Method and apparatus for emission control

Claim 3

The method of claim 1 wherein the catalyst bed is placed between two beds of a gas permeable material, said material being catalytically inactive with respect to catalytic reactions with the exhaust gases and serving for heat retention and regenerative heat exchange.

Claim 4

The method of claim 1 wherein the catalyst is a lean-NO x catalyst which is effective in NO x reduction to N 2 through the reaction with organic chemical reductant selected from the group consisting of linear, cyclic and aromatic hydrocarbons, aldehydes, alcohols and ketones, diesel fuel, gasoline, and mixtures thereof or wherein the catalyst is a selective catalytic reduction catalyst which is effective for NO x reduction to N 2 through the reaction with nitrogen containing reductant selected from the group consisting of ammonia, urea and mixtures thereof.

Claim 5

The method of claim 3 wherein said catalyst is a high temperature lean-NO x catalyst based on ion-exchanged zeolite which has temperature window for efficient NO x reduction between 250 and 500° C.

Claim 6

The method of claim 3 wherein said catalyst is a noble metal lean-NO x catalyst containing platinum, rhodium or palladium or mixtures thereof.

Claim 7

The method of claim 3 wherein said catalyst bed is divided into two parts and said organic reductant is added to the exhaust gases upstream of an inlet to the catalyst bed in the converter and between said two parts of the catalyst bed.

Claim 8

The method of claim 3 wherein said catalyst is a high temperature alumina supported or an aluminate based lean-NO x catalyst, having a temperature window for efficient NO x reduction between 350 and 700° C.

Claim 9

The method of claim 7 wherein said catalyst is a high temperature lean-NO x catalyst based on highly acidic gamma alumina.

Claim 10

The method of claim 3 wherein the catalyst bed is divided by two parts and a soot trap is installed between said two parts of catalyst, said trap being capable of collecting carbonaceous particulate matter and withstanding heating above a certain temperature limit, at which the collected carbonaceous particulate matter is burned thereby regenerating said trap.

Claim 11

The method of claim 9 wherein said adding of organic reductant to the trap provides for continuously maintaining said trap above the certain temperature limit, at which the collected carbonaceous particulate matter is burned.

Claim 12

The method of claim 10 wherein said adding of chemical reductant is performed with periodical increase in the amount of reductant added, thereby providing for periodical temperature increase inside said trap above the certain temperature limit at which the collected carbonaceous particulate matter is burned.

Claim 13

The method of claim 10 wherein said soot trap is divided by two parts and additional chemical reductant as hydrocarbons are added to the exhaust gases in the inlet of the catalyst bed and to said two parts of the trap.

Claim 14

A converter for substantially reducing the amount of NO x in exhaust gases from a fossil-fueled engine, using lean-burn combustion, said exhaust gases containing noxious materials including NO x , hydrocarbons, carbon monoxide, carbonaceous particulate matter and mixtures thereof, said converter comprising a container with an inlet and an outlet for the exhaust gases and a catalyst bed, a switching valve for periodically reversing the flow of the exhaust gases through the catalyst bed by reversing the flow between the inlet and the outlet of the container, said catalyst bed having a catalyst which is effective for NO x reduction to N 2 through the reaction of NO x with a chemical reductant, said catalyst being effective with regards to said NO x reduction within a certain temperature window and at a molar ratio between the amounts of chemical reductant and NO x above a certain minimum ratio at which said catalyst is effective with respect to NO x reduction, means for heating up or cooling down the catalyst bed thereby maintaining the temperature inside the catalyst bed within the temperature window at which the catalyst is effective with respect to NO x reduction, a reductant delivery system for adding chemical reductant to the exhaust gases thereby maintaining the ratio between the molar amounts of chemical reductant and NO x above the certain minimum ratio at which said catalyst is effective with respect to NO x reduction, the catalyst bed being divided into two parts and a soot trap is provided between said two parts of catalyst bed, a first catalyst bed on the inlet side of the converter and a second catalyst bed on the outlet side of the converter, said trap being capable of collecting carbonaceous particulate matter and withstanding heating above a certain temperature limit, at which the collected carbonaceous particulate is burned thereby regenerating said trap.

Claim 15

A converter for substantially reducing the amount of NO x in exhaust gases from a fossil-fueled engine, using lean-burn combustion, said exhaust gases containing noxious materials including NO x , hydrocarbons, carbon monoxide, carbonaceous particulate matter and mixtures thereof, said converter comprising a container with an inlet and an outlet for the exhaust gases and a catalyst bed, a switching valve for periodically reversing the flow of the exhaust gases through the catalyst bed by reversing the flow between the inlet and the outlet of the container, said catalyst bed having a catalyst which is effective for NO x reduction to N 2 through the reaction of NO x with a chemical reductant, said catalyst being effective with regards to said NO x reduction within a certain temperature window and at a molar ratio between the amounts of chemical reductant and NO x above a certain minimum ratio at which said catalyst is effective with respect to NO x reduction, means for heating up or cooling down the catalyst bed thereby maintaining the temperature inside the catalyst bed within the temperature window at which the catalyst is effective with respect to NO x reduction, a reductant delivery system for adding chemical reductant to the exhaust gases thereby maintaining the ratio between the molar amounts of chemical reductant and NO x above the certain minimum ratio at which said catalyst is effective with respect to NO x reduction, the catalyst bed being divided into two parts and a soot trap is provided between said two parts of catalyst bed, a first catalyst bed on the inlet side of the converter and a second catalyst bed on the outlet side of the converter, said trap being capable of collecting carbonaceous particulate matter and withstanding heating above a certain temperature limit, at which the collected carbonaceous particulate is burned thereby regenerating said trap.

Claim 16

The converter of claim 13 wherein the reductant delivery system adds chemical reductant to the exhaust gases before or as the exhaust gases flow through the catalyst bed on the side of the converter serving as the inlet as the exhaust gases are reverse flowed through the converter and as the exhaust gases flow through said filter.

Claim 17

A converter for substantially reducing the amount of NO x in exhaust gases from a fossil-fueled engine, using lean-burn combustion, said exhaust gases containing noxious materials including NO x , hydrocarbons, carbon monoxide, carbonaceous particulate matter and mixtures thereof, said converter comprising a container with an inlet and an outlet for the exhaust gases and a catalyst bed, a switching valve for periodically reversing the flow of the exhaust gases through the catalyst bed by reversing the flow between the inlet and the outlet of the container, said catalyst bed having a catalyst which is effective for NO x reduction to N 2 through the reaction of NO x with a chemical reductant, said catalyst being effective with regards to said NO x reduction within a certain temperature window and at a molar ratio between the amounts of chemical reductant and NO x above a certain minimum ratio at which said catalyst is effective with respect to NO x reduction, means for heating up or cooling down the catalyst bed thereby maintaining the temperature inside the catalyst bed within the temperature window at which the catalyst is effective with respect to NO x reduction, a reductant delivery system for adding chemical reductant to the exhaust gases thereby maintaining the ratio between the molar amounts of chemical reductant and NO x above the certain minimum ratio at which said catalyst is effective with respect to NO x reduction, the catalyst bed having a high temperature lean-NO x catalyst bed flanked by soot traps, said traps further flanked by low temperature lean-NO x catalyst beds on the inlet and outlet sides of the converter.

Claim 18

A converter for substantially reducing the amount of NO x in exhaust gases from a fossil-fueled engine, using lean-burn combustion, said exhaust gases containing noxious materials including NO x , hydrocarbons, carbon monoxide, carbonaceous particulate matter and mixtures thereof, said converter comprising a container with an inlet and an outlet for the exhaust gases and a catalyst bed, a switching valve for periodically reversing the flow of the exhaust gases through the catalyst bed by reversing the flow between the inlet and the outlet of the container, said catalyst bed having a catalyst which is effective for NO x reduction to N 2 through the reaction of NO x with a chemical reductant, said catalyst being effective with regards to said NO x reduction within a certain temperature window and at a molar ratio between the amounts of chemical reductant and NO x above a certain minimum ratio at which said catalyst is effective with respect to NO x reduction, means for heating up or cooling down the catalyst bed thereby maintaining the temperature inside the catalyst bed within the temperature window at which the catalyst is effective with respect to NO x reduction, a reductant delivery system for adding chemical reductant to the exhaust gases thereby maintaining the ratio between the molar amounts of chemical reductant and NO x above the certain minimum ratio at which said catalyst is effective with respect to NO x reduction, the catalyst bed having a high temperature lean-NO x catalyst bed flanked by soot traps, said traps further flanked by low temperature lean-NO x catalyst beds on the inlet and outlet sides of the converter.

Claim 19

The converter of claim 15 wherein the reductant delivery system adds chemical reductant to the exhaust gases before or as the exhaust gases flow through any or all of the catalyst beds and soot traps.