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US6133086A
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Fabrication method of a tantalum pentoxide dielectric layer for a DRAM capacitor
Assignee: United Microelectronics Corp
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Filing: 1999-06-24
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Granted: 2000-10-17
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Expires: 2019-06-24
Abstract
Abstract A method of fabricating a dielectric layer for a dynamic random access memory capacitor is described in which a tantalum pentoxide layer is deposited on the polysilicon storage electrode, followed by a two-step treatment on the tantalum pentoxide layer. The first treatment step includes a remote oxygen plasma or an ultraviolet-ozone treatment, followed by a spike annealing second treatment step.
Inventors
- 👤 Kuo-Tai Huang
- 👤 Tri-Rung Yew
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-09 01:07
CPC Classifications
H; H10; H10P; H10P14/00; H10P14/60; H10P14/65; H10P14/6516; H10P14/6529; H10P14/6532; H10P14/6536; H10P14/6538; H10P14/6544; H10D; H10D1/00; H10D1/60; H10D1/68; H10P14/63; H10P14/6326; H10P14/6328; H10P14/6334; H10P14/69; H10P14/692; H10P14/6938; H10P14/6939; H10P14/69393
Claims Analysis
Total Claims: 14
Claim 1
Independent Claim
115 words
A fabrication method of a dielectric layer for a dynamic random access memory capacitor, comprising the steps of: providing a substrate with a polysilicon storage electrode formed on the substrate; covering the polysilicon storage electrode with a tantalum pentoxide dielectric layer; conducting a remote oxygen plasma treatment on the tantalum pentoxide dielectric layer; and conducting a spike annealing process on the tantalum pentoxide dielectric layer after the remote oxygen plasma treatment is conducted, wherein the spike annealing process is conducted at a higher temperature than the remote oxygen plasma treatment, and a duration of the spike annealing process is short enough to substantially eliminate oxide layer formation on the polysilicon storage electrode of the capacitor.
Claim 2
Dependent Claim
115 words
A fabrication method of a dielectric layer for a dynamic random access memory capacitor, comprising the steps of: providing a substrate with a polysilicon storage electrode formed on the substrate; covering the polysilicon storage electrode with a tantalum pentoxide dielectric layer; conducting a remote oxygen plasma treatment on the tantalum pentoxide dielectric layer; and conducting a spike annealing process on the tantalum pentoxide dielectric layer after the remote oxygen plasma treatment is conducted, wherein the spike annealing process is conducted at a higher temperature than the remote oxygen plasma treatment, and a duration of the spike annealing process is short enough to substantially eliminate oxide layer formation on the polysilicon storage electrode of the capacitor.
Claim 3
Dependent Claim
31 words
The fabrication method of a dielectric layer for a dynamic random access memory capacitor according to claim 1, wherein the tantalum pentoxide layer is formed by methods including chemical vapor deposition.
Claim 4
Dependent Claim
38 words
The fabrication method of a dielectric layer for a dynamic random access memory capacitor according to claim 1, wherein the remote oxygen plasma treatment is conducted at approximately 350 to 500° C. for about 30 to 120 seconds.
Claim 5
Dependent Claim
53 words
The fabrication method of a dielectric layer for a dynamic random access memory capacitor according to claim 1, wherein the spike annealing process is conducted at about 1000 to 2000° C. for approximately 1 to 2 seconds, and the temperature is ramped at a rate of approximately 50 to 250° C. per second.
Claim 6
Dependent Claim
29 words
The fabrication method of a dielectric layer for a dynamic random access memory capacitor according to claim 4, wherein the spike annealing process is conducted in an oxygen atmosphere.
Claim 7
Dependent Claim
30 words
The fabrication method of a dielectric layer for a dynamic random access memory capacitor according to claim 4, wherein the spike annealing process is conducted in a nitrous oxide atmosphere.
Claim 8
Dependent Claim
111 words
A fabrication method of a dielectric layer of a dynamic random access memory capacitor, comprising the steps of: providing a substrate with a polysilicon storage electrode formed on the substrate; covering the polysilicon storage electrode with a tantalum pentoxide dielectric layer; conducting an ultraviolet light-ozone treatment on the tantalum pentoxide dielectric layer; and conducting a spike anneal treatment on the tantalum pentoxide dielectric layer after the ultraviolet-ozone treatment is conducted, wherein the spike annealing process is conducted at a higher temperature than the ultraviolet light-ozone treatment, and a duration of the spike annealing process is short enough to substantially eliminate oxide layer formation on the polysilicon storage electrode of the capacitor.
Claim 9
Dependent Claim
111 words
A fabrication method of a dielectric layer of a dynamic random access memory capacitor, comprising the steps of: providing a substrate with a polysilicon storage electrode formed on the substrate; covering the polysilicon storage electrode with a tantalum pentoxide dielectric layer; conducting an ultraviolet light-ozone treatment on the tantalum pentoxide dielectric layer; and conducting a spike anneal treatment on the tantalum pentoxide dielectric layer after the ultraviolet-ozone treatment is conducted, wherein the spike annealing process is conducted at a higher temperature than the ultraviolet light-ozone treatment, and a duration of the spike annealing process is short enough to substantially eliminate oxide layer formation on the polysilicon storage electrode of the capacitor.
Claim 10
Dependent Claim
32 words
The fabrication method of a dielectric layer of a dynamic random access memory capacitor according to claim 7, wherein the tantalum pentoxide dielectric layer is formed by methods including chemical vapor deposition.
Claim 11
Dependent Claim
32 words
The fabrication method of a dielectric layer for a dynamic random access memory capacitor according to claim 7, wherein the ultraviolet light-ozone treatment process is conducted at approximately 300 to 450° C.
Claim 12
Dependent Claim
56 words
The fabrication method of a dielectric layer for a dynamic random access memory capacitor according to claim 7, wherein the spike annealing process is conducted at a temperature of about 1000 to 2000° C. for approximately 1 to 2 seconds, and the temperature is ramped at a rate of approximately 50 to 250° C. per second.
Claim 13
Dependent Claim
29 words
The fabrication method of a dielectric layer for a dynamic random access memory capacitor according to claim 10, wherein the spike annealing process is conducted in an oxygen environment.
Claim 14
Dependent Claim
30 words
The fabrication method of a dielectric layer of a dynamic random access memory capacitor according to claim 7, wherein the spike annealing process is conducted in a nitrous oxide environment.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 2003-10-17 | 2004-04-17 | 2004-10-17 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 2007-10-17 | 2008-04-17 | 2008-10-17 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 2011-10-17 | 2012-04-17 | 2012-10-17 | $7700.00 | Window Closed / Lapsed |