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US6277733B1 Expired / Lapsed US ⏱️ 0.0 years remaining

Oxygen-free, dry plasma process for polymer removal

Assignee: Texas Instruments Inc
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Filing: 1999-09-29
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Granted: 2001-08-21
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Expires: 2019-09-29
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Abstract

Abstract An embodiment of the instant invention is a method of fabricating an electronic device formed on a semiconductor wafer, the method comprising the steps of: forming a conductive structure over the substrate, the conductive structure comprised of an oxygen-sensitive conductor; forming a layer of dielectric material over the conductive structure (step 306 of FIG. 1); forming a photoresist layer over the layer of the dielectric material (step 308 of FIG. 1); patterning the layer of the dielectric material (step 308); removing the photoresist layer after patterning the layer of the dielectric material (step 312 of FIG. 1); and subjecting the semiconductor wafer to a plasma which incorporates the combination of hydrogen or deuterium and a fluorine-containing mixture which is comprised of a gas selected from the group consisting of: CF4, C2F6, CHF3, CFH3 and other fluorine-containing hydrocarbon (step 313 of FIG. 1).

Inventors

  • 👤 Patricia B. Smith

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-04 21:36
CPC Classifications
H; H10; H10W; H10W20/00; H10W20/01; H10W20/071; H10W20/081; H10W20/084; H10W20/086; H10P; H10P50/00; H10P50/20; H10P50/28; H10P50/282; H10P50/283; H10P50/286; H10P50/287; H10W20/031; H10P70/00; H10P70/10; H10P70/12

Claims Analysis

Total Claims: 8
Claim 1
Independent Claim 86 words
A method of fabricating an electronic device on a semiconductor substrate, said method comprising the steps of: forming a conductive structure over said substrate, said conductive structure comprised of an oxygen-sensitive conductor capable of being oxidized when contacted by oxygen; forming and patterning a layer of dielectric material over said substrate with said conductive structure exposed; and subjecting said semiconductor substrate with patterned dielectric and exposed conductive structure to the combination of an active oxygen-free, hydrogen, hydrogen-containing, deuterium or deuterium-containing plasma which incorporates a fluorocarbon gas.
Claim 2
Independent Claim 86 words
A method of fabricating an electronic device on a semiconductor substrate, said method comprising the steps of: forming a conductive structure over said substrate, said conductive structure comprised of an oxygen-sensitive conductor capable of being oxidized when contacted by oxygen; forming and patterning a layer of dielectric material over said substrate with said conductive structure exposed; and subjecting said semiconductor substrate with patterned dielectric and exposed conductive structure to the combination of an active oxygen-free, hydrogen, hydrogen-containing, deuterium or deuterium-containing plasma which incorporates a fluorocarbon gas.
Claim 3
Dependent Claim 92 words
The method of claim 1 , wherein said step of patterning of said dielectric layer comprises the steps of forming a photoresist layer over said layer of said dielectric material; patterning said layer of said dielectric material and removing said photoresist layer after patterning said layer of said dielectric material, said step of removing said photoresist layer being performed by subjecting said semiconductor substrate to said plasma which incorporates a gas which includes NH 3 , N 2 H 2 , H 2 S, CH 4 or deuterated forms of these gases.
Claim 4
Dependent Claim 52 words
The method of claim 1 , where said oxygen-sensitive material is comprised of a material selected from the group consisting of: copper, tantalum, tantalum nitride, titanium, titanium nitride, titanium silicide, tungsten, tungsten nitride, tungsten silicide, aluminum, copper-doped aluminum, silver, gold, ruthenium, ruthenium oxide, iridium, platinum, cobalt, cobalt silicide and any combination thereof.
Claim 5
Dependent Claim 20 words
The method of claim 1 , wherein said fluorocarbon gas is from about 2 to about 10% of said combination.
Claim 6
Dependent Claim 16 words
The method of claim 4 , wherein said fluorocarbon gas is about 4% of said combination.
Claim 7
Dependent Claim 26 words
The method of claim 1 , wherein said step of subjecting said semiconductor substrate to a plasma removes any exposed hydrocarbons formed over the semiconductor substrate.
Claim 8
Dependent Claim 25 words
The method of claim 1 , wherein said step of subjecting said semiconductor substrate to a plasma does not substantially remove any exposed nitride-containing structures.

References Cited (Backward Citations)

US6107192A Cited
US5989997A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 2004-08-20 2005-02-19 2005-08-21 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 2008-08-20 2009-02-19 2009-08-21 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2012-08-20 2013-02-19 2013-08-21 $7700.00 Window Closed / Lapsed

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