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US6030901A Expired / Lapsed US ⏱️ 0.0 years remaining

Photoresist stripping without degrading low dielectric constant materials

Assignee: Advanced Micro Devices Inc
•
Filing: 1999-06-24
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Granted: 2000-02-29
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Expires: 2019-06-24
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Abstract

Abstract Photoresist masks are stripped using a H 2 -N 2 plasma to prevent increasing the dielectric constant of an exposed carbon-containing dielectric material. Embodiments of the present invention include forming a low dielectric constant, carbon-containing layer, e.g., a polymeric layer, on an exposed metal feature overlying a wafer, forming a photoresist mask on the dielectric layer, forming an opening in the dielectric layer exposing the metal feature and a portion of the dielectric layer, preheating the wafer and stripping the photoresist mask using the H 2 -N 2 plasma.

Inventors

  • 👤 Dawn Hopper
  • 👤 Richard J. Huang
  • 👤 Jacques Bertrand
  • 👤 Lu You

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-02 19:18
CPC Classifications
H; H10; H10P; H10P50/00; H10P50/20; H10P50/28; H10P50/286; H10P50/287; H10P50/282; H10P50/283; H10P14/00; H10P14/60; H10P14/68; H10P14/683; H10P14/69; H10P14/692; H10P14/6921; H10P14/6922; H10P14/6926; H10W; H10W20/00; H10W20/01; H10W20/071; H10W20/081; H10W20/084

Claims Analysis

Total Claims: 20
Claim 1
Independent Claim 64 words
A method of manufacturing a semiconductor device, the method comprising: depositing a carbon-containing dielectric layer; forming a photoresist mask on the carbon-containing dielectric layer; forming an opening in the carbon-containing layer; and removing the photoresist mask with a plasma containing hydrogen and nitrogen, wherein said plasma contains about 1 to about 10 vol % hydrogen and about 90 to about 99 vol % nitrogen.
Claim 2
Independent Claim 64 words
A method of manufacturing a semiconductor device, the method comprising: depositing a carbon-containing dielectric layer; forming a photoresist mask on the carbon-containing dielectric layer; forming an opening in the carbon-containing layer; and removing the photoresist mask with a plasma containing hydrogen and nitrogen, wherein said plasma contains about 1 to about 10 vol % hydrogen and about 90 to about 99 vol % nitrogen.
Claim 3
Dependent Claim 15 words
The method according to claim 1, wherein the carbon-containing dielectric layer is an inter-layer dielectric.
Claim 4
Dependent Claim 21 words
The method according to claim 1, wherein the carbon-containing dielectric layer has a dielectric constant of about 2.0 to about 3.8.
Claim 5
Dependent Claim 20 words
The method according to claim 1, wherein the carbon-containing dielectric layer comprises a polymer having a back bone containing carbon.
Claim 6
Dependent Claim 18 words
The method according to claim 4, wherein the carbon-containing dielectric layer comprises benzocyclobutene (BCB) or methyl silsesquioxane (MSQ).
Claim 7
Dependent Claim 18 words
The method according to claim 1, wherein the plasma contains about 2 to about 6 vol. % hydrogen.
Claim 8
Dependent Claim 32 words
The method according to claim 1, comprising removing the photoresist mask with the plasma at a temperature of about 250° C. at a pressure of about 1,000 to about 1,400 m Torr.
Claim 9
Dependent Claim 30 words
The method according to claim 7, comprising: depositing the carbon-containing dielectric layer overlying a wafer; and preheating the wafer to a temperature of about 150° C. to about 275° C.
Claim 10
Dependent Claim 21 words
The method according to claim 8, comprising preheating the wafer to a temperature of about 230° C. to about 270° C.
Claim 11
Dependent Claim 21 words
The method according to claim 9, comprising preheating the wafer to about 250° C. in about 5 to about 7 seconds.
Claim 12
Dependent Claim 21 words
The method according to claim 8, comprising preheating the wafer by placing the wafer on a platen and heating the platen.
Claim 13
Dependent Claim 19 words
The method according to claim 11, further comprising preheating the wafer by heating the platen and by infrared radiation.
Claim 14
Dependent Claim 15 words
The method according to claim 12, comprising maintaining heating of the wafer during photoresist removal.
Claim 15
Dependent Claim 25 words
The method according to claim 7, comprising removing the photoresist mask at a removal rate of about 3,000 Å to about 4,000 Å per minute.
Claim 16
Dependent Claim 41 words
The method according to claim 1, comprising: forming a patterned metal layer comprising a metal feature; depositing an inter-layer dielectric comprising the carbon-containing dielectric material on the metal feature; and forming the opening in the inter-layer dielectric exposing the metal feature.
Claim 17
Dependent Claim 19 words
The method according to claim 15, wherein the dielectric layer comprises about 0.5 to about 8 mol percent carbon.
Claim 18
Dependent Claim 33 words
The method according to claim 15, comprising removing the photoresist mask in the plasma containing nitrogen and hydrogen avoiding an increase in the dielectric constant and/or removing any of the carbon-containing dielectric layer.
Claim 19
Independent Claim 46 words
A method of manufacturing a semiconductor device, the method comprising: depositing a carbon-containing dielectric layer; forming a photo resist mask on the carbon-containing dielectric layer; forming an opening in the carbon-containing layer; and removing the photo resist mask with a plasma consisting of hydrogen and nitrogen.
Claim 20
Independent Claim 46 words
A method of manufacturing a semiconductor device, the method comprising: depositing a carbon-containing dielectric layer; forming a photo resist mask on the carbon-containing dielectric layer; forming an opening in the carbon-containing layer; and removing the photo resist mask with a plasma consisting of hydrogen and nitrogen.

References Cited (Backward Citations)

US3930913A Cited
US4357203A Cited
US5413963A Cited
US5882489A Cited
US5958798A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 2003-02-28 2003-08-30 2004-02-29 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 2007-02-28 2007-08-30 2008-02-29 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2011-02-28 2011-08-30 2012-02-29 $7700.00 Window Closed / Lapsed

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