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US6004878A Expired / Lapsed US ⏱️ 0.0 years remaining

Method for silicide stringer removal in the fabrication of semiconductor integrated circuits

Assignee: National Semiconductor Corp
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Filing: 1998-02-12
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Granted: 1999-12-21
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Expires: 2018-02-12
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Abstract

Abstract Sidewall spacers, adjacent a gate electrode and source/drain regions of a MOS transistor are formed of a dielectric material that can be etched selectively to the material selected as the isolation dielectric. A layer of silicide forming metal is deposited overlying the MOS transistor and heated, wherein silicide regions are formed where the metal makes contact with silicon, for example, in the gate electrode and source/drain regions. At least a portion of the sidewall spacers are etched-away and silicide stringers, if formed on the spacers, are removed.

Inventors

  • 👤 Michael E. Thomas
  • 👤 Brian J. Daniels

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-29 12:04
CPC Classifications
H; H10; H10D; H10D30/00; H10D30/01; H10D30/021; H10D30/0223; H10D30/0212

Claims Analysis

Total Claims: 20
Claim 1
Independent Claim 138 words
A method of forming a MOS integrated circuit, comprising the steps of: providing a gate electrode structure; forming a sidewall spacer adjacent each opposite sidewall of said gate electrode structure, said sidewall spacer being formed of a material selected from the group consisting of silicon oxide, phosphorus doped silicon oxide and silicon nitride, each spacer overlying a portion of a source region or a drain region proximate said gate electrode structure; depositing a metal layer overlying exposed portions of said gate electrode structure, source and drain regions and sidewall spacers, wherein said metal layer is a silicide forming material; forming metal silicide regions coincident to said exposed portions of said source and drain regions; removing unreacted metal of said metal layer; and etching said sidewall spacers, wherein at least a portion of said sidewall spacers is etched away.
Claim 2
Independent Claim 138 words
A method of forming a MOS integrated circuit, comprising the steps of: providing a gate electrode structure; forming a sidewall spacer adjacent each opposite sidewall of said gate electrode structure, said sidewall spacer being formed of a material selected from the group consisting of silicon oxide, phosphorus doped silicon oxide and silicon nitride, each spacer overlying a portion of a source region or a drain region proximate said gate electrode structure; depositing a metal layer overlying exposed portions of said gate electrode structure, source and drain regions and sidewall spacers, wherein said metal layer is a silicide forming material; forming metal silicide regions coincident to said exposed portions of said source and drain regions; removing unreacted metal of said metal layer; and etching said sidewall spacers, wherein at least a portion of said sidewall spacers is etched away.
Claim 3
Dependent Claim 21 words
The method of claim 1 further comprising forming a metal silicide region coincident to exposed portions of said gate electrode structure.
Claim 4
Dependent Claim 40 words
The method of claim 1 wherein forming a sidewall spacer adjacent each opposite sidewall of a gate electrode structure comprises forming said sidewall spacers having a first silicon oxide portion adjacent each sidewall, overlaid by a second silicon nitride portion.
Claim 5
Dependent Claim 33 words
The method of claim 1 wherein depositing a metal layer comprises depositing a metal layer selected from a group consisting of Co, Ti, W, Ta, Mo, Pt, Pd, Nd, Zr, Hf and Ni.
Claim 6
Dependent Claim 19 words
The method of claim 1 wherein depositing a metal layer comprises depositing a Co or a Ti metal layer.
Claim 7
Dependent Claim 34 words
The method of claim 1 further comprising forming an isolation region, wherein an active area for subsequently forming said gate electrode structure and said source and drain regions, is defined by said isolation region.
Claim 8
Dependent Claim 19 words
The method of claim 5, wherein forming an isolation region comprises forming a LOCOS or a trench isolation region.
Claim 9
Dependent Claim 21 words
The method of claim 1 wherein forming metal silicide regions comprise heating to a temperature between approximately 400 to 750° centigrade.
Claim 10
Dependent Claim 18 words
The method of claim 1 wherein etching said sidewall spacers comprises etching-away essentially all of said sidewall spacers.
Claim 11
Dependent Claim 38 words
The method of claim 1 wherein providing a gate electrode comprises forming a gate layer comprising a material selected from the group consisting of polysilicon, amorphous silicon, tungsten, molybdinum, tantalum and combinations thereof, overlying a gate dielectric layer.
Claim 12
Independent Claim 216 words
A method for forming a MOS transistor with silicide stringers removed, comprising the steps of: providing a semiconductor wafer having an upper surface comprised of silicon; forming an isolation region in said wafer, wherein an active area, adjacent said upper surface, is defined by said isolation region; forming a gate dielectric overlying at least a portion of said active area; forming a gate electrode overlying said gate dielectric; forming a source region and a drain region, in said active area, adjacent opposite sidewalls of said gate electrode; forming sidewall spacers adjacent each of said opposite sidewalls and overlying a portion of said source and drain regions, said sidewall spacers being formed of a material selected from the group consisting of silicon oxide, phosphorus doped silicon oxide and silicon nitride; depositing a blanket silicide forming metal layer overlying said semiconductor wafer, wherein said metal layer is in contact with the silicon of an upper surface of said source and drain regions; heating said substrate to a first temperature, wherein said first temperature is sufficiently high for said metal layer to react to form metal silicide regions; selectively etching said metal layer, wherein unreacted metal of said metal layer is removed; and etching said sidewall spacers, wherein at least a portion of said sidewall spacers is etched away.
Claim 13
Independent Claim 216 words
A method for forming a MOS transistor with silicide stringers removed, comprising the steps of: providing a semiconductor wafer having an upper surface comprised of silicon; forming an isolation region in said wafer, wherein an active area, adjacent said upper surface, is defined by said isolation region; forming a gate dielectric overlying at least a portion of said active area; forming a gate electrode overlying said gate dielectric; forming a source region and a drain region, in said active area, adjacent opposite sidewalls of said gate electrode; forming sidewall spacers adjacent each of said opposite sidewalls and overlying a portion of said source and drain regions, said sidewall spacers being formed of a material selected from the group consisting of silicon oxide, phosphorus doped silicon oxide and silicon nitride; depositing a blanket silicide forming metal layer overlying said semiconductor wafer, wherein said metal layer is in contact with the silicon of an upper surface of said source and drain regions; heating said substrate to a first temperature, wherein said first temperature is sufficiently high for said metal layer to react to form metal silicide regions; selectively etching said metal layer, wherein unreacted metal of said metal layer is removed; and etching said sidewall spacers, wherein at least a portion of said sidewall spacers is etched away.
Claim 14
Dependent Claim 33 words
The method of claim 11 wherein forming a gate electrode comprises forming a gate electrode with a material selected from the group consisting of polysilicon, amorphous silicon, tungsten, molybdinum, tantalum and combinations thereof.
Claim 15
Dependent Claim 21 words
The method of claim 11 wherein forming an isolation region comprises forming a LOCOS isolation region or a trench isolation region.
Claim 16
Dependent Claim 26 words
The method of claim 11 wherein heating said substrate to a first temperature comprises heating said substrate to a temperature between approximately 400 to 750° centigrade.
Claim 17
Dependent Claim 18 words
The method of claim 11 comprising heating said substrate to a second temperature higher than said first temperature.
Claim 18
Dependent Claim 36 words
The method of claim 11 wherein depositing a blanket silicide forming metal layer comprises depositing a metal layer selected from a group consisting of Co, Ti, W, Ta, Mo, Pt, Pd, Nd, Zr, Hf and Ni.
Claim 19
Dependent Claim 22 words
The method of claim 11 wherein depositing a blanket silicide forming metal layer comprises depositing a Co or a Ti metal layer.
Claim 20
Dependent Claim 26 words
The method of claim 11 wherein etching said semiconductor wafer using an etchant selective to said sidewall spacers comprises etching-away essentially all of said sidewall spacers.

References Cited (Backward Citations)

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USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 2002-12-20 2003-06-21 2003-12-21 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 2006-12-20 2007-06-21 2007-12-21 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2010-12-20 2011-06-21 2011-12-21 $7700.00 Window Closed / Lapsed

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