← Back to Patent Explorer
US6183703B1 Expired / Lapsed US ⏱️ 0.0 years remaining

Thermally enhanced compact reformer

Assignee: ZTEK Corp
•
Filing: 1999-01-11
•
Granted: 2001-02-06
•
Expires: 2019-01-11
📄 Original PDF 🌐 Google Patents 🔄 Sync Now

Abstract

Abstract A natural gas reformer comprising a stack of thermally conducting plates interspersed with catalyst plates and provided with internal or external manifolds for reactants. The catalyst plate is in intimate thermal contact with the conducting plates so that its temperature closely tracks the temperature of the thermally conducting plate, which can be designed to attain a near isothermal state in-plane to the plate. One or more catalysts may be used, distributed along the flow direction, in-plane to the thermally conducting plate, in a variety of optional embodiments. The reformer may be operated as a steam reformer or as a partial oxidation reformer. When operated as a steam reformer, thermal energy for the (endothermic) steam reforming reaction is provided externally by radiation and/or conduction to the thermally conducting plates. This produces carbon monoxide, hydrogen, steam and carbon dioxide. When operated as a partial oxidation reformer, a fraction of the natural gas is oxidized assisted by the presence of a combustion catalyst and reforming catalyst. This produces carbon monoxide, hydrogen, steam and carbon dioxide. Because of the intimate thermal contact between the catalyst plate and the conducting plates, no excessive temperature can develop within the stack assembly. Details of the plate design may be varied to accommodate a variety of manifolding embodiments providing one or more inlets and exit ports for introducing, pre-heating and exhaust the reactants.

Inventors

  • 👤 Michael S. Hsu
  • 👤 Ethan D. Hoag

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-07 16:01
CPC Classifications
C; C01; C01B; C01B3/00; C01B3/02; C01B3/32; C01B3/34; C01B3/38; C01B3/382; B; B01; B01D; B01D53/00; B01D53/34; B01D53/74; B01D53/86; B01D53/864; B01D53/8643; B01D53/8646; B01D53/8653; B01J; B01J12/00; B01J12/005; B01J12/007; B01J15/00; B01J15/005; B01J19/00; B01J19/24; B01J19/248; B01J19/249; C01B3/384; C01B3/386; H; H01; H01M; H01M8/00; H01M8/06; H01M8/0606; H01M8/0612; H01M8/0625; H01M8/0631; H01M8/0662; H01M8/24; H01M8/2404; H01M8/241; H01M8/2425; H01M8/2432; H01M8/2465; H01M8/2483; H01M8/2484; B01J2208/00; B01J2208/00008; B01J2208/00017; B01J2208/00106; B01J2208/00309; B01J2208/02; B01J2208/021; B01J2208/022; B01J2219/00; B01J2219/24; B01J2219/2401; B01J2219/245; B01J2219/2451; B01J2219/2453; B01J2219/2456; B01J2219/2458; B01J2219/2461; B01J2219/2465; B01J2219/2467; B01J2219/2476; B01J2219/2477; B01J2219/2479; B01J2219/2482; B01J2219/2483; B01J2219/2485; B01J2219/2487; B01J2219/2491; B01J2219/2492; B01J2219/2493; B01J2219/2498; C01B2203/00; C01B2203/02; C01B2203/0205; C01B2203/0227; C01B2203/0233; C01B2203/0238; C01B2203/0244; C01B2203/025; C01B2203/0261; C01B2203/0283; C01B2203/06; C01B2203/066; C01B2203/08; C01B2203/0805; C01B2203/0811; C01B2203/0833; C01B2203/0838; C01B2203/0844; C01B2203/0866; C01B2203/10; C01B2203/1005; C01B2203/1035; C01B2203/1041; C01B2203/12; C01B2203/1205; C01B2203/1211; C01B2203/1235; C01B2203/1241; C01B2203/1276; C01B2203/14; C01B2203/142; C01B2203/80; C01B2203/82; H01M8/10; H01M8/12; H01M2008/1293; H01M2300/00; H01M2300/0017; H01M2300/0065; H01M2300/0068; H01M2300/0071; H01M2300/0074; H01M2300/0077; H01M8/04; H01M8/04007; H01M8/04014; H01M8/04022; H01M8/0618; Y; Y02; Y02E; Y02E60/00; Y02E60/30; Y02E60/50; Y02P; Y02P20/00; Y02P20/10; Y02P20/129; Y02P20/50; Y02P20/52

Claims Analysis

Total Claims: 72
Claim 1
Independent Claim 92 words
A method for reforming a reactant into reaction species with a plate-type reformer, comprising the steps of providing a plurality of catalyst plates having associated therewith one or more catalyst materials for promoting reformation, providing a plurality of conductive plates formed of a thermally conducting material, stacking said catalyst plates and said conductive plates to form a plate-type reforming structure, conductively transferring heat energy in-plane across a surface of the conductive plate to support the reforming process, and reforming the reactant into the reaction species when passing through the platetype reforming structure.
Claim 2
Independent Claim 92 words
A method for reforming a reactant into reaction species with a plate-type reformer, comprising the steps of providing a plurality of catalyst plates having associated therewith one or more catalyst materials for promoting reformation, providing a plurality of conductive plates formed of a thermally conducting material, stacking said catalyst plates and said conductive plates to form a plate-type reforming structure, conductively transferring heat energy in-plane across a surface of the conductive plate to support the reforming process, and reforming the reactant into the reaction species when passing through the platetype reforming structure.
Claim 3
Dependent Claim 39 words
The method of claim 1 , further comprising the step of performing one or more reforming reactions including a catalytically assisted chemical reaction between two or more reaction species, and a catalytically assisted thermal dissociation of a single species.
Claim 4
Dependent Claim 45 words
The method of claim 1 , further comprising the steps of introducing the reactant through at least one axial manifold in said reforming structure, and forming at least one manifold in said reforming structure for allowing the reaction species to exit from the reforming structure.
Claim 5
Dependent Claim 34 words
The method of claim 1 , further comprising the step of exposing a substantial portion of the peripheral surface of the reforming structure to allow the exchange of heat energy with an external environment.
Claim 6
Dependent Claim 39 words
The method of claim 1 , further comprising the steps of forming one or more axial reactant manifolds in said reforming structure for introducing the reactant thereto, and exhausting reaction species from a peripheral portion of the reforming structure.
Claim 7
Dependent Claim 49 words
The method of claim 1 , further comprising the steps of disposing a thermally conductive, gas-tight housing about the reforming structure to form a peripheral axial manifold to allow pressurized reformer operation, introducing reaction species into the peripheral axial manifold, and capturing said reaction species with said gas-tight housing.
Claim 8
Dependent Claim 40 words
The method of claim 1 , further comprising the steps of disposing a thermally conductive, gas-tight housing about said reforming structure, and exchanging heat energy between the external environment and said conductive plate by one of radiation, conduction and convection.
Claim 9
Dependent Claim 52 words
The method of claim 1 , further comprising the steps of disposing a thermally conductive, gas-tight housing about said reforming structure, placing in contact an outer surface of the reforming structure with an inner surface of said gas-tight housing, and conductively transferring heat energy from said gas-tight housing to the conductive plates.
Claim 10
Dependent Claim 22 words
The method of claim 1 , further comprising the step of forming a generally isothermal condition, in plane of the conductive plate.
Claim 11
Dependent Claim 24 words
The method of claim 1 , further comprising the step of forming a generally isothermal condition along an elongated axis of the reforming structure.
Claim 12
Dependent Claim 61 words
The method of claim 1 , further comprising the steps of forming at least one axial reactant manifold in said reforming structure for introducing a reactant thereto, providing an integrally formed lip structure on an outer end or an inner end of the conductive plate, and preheating an incoming reactant with said lip structure when extending into the axial reactant manifold.
Claim 13
Dependent Claim 42 words
The method of claim 1 , further comprising the step of forming a passage in an in-plane surface of at least one of the conductive plate and the catalyst plate for allowing the reactant to flow over the surface of the plate.
Claim 14
Dependent Claim 61 words
The method of claim 1 , further comprising the steps of forming an axial manifold within the reforming structure, forming passages between the conductive plate and the catalyst plate, and generating a reactant flow pressure drop through the passages between the conductive plate and the catalyst plate that is substantially greater than a reactant flow pressure drop within the axial manifold.
Claim 15
Dependent Claim 63 words
The method of claim 1 , further comprising the steps of forming passages between the catalyst plate and the conductive plate for allowing an incoming reactant to pass over a surface of one of the plates, and maintaining a substantially uniform pressure drop within the reforming structure to provide for a substantially uniform flow of reactants along an axis of the reforming structure.
Claim 16
Dependent Claim 24 words
The method of claim 1 , further comprising the step of producing a substantially uniform temperature condition along an axis of the reforming structure.
Claim 17
Dependent Claim 49 words
The method of claim 1 , further comprising the step of forming the catalyst plate and of a porous catalyst material or the conductive plate of a porous conductive material to form passages therein to allow an incoming reactant to pass through at least a portion of the plate.
Claim 18
Dependent Claim 30 words
The method of claim 1 , further comprising the step of forming the conductive plate of at least one of a nonmetal such as silicon carbide, and a composite material.
Claim 19
Dependent Claim 40 words
The method of claim 1 , further comprising the step of forming the conductive plate of at least one metal such as aluminum, copper, iron, steel alloys, nickel, nickel alloys, chromium, chromium alloys, platinum, platinum alloys and other refractory metals.
Claim 20
Dependent Claim 27 words
The method of claim 1 , further comprising the step of forming the catalyst plate of a ceramic or metallic support plate having the catalyst material coating.
Claim 21
Dependent Claim 51 words
The method of claim 1 , further comprising the step of selecting the catalyst material from the group consisting of platinum, palladium, nickel, nickel oxide, iron, iron oxide, chromium, chromium oxide, cobalt, cobalt oxide, copper, copper oxide, zinc, zinc oxide, molybdenum, molybdenum oxide, and other suitable transition metals and their oxides.
Claim 22
Dependent Claim 28 words
The method of claim 1 , further comprising the step of forming the catalyst plate of at least one of platinum, nickel, nickel oxide, chromium and chromium oxide.
Claim 23
Dependent Claim 86 words
The method of claim 1 , further comprising the step of forming the reactant from at least one of an alkane such as a paraffin hydrocarbon, a hydroxyl such as a hydrocarbon bonded with alcohols, a hydrocarbon bonded with a carboxyl, a hydrocarbon bonded with a carbonyl, an alkene such as an olifin hydrocarbon, a hydrocarbon bonded with an ether, a hydrocarbon bonded with an ester, a hydrocarbon bonded with an amine, a hydrocarbon bonded with an aromatic derivative, and a hydrocarbon bonded with another organo-derivative.
Claim 24
Dependent Claim 23 words
The method of claim 1 , further comprising the step of coupling reaction species exiting the reforming structure to an external fuel cell.
Claim 25
Dependent Claim 99 words
The method of claim 1 , further comprising the steps of providing a hydrocarbon fuel as a fuel reactant and at least one of H 2 O and CO 2 , and performing on the hydrocarbon fuel and at least said one of H 2 O and CO 2 an endothermic catalytic reformation to produce H 2 , CO, H 2 O and CO 2 , the energy requirements for the endothermic reforming being supplied by energy produced by an external fuel cell, said energy being transferred from the fuel cell by the conducting plate through in-plane thermal conduction.
Claim 26
Dependent Claim 93 words
The method of claim 1 , further comprising the steps of providing a hydrocarbon fuel as a fuel reactant and at least one of H 2 O and CO 2 , and performing on the hydrocarbon fuel and O 2 a catalytic combustion and reformation processes to produce H 2 , CO, H 2 O and CO 2 , and at least one of an exothermic combustion and an exothermic reaction of an external fuel cell supplementing the energy requirements for the endothermic reforming through the in-plane thermal conduction of the conducting plate.
Claim 27
Dependent Claim 54 words
The method of claim 1 , further comprising the steps of forming the reforming structure in a cylindrical shape, and providing at least one of the catalyst plate and the conductive plate of a diameter between about 1 inch and about 20 inches, and a thickness between about 0.002 inch and about 0.2 inch.
Claim 28
Dependent Claim 31 words
The method of claim 1 , further comprising the step of only conducting heat with said conductive plates in the in-plane direction from one end region of the surface to another.
Claim 29
Dependent Claim 45 words
The method of claim 1 , further comprising the step of forming the catalyst plate to have a plurality of zones spaced along a surface of the plate for effecting selected reactions, said zones including a combustion zone, a reforming zone, and an electrochemical zone.
Claim 30
Dependent Claim 29 words
The method of claim 1 , further comprising the step of forming with said conductive plate a near isothermal temperature condition in-pane of said catalyst and said conductive plates.
Claim 31
Dependent Claim 58 words
The method of claim 1 , further comprising the steps of configuring said reforming structure to extend, in one orientation, along a vertical axis, and configuring said reforming structure to include at least one vertically-extending axial manifold for introducing the reactant thereto and at least one manifold for allowing the reaction species to exit from the reforming structure.
Claim 32
Dependent Claim 49 words
The method of claim 1 , further comprising the steps of exhausting the reaction species from a peripheral portion of the reforming structure, and disposing a thermally conductive, gas-tight housing about the stacked reforming structure to capture the reaction species exhausted by said reforming structure through said peripheral portion.
Claim 33
Dependent Claim 29 words
The method of claim 31 , further comprising the steps of allowing the reaction species to enter the gas-tight housing, and capturing the reaction species with the gas-tight housing.
Claim 34
Independent Claim 100 words
A method for reforming a reactant into reaction species with a plate-type reformer during operation, said method comprising the steps of providing a plurality of plates at least one of said plurality of said plates being composed of a thermally conductive material interspersed throughout a thickness of the plate with one or more catalyst materials for promoting the reforming process, stacking said plates being together to form a reforming structure, conductively transferring heat energy in-plane, across a surface of the plates, to support the reforming process, and reforming the reactant into the reaction species when passing through the reforming structure.
Claim 35
Independent Claim 100 words
A method for reforming a reactant into reaction species with a plate-type reformer during operation, said method comprising the steps of providing a plurality of plates at least one of said plurality of said plates being composed of a thermally conductive material interspersed throughout a thickness of the plate with one or more catalyst materials for promoting the reforming process, stacking said plates being together to form a reforming structure, conductively transferring heat energy in-plane, across a surface of the plates, to support the reforming process, and reforming the reactant into the reaction species when passing through the reforming structure.
Claim 36
Dependent Claim 46 words
The method of claim 33 , further comprising the steps of introducing the reactant through at least one axial manifold formed in said reforming structure, and forming at least one manifold in said reforming structure for allowing the reaction species to exit from the reforming structure.
Claim 37
Dependent Claim 34 words
The method of claim 33 , further comprising the step of exposing a substantial portion of a peripheral surface of the reforming structure to allow the exchange of heat energy with an external environment.
Claim 38
Dependent Claim 39 words
The method of claim 33 , further comprising the steps of forming one or more axial reactant manifolds in said reforming structure for introducing the reactant thereto, and exhausting reaction species from a peripheral portion of the reforming structure.
Claim 39
Dependent Claim 49 words
The method of claim 33 , further comprising the steps of disposing a thermally conductive, gas-tight housing about the reforming structure to form a peripheral axial manifold to allow pressurized reformer operation, introducing reaction species into the peripheral axial manifold, and capturing said reaction species with said gas-tight housing.
Claim 40
Dependent Claim 40 words
The method of claim 33 , further comprising the steps of disposing a thermally conductive, gas-tight housing about said reforming structure, and exchanging heat energy between the external environment and said reforming structure by one of radiation, conduction and convection.
Claim 41
Dependent Claim 52 words
The method of claim 33 , further comprising the steps of disposing a thermally conductive, gas-tight housing about said reforming structure, placing in contact an outer surface of the reforming structure with an inner surface of said gas-tight housing, and conductively transferring heat energy from said gas-tight housing to the reforming structure.
Claim 42
Dependent Claim 31 words
The method of claim 33 , further comprising the step of forming a generally isothermal condition, in plane of the conductive plate, or along an elongated axis of the reforming structure.
Claim 43
Dependent Claim 57 words
The method of claim 33 , further comprising the steps of forming at least one axial reactant manifold in said reforming structure for introducing a reactant thereto, providing an extension on an outer end or an inner end of the conductive plate, and preheating an incoming reactant with said extension when extending into the axial reactant manifold.
Claim 44
Dependent Claim 32 words
The method of claim 33 , further comprising the step of forming a passage in said reforming structure for allowing the reactant to flow over the surface of one of said plates.
Claim 45
Dependent Claim 60 words
The method of claim 33 , further comprising the steps of forming an axial manifold within the reforming structure, forming passages in said reforming structure for allowing a reactant to flow inplane of the reforming structure, and generating a reactant flow pressure drop through the passages that is substantially greater than a reactant flow pressure drop within the axial manifold.
Claim 46
Dependent Claim 72 words
The method of claim 43 , further comprising the step of allowing the hydrocarbon fuel and at least one of H 2 O and CO 2 to undergo a catalytic reformation to produce H 2 , CO, H 2 O and CO 2 , and wherein an exothermic reaction of an external fuel cell supplements the energy requirements for the endothermic reforming reaction of the reforming structure through the thermally conductive material.
Claim 47
Dependent Claim 72 words
The method of claim 43 , further comprising the step of allowing the hydrocarbon fuel and O 2 to undergo catalytic combustion and reformation to produce H 2 , CO, H 2 O and CO 2 , and at least one of an exothermic combustion and an exothermic reaction of an external fuel cell supplements the energy requirements for the endothermic reforming reaction of the reforming structure through the thermally conductive material.
Claim 48
Dependent Claim 66 words
The method of claim 33 , further comprising the steps of forming passages between the catalyst plate and the conductive plate for allowing an incoming reactant to pass over a surface of one of the plates, and maintaining a substantially uniform pressure drop within the reforming structure with said passages to provide for a substantially uniform flow of reactants along an axis of the reforming structure.
Claim 49
Dependent Claim 30 words
The method of claim 33 , further comprising the step of forming the conductive plate of at least one of a nonmetal such as silicon carbide, and a composite material.
Claim 50
Dependent Claim 37 words
The method of claim 33 , further comprising the step of forming the conductive plate of at least one metal such as aluminum, copper, iron, steel alloys, nickel, nickel alloys, chromium, chromium alloys, platinum, and platinum alloys.
Claim 51
Dependent Claim 51 words
The method of claim 33 , further comprising the step of selecting the catalyst material from the group consisting of platinum, palladium, nickel, nickel oxide, iron, iron oxide, chromium, chromium oxide, cobalt, cobalt oxide, copper, copper oxide, zinc, zinc oxide, molybdenum, molybdenum oxide, and other suitable transition metals and their oxides.
Claim 52
Dependent Claim 50 words
The method of claim 33 , further comprising the step of selecting the catalyst a material from a group consisting of platinum, palladium, nickel, nickel oxide, iron, iron oxide, chromium, chromium oxide, cobalt, cobalt oxide, copper, copper oxide, zinc, zinc oxide, molybdenum, molybdenum oxide, other transition metals and their oxides.
Claim 53
Dependent Claim 33 words
The method of claim 33 , further comprising the step of providing as the reactant a hydrocarbon species and at least one of O 2 , H 2 O and CO 2 .
Claim 54
Dependent Claim 23 words
The method of claim 33 , further comprising the step of coupling the reaction species exiting the reformer to an external fuel cell.
Claim 55
Dependent Claim 31 words
The method of claim 33 , further comprising the step of configuring the reforming structure to have a cylindrical shape and a diameter between about 1 inch and about 20 inches.
Claim 56
Dependent Claim 31 words
The method of claim 33 , further comprising the step of only conducting heat with said conductive plates in the in-plane direction from one end region of the surface to another.
Claim 57
Dependent Claim 29 words
The method of claim 33 , further comprising the step of forming with said conductive plate a near isothermal temperature condition in-pane of said catalyst and said conductive plates.
Claim 58
Independent Claim 117 words
A method for reforming a reactant into reaction species, comprising the steps of providing a plurality of catalyst plates having one or more zones spaced along a surface of at least one of said plurality of catalyst plates for effecting selected reactions, said zones including at least one of a combustion zone, a reforming zone, and an electrochemical zone, providing a plurality of conductive plates formed of a thermally conducting material, stacking said catalyst plates and said conductive plates to form a plate-type reforming structure, conductively transferring heat energy in-plane across a surface of the conductive plate to support the reforming process, and reforming the reactant into the reaction species when passing through the plate-type returning structure.
Claim 59
Independent Claim 117 words
A method for reforming a reactant into reaction species, comprising the steps of providing a plurality of catalyst plates having one or more zones spaced along a surface of at least one of said plurality of catalyst plates for effecting selected reactions, said zones including at least one of a combustion zone, a reforming zone, and an electrochemical zone, providing a plurality of conductive plates formed of a thermally conducting material, stacking said catalyst plates and said conductive plates to form a plate-type reforming structure, conductively transferring heat energy in-plane across a surface of the conductive plate to support the reforming process, and reforming the reactant into the reaction species when passing through the plate-type returning structure.
Claim 60
Dependent Claim 54 words
The method of claim 56 , further comprising the steps of providing steam as part of the reactant, providing a steam reforming catalyst in said reforming zone, and providing heat for the reforming zone to support the reformation process by the conductively transferred heat energy flowing in-plane across the surface of the conductive plate.
Claim 61
Dependent Claim 28 words
The method of claim 56 , further comprising the step of forming said zones into bands that are spaced from each other across the surface of the plate.
Claim 62
Dependent Claim 70 words
The method of claim 56 , further comprising the step of configuring the catalyst plate into a cylindrical shape, disposing the combustion zone at an outermost region of the cylindrical plate relative to the fuel flow, disposing the reforming zone at an intermediate region of the cylindrical plate relative to the fuel flow, and disposing the electrochemical zone at an innermost region of the plate relative to the fuel flow.
Claim 63
Dependent Claim 37 words
The method of claim 56 , further comprising the steps of first passing a fuel reactant over the combustion zone, then passing the reactant over the reforming zone, and finally passing the reactant over the electrochemical zone.
Claim 64
Dependent Claim 71 words
The method of claim 56 , further comprising the steps of providing oxygen as part of the reactant, providing a combustion catalyst in said combustion zone, providing a steam reforming catalyst in said reforming zone, and providing heat for the reforming zone to support the reformation process from the combustion zone to the reformation zone by the conductive transfer of heat energy flowing in-plane across the surface of the conductive plate.
Claim 65
Dependent Claim 34 words
The method of claim 56 , further comprising the step of exposing a substantial portion of the peripheral surface of the reforming structure to allow the exchange of heat energy with an external environment.
Claim 66
Dependent Claim 39 words
The method of claim 56 , further comprising the steps of forming one or more axial reactant manifolds in said reforming structure for introducing the reactant thereto, and exhausting reaction species from a peripheral portion of the reforming structure.
Claim 67
Dependent Claim 49 words
The method of claim 56 , further comprising the steps of disposing a thermally conductive, gas-tight housing about the reforming structure to form a peripheral axial manifold to allow pressurized reformer operation, introducing reaction species into the peripheral axial manifold, and capturing said reaction species with said gas-tight housing.
Claim 68
Dependent Claim 28 words
The method of claim 56 , further comprising the step of forming a generally isothermal condition, in plane of the reforming structure with said conductive plate during use.
Claim 69
Dependent Claim 30 words
The method of claim 56 , further comprising the step of forming a generally isothermal condition along an elongated axis of the reforming structure with said conductive plate during use.
Claim 70
Dependent Claim 61 words
The method of claim 56 , further comprising the steps of forming at least one axial reactant manifold in said reforming structure for introducing a reactant thereto, providing an integrally formed lip structure on an outer end or an inner end of the conductive plate, and preheating an incoming reactant with said lip structure when extending into the axial reactant manifold.
Claim 71
Independent Claim 54 words
A method for reforming a reactant into reaction species, comprising the steps of providing a plate-type reformer having stacked catalyst and conductive plates, conductively transferring heat energy in-plane across a surface of the conductive plate to support the reforming process, and reforming the reactants into the reaction species when passing through the platetype reformer.
Claim 72
Independent Claim 54 words
A method for reforming a reactant into reaction species, comprising the steps of providing a plate-type reformer having stacked catalyst and conductive plates, conductively transferring heat energy in-plane across a surface of the conductive plate to support the reforming process, and reforming the reactants into the reaction species when passing through the platetype reformer.

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 2004-02-06 2004-08-07 2005-02-06 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 2008-02-06 2008-08-07 2009-02-06 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2012-02-06 2012-08-07 2013-02-06 $7700.00 Window Closed / Lapsed

Assigned Categories & Tags

No categories assigned to this patent yet.

Assign Category Tag