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US5866945A Expired / Lapsed US ⏱️ 0.0 years remaining

Borderless vias with HSQ gap filled patterned metal layers

Assignee: Aluma Enterprises Inc
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Filing: 1997-10-16
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Granted: 1999-02-02
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Expires: 2017-10-16
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Abstract

Abstract Spin-on HSQ is employed to gap fill metal layers in manufacturing a high density, multi-metal layer semiconductor device. The degradation of deposited HSQ layers during formation of borderless vias, as from photoresist stripping using an O 2 -containing plasma, is overcome by treating the degraded HSQ layer with an H 2 -containing plasma to restore the dangling Si--H bonds, thereby passivating the surface and preventing moisture absorption, before filling the via opening with conductive material, such as a barrier layer.

Inventors

  • 👤 Robert C. Chen
  • 👤 Jeffrey A. Shields
  • 👤 Robert Dawson
  • 👤 Khanh Tran

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-31 18:42
CPC Classifications
H; H10; H10P; H10P14/00; H10P14/60; H10P14/63; H10P14/6326; H10P14/6328; H10P14/6334; H10P14/6336; H10P14/69; H10P14/692; H10P14/6921; H10P14/6922; H10P14/6925; H10P76/00; H10W; H10W20/00; H10W20/01; H10W20/071; H10W20/081; H10W20/089; H10W20/093; H10W20/096; H10W20/098

Claims Analysis

Total Claims: 7
Claim 1
Independent Claim 57 words
A semiconductor device comprising an interconnection pattern having: an opening filled with conductive material forming an electrical connection between a first lower metal feature and a second upper metal feature; and a layer of hydrogen silsesquioxane (HSQ) adjoining the first metal feature and conductive material; wherein the layer of HSQ comprises more than about 70% Si--H bonds.
Claim 2
Dependent Claim 57 words
A semiconductor device comprising an interconnection pattern having: an opening filled with conductive material forming an electrical connection between a first lower metal feature and a second upper metal feature; and a layer of hydrogen silsesquioxane (HSQ) adjoining the first metal feature and conductive material; wherein the layer of HSQ comprises more than about 70% Si--H bonds.
Claim 3
Dependent Claim 19 words
The semiconductor device according to claim 1, wherein the layer of HSQ comprises more than about 80% Si--H bonds.
Claim 4
Dependent Claim 20 words
The semiconductor device according to claim 2, wherein the layer of HSQ comprises about 87% to about 90% Si--H bonds.
Claim 5
Dependent Claim 191 words
The semiconductor device according to claim 1, comprising: a first dielectric layer on a semiconductor substrate; a first patterned metal layer having gaps formed on the first dielectric layer, the first patterned metal layer comprising the first lower metal feature having an upper surface and side surfaces; a layer of HSQ filling the gaps; a second dielectric layer formed on the first patterned metal layer and on the HSQ layer; a through-hole formed in the second dielectric layer exposing a portion of the upper surface and at least a portion of a side surface of the first lower metal feature, and penetrating into and exposing a portion of the HSQ layer; and conductive material filling the through-hole to form a borderless via; wherein, the through-hole is formed by: depositing a photoresist mask on the second dielectric layer; etching; and removing the photoresist mask using an O 2 -containing plasma causing a reduction in the number of Si--H bonds of the HSQ layer and, wherein, the HSQ layer is subsequently treated with a H 2 -containing plasma to increase the number of Si--H bonds before filling the through-hole with the conductive material.
Claim 6
Dependent Claim 31 words
The semiconductor device according to claim 4, wherein the conductive material is a composition comprising a first conductive barrier layer which acts as an adhesion promoter for a second conductive layer.
Claim 7
Dependent Claim 29 words
The semiconductor device according to claim 5, wherein the first conductive layer comprises titanium, titanium-nitride, titanium-tungsten, ortitanium-titanium nitride, and the second conductive layer comprises aluminum or an aluminum alloy.

References Cited (Backward Citations)

US5563102A Cited
US5604380A Cited
US5506177A Cited
US5456952A Cited
US5549934A Cited
US5534731A Cited
US5530293A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 2002-02-01 2002-08-03 2003-02-02 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 2006-02-01 2006-08-03 2007-02-02 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2010-02-01 2010-08-03 2011-02-02 $7700.00 Window Closed / Lapsed

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