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US5932006A Expired / Lapsed US ⏱️ 0.0 years remaining

BaF2 /GaAs electronic components

Assignee: United States Department of the Navy
•
Filing: 1996-03-25
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Granted: 1999-08-03
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Expires: 2016-03-25
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Abstract

Abstract Metal insulator semiconductor field effect transistors (MISFETs), charge coupled devices (CCDs), and capacitors based on an epitaxial barium fluoride (BF 2 ) insulator layer deposited directly onto a single crystal gallium arsenide (GaAs) substrate.

Inventors

  • 👤 Francisco Santiago
  • 👤 Tak Kin Chu

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-09 01:58
CPC Classifications
H; H10; H10D; H10D64/00; H10D64/60; H10D64/66; H10D64/68; H10D64/681; H10D64/685; H10D1/00; H10D1/01; H10D1/045; H10D1/047; H10D30/00; H10D30/01; H10D30/021; H10D30/60; H10D30/68; H10D30/681; H10D44/00; H10D44/01; H10D44/041; H10D64/01; H10D64/013; H10D64/01358; H10P; H10P14/00; H10P14/60; H10P14/63; H10P14/6326; H10P14/6349; H10D1/60; H10D1/68; H10D1/692; H10D62/00; H10D62/80; H10D62/85

Claims Analysis

Total Claims: 20
Claim 1
Independent Claim 82 words
A method of producing a BaF 2 /GaAs electronic component comprising the steps of heating a clean single crystal gallium arsenide substrate surface in a vacuum, and exposing the heated substrate surface to barium fluoride vapor at a flux such that barium fluoride is deposited on the surface of the substrate at a deposition rate sufficiently low to produce, on the surface of the substrate, a thin, uniform, epitaxial layer of barium fluoride/gallium arsenide reaction product, substantially free of unreacted barium fluoride.
Claim 2
Independent Claim 82 words
A method of producing a BaF 2 /GaAs electronic component comprising the steps of heating a clean single crystal gallium arsenide substrate surface in a vacuum, and exposing the heated substrate surface to barium fluoride vapor at a flux such that barium fluoride is deposited on the surface of the substrate at a deposition rate sufficiently low to produce, on the surface of the substrate, a thin, uniform, epitaxial layer of barium fluoride/gallium arsenide reaction product, substantially free of unreacted barium fluoride.
Claim 3
Dependent Claim 37 words
The method of claim 1 wherein the single crystal gallium arsenide substrate surface is heated to a temperature in the range from 500° C. to 700° C. during the formation of the barium fluoride/gallium arsenide reaction product.
Claim 4
Dependent Claim 37 words
The method of claim 1 wherein the single crystal gallium arsenide substrate surface is heated to a temperature in the range from 550° C. to 650° C. during the formation of the barium fluoride/gallium arsenide reaction product.
Claim 5
Dependent Claim 37 words
The method of claim 1 wherein the single crystal gallium arsenide substrate surface is heated to a temperature in the range from 575° C. to 625° C. during the formation of the barium fluoride/gallium arsenide reaction product.
Claim 6
Dependent Claim 38 words
The method of claim 1 wherein the barium fluoride is deposited on the surface of the substrate at a rate of from 1 to 5 Å per minute during the formation of the barium fluoride/gallium arsenide reaction product.
Claim 7
Dependent Claim 38 words
The method of claim 1 wherein the barium fluoride is deposited on the surface of the substrate at a rate of from 2 to 3 Å per minute during the formation of the barium fluoride/gallium arsenide reaction product.
Claim 8
Dependent Claim 97 words
The method of claim 1 wherein the single crystal gallium arsenide substrate is selected from the group consisting of gallium arsenide single crystal wafers, gallium arsenide epitaxial layers on gallium arsenide single crystal wafers, epitaxial layers of gallium arsenide alloys on single crystal gallium arsenide wafers, heterostructures of super-lattice made of combinations of gallium arsenide alloys on gallium arsenide single crystal wafers, gallium arsenide single crystal epitaxial layers on suitable substrate materials, epitaxial layers of gallium arsenide alloys on suitable substrate materials, and heterostructures of super-lattice made of combinations of gallium arsenide alloys on suitable substrate materials.
Claim 9
Dependent Claim 45 words
The method of claim 7 wherein the single crystal gallium arsenide substrate is selected from the group consisting of gallium arsenide single crystal wafers, gallium arsenide epitaxial layers on gallium arsenide single crystal wafers, and gallium arsenide single crystal epitaxial layers on suitable substrate materials.
Claim 10
Dependent Claim 19 words
The method of claim 8 wherein the single crystal gallium arsenide substrate is a gallium arsenide single crystal wafer.
Claim 11
Dependent Claim 27 words
The method of claim 8 wherein the single crystal gallium arsenide substrate is a gallium arsenide single crystal epitaxial layer on a gallium arsenide single crystal wafer.
Claim 12
Dependent Claim 30 words
The method of claim 1 wherein the uniform epitaxial layer of barium fluoride/gallium arsenide reaction product has the same orientation as that of the single crystal gallium arsenide substrate surface.
Claim 13
Dependent Claim 17 words
The method of claim 1 in which the vacuum is less than 10 -9 millibars background pressure.
Claim 14
Dependent Claim 26 words
The method of claim 1 wherein the thin, uniform epitaxial layer of barium fluoride/gallium arsenide reaction product is held to a thickness less than 20 Å.
Claim 15
Dependent Claim 26 words
The method of claim 1 wherein the thin, uniform epitaxial layer of barium fluoride/gallium arsenide reaction product is held to a thickness less than 15 Å.
Claim 16
Dependent Claim 42 words
The method in accordance with claim 1 in which said step of exposing the heated substrate surface to barium fluoride vapor is followed by the step of depositing barium fluoride onto said thin, uniform, epitaxial layer of barium fluoride/gallium arsenide reaction product.
Claim 17
Dependent Claim 45 words
The method in accordance with claim 15 in which said clean single crystal gallium arsenide substrate surface is a surface of a channel region of a substrate doped to provide a source region, a channel region and a drain region of a field effect transistor.
Claim 18
Dependent Claim 55 words
The method in accordance with claim 15 in which the steps of exposing the heated substrate surface to barium fluoride vapor and depositing barium fluoride onto said thin, uniform, epitaxial layer of barium fluoride/gallium arsenide reaction product produce an insulator structure, and in which a capacitor is formed by applying electrodes to said insulator structure.
Claim 19
Dependent Claim 55 words
The method in accordance with claim 15 in which the steps of exposing the heated substrate surface to barium fluoride vapor and depositing barium fluoride onto said thin, uniform, epitaxial layer of barium fluoride/gallium arsenide reaction product, are followed by the application of gate electrodes to the deposited barium fluoride to produce a chargecoupled device.
Claim 20
Dependent Claim 52 words
The method in accordance with claim 1 in which said step of exposing the heated substrate surface to barium fluoride vapor is followed by the step of depositing barium fluoride onto said thin, uniform, epitaxial layer of barium fluoride/gallium arsenide reaction product at a deposition rate greater than said low deposition rate.

References Cited (Backward Citations)

US4291327A Cited
US4692993A Cited
US4550331A Cited
US4847666A Cited
JPH02266569A Cited
US5124762A Cited
US5435264A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 2002-08-02 2003-02-01 2003-08-03 $2000.00 Window Closed / Lapsed
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