10
Dependent Claim 48 words
A method for forming a refractory metal-silicon-nitrogen capacitor in a semiconductor structure according to claim 1 further comprising the step of sputter depositing said first, second and third refractory metal-silicon-nitrogen layers formed of a refractory metal selected from the group consisting of Ta, Nb, V, W and Ti.
Claim 11
Dependent Claim 39 words
A method for forming a refractory metal-silicon-nitrogen capacitor in a semiconductor structure according to claim 1 further comprising the step of sputter depositing said first, second and third refractory metal-silicon-nitrogen layers from a sputtering target of refractory metal silicide.
Claim 12
Dependent Claim 42 words
A method for forming a refractory metal-silicon-nitrogen capacitor in a semiconductor structure according to claim 1 further comprising the step of sputter depositing said first, second and third refractory metal-silicon-nitrogen layers from two sputtering targets of a refractory metal and a silicon.

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