Patent US5858075A successfully refreshed from Google Patents.
US5858075A
Expired / Lapsed
US
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Dye set for improved ink-jet image quality
Assignee: HP Inc
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Filing: 1997-03-03
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Granted: 1999-01-12
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Expires: 2017-03-03
Abstract
Abstract In accordance with the invention a set of dyes suitable for use in ink-jet inks and method for formulating the same are provided. The yellow ink of the present invention contains a yellow colorant having a CIELAB hue angle, h°, less than 90° to provide a true representation of colors, particularly skin tone colors. More specifically, a specific dye set for formulating the yellow, cyan, and magenta inks is disclosed, comprising Yellow 104, Direct Blue 199, and Magenta 377 dyes, respectively. The Yellow 104, the Magenta 377, and the DB 199 dyes provide near photographic images having lightfast characteristics necessary to preserve the trueness of the inkjet images by (1) producing images having less light fade and (2) images that when they do fade, fade in a more uniform manner across the color set.
Inventors
- 👤 Larrie A. Deardurff
- 👤 Hiang P. Lauw
- 👤 Mary E. Austin
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-23 22:26
CPC Classifications
C; C09; C09D; C09D11/00; C09D11/30; C09D11/40; B; B41; B41J; B41J2/00; B41J2/005; B41J2/01; C09D11/32; C09D11/328
Claims Analysis
Total Claims: 42
Claim 1
Independent Claim
50 words
A set of ink-jet inks for ink-jet printing, including: at least one yellow ink containing at least one yellow colorant having a hue angle less than 90°; at least one cyan ink containing at least one cyan dye; and at least one magenta ink containing at least one magenta dye.
Claim 2
Dependent Claim
50 words
A set of ink-jet inks for ink-jet printing, including: at least one yellow ink containing at least one yellow colorant having a hue angle less than 90°; at least one cyan ink containing at least one cyan dye; and at least one magenta ink containing at least one magenta dye.
Claim 3
Dependent Claim
26 words
The set of ink-jet inks of claim 1 wherein the yellow colorant has a hue angle in a range from about 78° to less than 90°.
Claim 4
Dependent Claim
25 words
The set of ink-jet inks of claim 1 wherein the yellow colorant has a hue angle in a range from about 80° to about 88°.
Claim 5
Dependent Claim
30 words
The set of ink-jet inks of claim 1 wherein the yellow colorant is selected from the group consisting of Yellow 104, Direct Yellow 4, Direct Yellow 50, and mixtures thereof.
Claim 6
Dependent Claim
18 words
The set of ink-jet inks of claim 1 wherein the cyan dye comprises at least one phthalocyanine dye.
Claim 7
Dependent Claim
30 words
The set of ink-jet inks of claim 1 wherein the magenta dye is selected from the group consisting of Magenta 377, Reactive Red 29, Reactive Red 180, and mixtures thereof.
Claim 8
Dependent Claim
16 words
The set of ink-jet inks of claim 1 wherein the yellow colorant is Yellow 104 dye.
Claim 9
Dependent Claim
31 words
The set of ink-jet inks of claim 1 wherein the yellow colorant is Yellow 104 dye; the cyan dye is Direct Blue 199 dye; and the magenta dye is Magenta 377.
Claim 10
Dependent Claim
27 words
The set of ink-jet inks of claim 1 wherein each of said yellow, cyan, and magenta inks comprises from about 0.1 to about 5 wt % dye.
Claim 11
Dependent Claim
27 words
The set of ink-jet inks of claim 1 wherein each of said yellow, cyan, and magenta inks comprises from about 2.5 to about 5 wt % dye.
Claim 12
Dependent Claim
27 words
The set of ink-jet inks of claim 8 wherein each of said yellow, cyan, and magenta inks comprises from about 0.1 to about 5 wt % dye.
Claim 13
Dependent Claim
27 words
The set of ink-jet inks of claim 8 wherein each of said yellow, cyan, and magenta inks comprises from about 2.5 to about 5 wt % dye.
Claim 14
Dependent Claim
66 words
The set of ink-jet inks of claim 1 wherein each of said yellow, cyan, and magenta inks further comprises: about 5 to about 20 wt % of at least one diol; 0 to about 5 wt % of at least one alcohol; 0 to about 1.5 wt % of at least one component independently selected from the group consisting of surfactants, buffers, biocides, and metal chelators.
Claim 15
Dependent Claim
109 words
The set of ink-jet inks of claim 13 wherein said at least one diol is selected from the group consisting of 1,2-butanediol, 1,4-butanediol, 1,2-pentanediol, 1,5-pentanediol, 1,2-hexanediol, 1,6-hexanediol, 2,5-hexanediol, 1,2-heptanediol, 1,2-octanediol, and 1,8-octanediol; wherein said at least one alcohol is independently selected from the group consisting of propanol, butanol, pentanol, hexanol, and isomers thereof; and wherein said at least one surfactant is a non-ionic surfactant selected from the group consisting of secondary alcohol ethoxylate surfactants predominantly having about 4 to about 8 ethoxylated units and an aliphatic chain from about 12 to about 18 carbon atoms, non-ionic fluoro surfactants, fatty acid ethoxylate surfactants, fatty amide ethoxylate surfactants, and mixtures thereof.
Claim 16
Dependent Claim
87 words
The set of ink-jet inks of claim 13 wherein said at least one diol is selected from the group consisting of 1,2 pentanediol, 1,2-hexanediol, and 1,2-heptanediol; wherein said at least one alcohol is selected from the group consisting of n-butanol, iso-butanol, n-propanol, n-pentanol, and 1,2-butanediol; and wherein said at least one surfactant is selected from the group consisting of at least one secondary alcohol ethoxylate surfactant predominantly having about 5 to about 7 ethoxylated units and an aliphatic chain from about 14 to about 16 carbon atoms.
Claim 17
Dependent Claim
49 words
The set of ink-jet inks of claim 13 wherein said at least one diol comprises 1,2-hexanediol; said at least one alcohol comprises n-butanol; said at least one surfactant comprises a secondary alcohol ethoxylate surfactant predominantly having about 5 ethoxylated units and an aliphatic chain of about 15 carbon atoms.
Claim 18
Dependent Claim
82 words
The set of ink-jet inks of claim 8 wherein each of said yellow, cyan, and magenta inks further comprises: about 8 to about 15 wt % of said at least one diol; about 1 to about 5 wt % of said at least one alcohol; about 0.5 to about 1.2 wt % of said at least one surfactant; about 0.1 to 0.5 wt % of said at least one component independently selected from the group consisting of buffers, biocides, and metal chelators.
Claim 19
Dependent Claim
13 words
The set of ink-jet inks of claim 1 further including a black ink.
Claim 20
Dependent Claim
17 words
The set of ink-jet inks of claim 18 wherein the black ink comprises Processed Reactive Black 31.
Claim 21
Dependent Claim
32 words
The set of ink-jet inks of claim 18 wherein the black ink is formed on the printed media by the addition of the yellow ink, the cyan ink, and the magenta ink.
Claim 22
Independent Claim
51 words
A method for ink-jet printing, said method comprising the steps of ejecting ink, said ink, including: a yellow ink containing at least one yellow colorant having a hue angle less than 90°; a cyan ink containing at least one cyan dye; and a magenta ink containing at least one magenta dye.
Claim 23
Independent Claim
51 words
A method for ink-jet printing, said method comprising the steps of ejecting ink, said ink, including: a yellow ink containing at least one yellow colorant having a hue angle less than 90°; a cyan ink containing at least one cyan dye; and a magenta ink containing at least one magenta dye.
Claim 24
Dependent Claim
25 words
The ink-jet printing method of claim 21 wherein the yellow colorant has a hue angle in a range from about 78° to less than 90°.
Claim 25
Dependent Claim
24 words
The ink-jet printing method of claim 21 wherein the yellow colorant has a hue angle in a range from about 80° to about 88°.
Claim 26
Dependent Claim
29 words
The ink-jet printing method of claim 21 wherein the yellow colorant is selected from the group consisting of Yellow 104, Direct Yellow 4, Direct Yellow 50, and mixtures thereof.
Claim 27
Dependent Claim
17 words
The ink-jet printing method of claim 21 wherein the cyan dye comprises at least one phthalocyanine dye.
Claim 28
Dependent Claim
29 words
The ink-jet printing method of claim 21 wherein the magenta dye is selected from the group consisting of Magenta 377, Reactive Red 29, Reactive Red 180, and mixtures thereof.
Claim 29
Dependent Claim
15 words
The ink-jet printing method of claim 21 wherein the yellow colorant is Yellow 104 dye.
Claim 30
Dependent Claim
30 words
The ink-jet printing method of claim 21 wherein the yellow colorant is Yellow 104 dye; the cyan dye is Direct Blue 199 dye; and the magenta dye is Magenta 377.
Claim 31
Dependent Claim
26 words
The ink-jet printing method of claim 21 wherein each of said yellow, cyan, and magenta inks comprises from about 0.1 to about 5 wt % dye.
Claim 32
Dependent Claim
26 words
The ink-jet printing method of claim 21 wherein each of said yellow, cyan, and magenta inks comprises from about 2.5 to about 5 wt % dye.
Claim 33
Dependent Claim
26 words
The ink-jet printing method of claim 28 wherein each of said yellow, cyan, and magenta inks comprises from about 0.1 to about 5 wt % dye.
Claim 34
Dependent Claim
26 words
The ink-jet printing method of claim 28 wherein each of said yellow, cyan, and magenta inks comprises from about 2.5 to about 5 wt % dye.
Claim 35
Dependent Claim
65 words
The ink-jet printing method of claim 21 wherein each of said yellow, cyan, and magenta inks further comprises: about 5 to about 20 wt % of at least one diol; 0 to about 5 wt % of at least one alcohol; 0 to about 1.5 wt % of at least one component independently selected from the group consisting of surfactants, buffers, biocides, and metal chelators.
Claim 36
Dependent Claim
108 words
The ink-jet printing method of claim 33 wherein said at least one diol is selected from the group consisting of 1,2-butanediol, 1,4-butanediol, 1,2-pentanediol, 1,5-pentanediol, 1,2-hexanediol, 1,6-hexanediol, 2,5-hexanediol, 1,2-heptanediol, 1,2-octanediol, and 1,8-octanediol; wherein said at least one alcohol is independently selected from the group consisting of propanol, butanol, pentanol, hexanol, and isomers thereof; and wherein said at least one surfactant is a non-ionic surfactant selected from the group consisting of secondary alcohol ethoxylate surfactants predominantly having about 4 to about 8 ethoxylated units and an aliphatic chain from about 12 to about 18 carbon atoms, non-ionic fluoro surfactants, fatty acid ethoxylate surfactants, fatty amide ethoxylate surfactants, and mixtures thereof.
Claim 37
Dependent Claim
86 words
The ink-jet printing method of claim 33 wherein said at least one diol is selected from the group consisting of 1,2 pentanediol, 1,2-hexanediol, and 1,2-heptanediol; wherein said at least one alcohol is selected from the group consisting of n-butanol, iso-butanol, n-propanol, n-pentanol, and 1,2-butanediol; and wherein said at least one surfactant is selected from the group consisting of at least one secondary alcohol ethoxylate surfactant predominantly having about 5 to about 7 ethoxylated units and an aliphatic chain from about 14 to about 16 carbon atoms.
Claim 38
Dependent Claim
48 words
The ink-jet printing method of claim 33 wherein said at least one diol comprises 1,2-hexanediol; said at least one alcohol comprises n-butanol; said at least one surfactant comprises a secondary alcohol ethoxylate surfactant predominantly having about 5 ethoxylated units and an aliphatic chain of about 15 carbon atoms.
Claim 39
Dependent Claim
68 words
The ink-jet printing method of claim 28 wherein each of said yellow, cyan and magenta inks further comprises: about 8 to about 15 wt % of said at least one diol; about 1 to about 5 wt % of said at least one alcohol; about 0.1 to 0.5 wt % of said at least one component independently selected from the group consisting of buffers, biocides, and metal chelators.
Claim 40
Dependent Claim
12 words
The ink-jet printing method of claim 21 further including a black ink.
Claim 41
Dependent Claim
16 words
The ink-jet printing method of claim 38 wherein the black ink comprises Processed Reactive Black 31.
Claim 42
Dependent Claim
31 words
The ink-jet printing method of claim 38 wherein the black ink is formed on the printed media by the addition of the yellow ink, the cyan ink, and the magenta ink.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 2002-01-11 | 2002-07-13 | 2003-01-12 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 2006-01-11 | 2006-07-13 | 2007-01-12 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 2010-01-11 | 2010-07-13 | 2011-01-12 | $7700.00 | Window Closed / Lapsed |