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US6207783B1 Expired / Lapsed US ⏱️ 0.0 years remaining

Silicone oligomers with higher alkoxy groups

Assignee: General Electric Co
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Filing: 1999-05-18
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Granted: 2001-03-27
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Expires: 2019-05-18
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Abstract

Abstract An oligomer of the formula:whereineach R is selected individually from the group consisting of R1, -OR2 and -OR3;each R1 is independently a substituted or unsubstituted hydrocarbon group; eachR2 is a C1-C6 alkyl group or an acyl group; and each R3 is a independently an alkyl or alkenyl group having at least 8 carbon atoms;with the provisos thatif R3 is alkenyl, there is no unsaturation within two carbon atoms adjacent to the oxygen atom of the -OR3 group; at least one R group is -OR3; at least one quarter of all R groups are -OR2 or -OR3; m=2 to 20; n=0 to 50; o=0 to 20; and p=0 to 10.The oligomer is a useful component of in insulation formulations for wire and cable used in underground locations.

Inventors

  • 👤 Herbert E. Petty
  • 👤 Robert Pickwell

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-08 12:21
CPC Classifications
C; C08; C08G; C08G77/00; C08G77/48; C08G77/485; C08F; C08F290/00; C08F290/08; C08F290/14; C08F290/148; C08G77/04; C08G77/045; C08K; C08K5/00; C08K5/54; C08K5/541; C08K5/5425

Claims Analysis

Total Claims: 4
Claim 1
Independent Claim 198 words
An oligomer of the formula: [R 3 SiO 1/2 ] m [O 1/2 SiR 2 O 1/2 ] n [SiO 3/2 R] o [SiO 4/2 ] p (I) wherein each R is selected individually from the group consisting of R 1 , —OR 2 and —OR 3 ; at least one R 1 is a group of the formula —A—W wherein W is a silyl group and A is a group the respective ends of which are bound by Si—C bonds to the group W and to a silicon atom of the oligomer of formula I; each R 2 is a C 1-6 alkyl group or an acyl group; and each R 3 is independently an alkyl or alkenyl group having at least 8 carbon atoms; with the provisos that is R 3 is alkenyl, there is no unsaturation within the two carbons adjacent to the oxygen atom of the —OR 3 group; at least one R group is —OR 3 ; at least one quarter of all R groups are —OR 2 or —OR 3 ; m is 2 to 20; n is 0 to 50; o is 0 to 20; and p is 0 to 10.
Claim 2
Dependent Claim 198 words
An oligomer of the formula: [R 3 SiO 1/2 ] m [O 1/2 SiR 2 O 1/2 ] n [SiO 3/2 R] o [SiO 4/2 ] p (I) wherein each R is selected individually from the group consisting of R 1 , —OR 2 and —OR 3 ; at least one R 1 is a group of the formula —A—W wherein W is a silyl group and A is a group the respective ends of which are bound by Si—C bonds to the group W and to a silicon atom of the oligomer of formula I; each R 2 is a C 1-6 alkyl group or an acyl group; and each R 3 is independently an alkyl or alkenyl group having at least 8 carbon atoms; with the provisos that is R 3 is alkenyl, there is no unsaturation within the two carbons adjacent to the oxygen atom of the —OR 3 group; at least one R group is —OR 3 ; at least one quarter of all R groups are —OR 2 or —OR 3 ; m is 2 to 20; n is 0 to 50; o is 0 to 20; and p is 0 to 10.
Claim 3
Dependent Claim 184 words
An oligomer of the formula: [R 3 SiO 1/2 ] m [O 1/2 SiR 2 O 1/2 ] n [SiO 3/2 R] o [SiO 4/2 ] p (I) wherein each R is selected individually from the group consisting of R 1 , —OR 2 and —OR 3 ; each R 1 is independently a substituted or unsubstituted hydrocarbon group or olefinic hydrocarbon group; each R 2 is a C 1-6 alkyl group or an acyl group; and each R 3 is independently an alkyl or alkenyl group having at least 8 carbon atoms; with the provisos that if R 3 is alkenyl, there is no unsaturation within two carbon atoms adjacent to the oxygen atom of the —OR 3 group; at least one R group is —OR 3 ; for each terminal or linear repeat unit, if one R group is an R 1 group, the other R groups on said unit are —OR 2 or —OR 3 , or a mixture thereof; m is 2 to 20; n is 0 to 50; o is 0 to 20; and p is 0 to 10.
Claim 4
Dependent Claim 184 words
An oligomer of the formula: [R 3 SiO 1/2 ] m [O 1/2 SiR 2 O 1/2 ] n [SiO 3/2 R] o [SiO 4/2 ] p (I) wherein each R is selected individually from the group consisting of R 1 , —OR 2 and —OR 3 ; each R 1 is independently a substituted or unsubstituted hydrocarbon group or olefinic hydrocarbon group; each R 2 is a C 1-6 alkyl group or an acyl group; and each R 3 is independently an alkyl or alkenyl group having at least 8 carbon atoms; with the provisos that if R 3 is alkenyl, there is no unsaturation within two carbon atoms adjacent to the oxygen atom of the —OR 3 group; at least one R group is —OR 3 ; for each terminal or linear repeat unit, if one R group is an R 1 group, the other R groups on said unit are —OR 2 or —OR 3 , or a mixture thereof; m is 2 to 20; n is 0 to 50; o is 0 to 20; and p is 0 to 10.

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 2004-03-26 2004-09-25 2005-03-27 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 2008-03-26 2008-09-25 2009-03-27 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2012-03-26 2012-09-25 2013-03-27 $7700.00 Window Closed / Lapsed

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