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US5897982A Expired / Lapsed US ⏱️ 0.0 years remaining

Resist develop process having a post develop dispense step

Assignee: Toshiba Corp
•
Filing: 1996-03-05
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Granted: 1999-04-27
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Expires: 2016-03-05
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Abstract

Abstract A resist develop process involves the steps of dispensing a developer on a resist on a semiconductor wafer, forming the developer into a puddle where a portion of the resist dissolves into the developer, dispensing additional developer following development, rinsing the wafer with a rinsing agent, and drying the wafer surface. The additional developer dispense step replaces developer with resist dissolved therein with new developer prior to the rinsing step to prevent potential resist precipitation during the rinsing step which can lead to bridging.

Inventors

  • 👤 Tsuyoshi Shibata
  • 👤 Eric A. Lehner

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-30 19:18
CPC Classifications
G; G03; G03F; G03F7/00; G03F7/26; G03F7/30; G03F7/3021

Claims Analysis

Total Claims: 25
Claim 1
Independent Claim 102 words
A resist develop process for manufacturing a semiconductor device comprising the steps of: dispensing a first developer on a semiconductor wafer coated with a resist to form a puddle; developing the resist on the wafer surface by dissolving portions of the resist in the first developer; spin drying the dissolved portions of the resist; and after said step of spin drying, dispensing a second developer onto the wafer surface while rotating the wafer to reduce the concentration of the first developer containing dissolved portions of the resist on the wafer surface without forming another puddle, the second developer replacing the first developer.
Claim 2
Dependent Claim 102 words
A resist develop process for manufacturing a semiconductor device comprising the steps of: dispensing a first developer on a semiconductor wafer coated with a resist to form a puddle; developing the resist on the wafer surface by dissolving portions of the resist in the first developer; spin drying the dissolved portions of the resist; and after said step of spin drying, dispensing a second developer onto the wafer surface while rotating the wafer to reduce the concentration of the first developer containing dissolved portions of the resist on the wafer surface without forming another puddle, the second developer replacing the first developer.
Claim 3
Dependent Claim 27 words
The resist develop process of claim 1, wherein said step of dispensing the second developer occurs in a period of less than or equal to five seconds.
Claim 4
Dependent Claim 14 words
The resist develop process of claim 2, wherein the period is approximately two seconds.
Claim 5
Dependent Claim 20 words
The resist develop process of claim 3, wherein approximately twenty-five milliliters of the second developer is dispensed during the period.
Claim 6
Dependent Claim 39 words
The resist develop process of claim 1, wherein said step of dispensing the second developer includes dispensing the second developer while the wafer rotates on a wafer chuck at a rate of between 100 and 1000 revolutions per minute.
Claim 7
Dependent Claim 37 words
The resist develop process of claim 1, wherein said step of dispensing the second developer includes dispensing the second developer while the wafer rotates on a wafer chuck at a rate of approximately 1000 revolutions per minute.
Claim 8
Dependent Claim 34 words
The resist develop process of claim 1, wherein said steps of dispensing the first developer and developing the resist are repeated at least three times prior to said step of dispensing the second developer.
Claim 9
Dependent Claim 24 words
The resist develop process of claim 1, wherein said step of spin drying does not completely spin dry the dissolved portions of the resist.
Claim 10
Dependent Claim 25 words
The resist develop process of claim 1, wherein the second developer is different from the first developer, but compatible with the wafer and the resist.
Claim 11
Dependent Claim 21 words
The resist develop process of claim 1, wherein the second developer contains a different amount of surfactant than the first developer.
Claim 12
Dependent Claim 18 words
The resist develop process of claim 1, wherein the first developer and the second developer are the same.
Claim 13
Dependent Claim 31 words
The resist develop process of claim 1, wherein the first developer is tetramethylammonium hydroxide (TMAH) and the second developer is tetramethylammonium hydroxide (TMAH) having a different normality than the first developer.
Claim 14
Dependent Claim 13 words
The resist develop process of claim 1, wherein the resist is chemically amplified.
Claim 15
Dependent Claim 27 words
The resist develop process of claim 1, further comprising the step of rinsing the wafer surface with water after starting said step of dispensing the second developer.
Claim 16
Dependent Claim 23 words
The resist develop process of claim 14, wherein said steps of dispensing the second developer and rinsing the wafer surface are approximately simultaneous.
Claim 17
Dependent Claim 25 words
The resist develop process of claim 15, wherein said steps of dispensing the second developer and rinsing the wafer surface are performed in immediate succession.
Claim 18
Dependent Claim 35 words
The resist develop process of claim 1, wherein said step of dispensing the second developer includes spinning a wafer chuck holding the wafer to remove the first developer with the dissolved portions of the resist.
Claim 19
Dependent Claim 20 words
The resist develop process of claim 1, wherein the semiconductor device has line/space structures less than 5 μm in size.
Claim 20
Dependent Claim 94 words
A resist develop process for manufacturing a semiconductor device comprising the steps of: dispensing a first developer on a semiconductor wafer coated with a resist to form a puddle; developing the resist on the wafer surface by dissolving portions of the resist in the first developer; dispensing a second developer onto the wafer surface without forming another puddle while removing the first developer having dissolved portions of the resist by spinning the wafer; and repeating the steps of developing and dispensing the first developer prior to performing the step of dispensing the second developer.
Claim 21
Dependent Claim 94 words
A resist develop process for manufacturing a semiconductor device comprising the steps of: dispensing a first developer on a semiconductor wafer coated with a resist to form a puddle; developing the resist on the wafer surface by dissolving portions of the resist in the first developer; dispensing a second developer onto the wafer surface without forming another puddle while removing the first developer having dissolved portions of the resist by spinning the wafer; and repeating the steps of developing and dispensing the first developer prior to performing the step of dispensing the second developer.
Claim 22
Dependent Claim 106 words
A resist develop process for manufacturing a semiconductor device comprising the steps of: dispensing a first developer on a semiconductor wafer coated with a resist to form a puddle; developing the resist on the wafer surface by dissolving portions of the resist in the first developer; and dispensing a second developer onto the wafer surface while rotating the wafer to reduce the concentration of the first developer containing dissolved portions of the resist on the wafer surface without forming another puddle, the second developer replacing the first developer, wherein the second developer is different from the first developer, but compatible with the wafer and the resist.
Claim 23
Dependent Claim 106 words
A resist develop process for manufacturing a semiconductor device comprising the steps of: dispensing a first developer on a semiconductor wafer coated with a resist to form a puddle; developing the resist on the wafer surface by dissolving portions of the resist in the first developer; and dispensing a second developer onto the wafer surface while rotating the wafer to reduce the concentration of the first developer containing dissolved portions of the resist on the wafer surface without forming another puddle, the second developer replacing the first developer, wherein the second developer is different from the first developer, but compatible with the wafer and the resist.
Claim 24
Dependent Claim 92 words
A resist develop process for manufacturing a semiconductor device comprising the steps of: dispensing a first developer on a semiconductor wafer coated with a resist to form a puddle; developing the resist on the wafer surface by dissolving portions of the resist in the first developer; and dispensing a second developer onto the wafer surface without forming another puddle while removing the first developer having dissolved portions of the resist by spinning the wafer, wherein the second developer is different from the first developer, but compatible with the wafer and the resist.
Claim 25
Dependent Claim 92 words
A resist develop process for manufacturing a semiconductor device comprising the steps of: dispensing a first developer on a semiconductor wafer coated with a resist to form a puddle; developing the resist on the wafer surface by dissolving portions of the resist in the first developer; and dispensing a second developer onto the wafer surface without forming another puddle while removing the first developer having dissolved portions of the resist by spinning the wafer, wherein the second developer is different from the first developer, but compatible with the wafer and the resist.

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 2002-04-26 2002-10-26 2003-04-27 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 2006-04-26 2006-10-26 2007-04-27 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2010-04-26 2010-10-26 2011-04-27 $7700.00 Window Closed / Lapsed

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