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US5211747A Expired / Lapsed US ⏱️ 0.0 years remaining

Ink jet ink compositions containing desizing agents

Assignee: Samsung Electronics Co Ltd
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Filing: 1991-05-16
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Granted: 1993-05-18
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Expires: 2011-05-16
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Abstract

Abstract An ink composition having a pH of about 5 to about 10 contains a colorant, a liquid carrier and less than about 5 wt. % of a desizing agent. The desizing agent may be (1) poly(oxyalkylene) modified compounds of sorbitan esters, fatty amines, alkanol amides, castor oil, fatty acid, fatty alcohol; (2) hydrophilic poly(dialkyl-siloxanes); (3) fatty imidazolines; (4) fatty ester modified compounds of phosphate, sorbitan, glycerol, poly(ethylene glycol), sulfosuccinic acid, sulfonic acid, alkyl amine; (5) quaternary alkosulfate compounds; (6) poly(propylene oxide)--poly(ethylene oxide) copolymers; (7) poly(alkylene glycol); or (8) mixtures thereof.

Inventors

  • 👤 Marcel P. Breton
  • 👤 Shadi L. Malhotra
  • 👤 Toshitake Yui
  • 👤 Kerstin M. Henseleit
  • 👤 Melvin D. Croucher

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-26 11:43
CPC Classifications
C; C09; C09D; C09D11/00; C09D11/30

Claims Analysis

Total Claims: 35
Claim 1
Independent Claim 67 words
An ink composition comprising a colorant, an ink vehicle and a desizing agent wherein said desizing agent is selected from the group consisting of (1) poly(oxyalkylene) modified compounds of sorbitan esters, alkanol amides, castor oil, or fatty acids; (2) hydrophilic poly(dialkyl-siloxanes); (3) fatty imidazolines; (4) fatty ester modified compounds of sorbitan, glycerol, poly(ethylene glycol), sulfonic acid, or alkyl amine; (5) quaternary alkosulfate compounds; and (6) poly(alkylene glycols).
Claim 2
Dependent Claim 67 words
An ink composition comprising a colorant, an ink vehicle and a desizing agent wherein said desizing agent is selected from the group consisting of (1) poly(oxyalkylene) modified compounds of sorbitan esters, alkanol amides, castor oil, or fatty acids; (2) hydrophilic poly(dialkyl-siloxanes); (3) fatty imidazolines; (4) fatty ester modified compounds of sorbitan, glycerol, poly(ethylene glycol), sulfonic acid, or alkyl amine; (5) quaternary alkosulfate compounds; and (6) poly(alkylene glycols).
Claim 3
Dependent Claim 16 words
The ink composition of claim 1, comprising less than 2 wt. % of said desizing agent.
Claim 4
Dependent Claim 21 words
The ink composition of claim 1, said composition having a Hercules sizing value on diazo paper of less than about 6.
Claim 5
Dependent Claim 46 words
The ink composition of claim 1, wherein said poly(oxyalkylene) modified compounds are selected from the group consisting of (a) poly(oxyethylene) sorbitan mono-laurate, poly(oxyethylene) sorbitan-mono oleate, poly(oxyethylene) sorbitan tri-oleate; (b) castor oil ethoxylates; (c) cocoalkanolamide ethoxylates; and (d) oleic acid ethoxylates, lauric acid ethoxylates, palmitic acid ethoxylates.
Claim 6
Dependent Claim 65 words
The ink composition of claim 1, wherein said hydrophilic poly(dialkyl siloxanes) are selected from the group consisting of (a) carbinol terminated poly(dimethyl siloxanes) selected from poly(ethylene oxide)-b-poly(dimethyl siloxane) diblock copolymers and poly(ethylene oxide)-b-poly(dimethyl siloxane)-b-poly(ethylene oxide) triblock copolymers; (b) poly(dimethyl siloxane)-b-poly(ethylene oxide)-b-poly(propylene oxide) triblock copolymers; (c) poly(dimethyl siloxane)-b-(methyl siloxane alkylene oxide) diblock copolymers where alkylene is ethylene, propylene or ethylene-propylene; and (d) poly quaternary poly(dimethyl siloxane).
Claim 7
Dependent Claim 35 words
The ink composition of claim 1, said fatty imidazolines are selected from the group consisting of (a) coco hydroxyethyl imidazoline; (b) oleic hydroxyethyl imidazoline; (c) tall oil amino ethyl imidazoline; and (d) sodium carboxylic imidazoline.
Claim 8
Dependent Claim 86 words
The ink composition of claim 1, wherein said fatty ester modified compounds are selected from the group consisting of: (a) sorbitan mono laurate, sorbitan mono oleate and sorbitan trioleate; (b) glyceryl mono oleate, glyceryl dioleate, glyceryl trioleate; (c) poly(ethylene glycol) mono oleate, poly(ethylene glycol) mono laurate, poly(ethylene glycol) dioleate, poly(ethylene glycol) di-laurate, poly(ethylene glycol) di-tallow; (d) isopropylamine dodecyl benzene sulfonate, calcium dodecyl benzene sulfonate; and (e) coco diethanol amide, lauric diethanol amide, coco monoethanol amide, lauric monoethanol amide, lauric mono isopropyl amide, and soya diethanol amide.
Claim 9
Dependent Claim 44 words
The ink composition of claim 1 wherein said quaternary alkosulfate compounds are selected from the group consisting of (a) nonpolymeric quaternary ammonium ethosulfate; (b) quaternary dialkyl dimethyl methosulfate; (c) quaternary alkoxylated di-tallow methosulfate; (d) quaternized tallow imidazoline methosulfate; and (e) quaternized oleic imidazoline methosulfate.
Claim 10
Dependent Claim 36 words
The ink composition of claim 1, wherein said poly glycol) is selected from the group consisting of poly(propylene glycol), poly(propylene glycol dimethacrylate), poly(ethylene glycol monomethyl-ether), poly(ethylene glycol diglycidyl ether), poly(ethylene glycol dimethyl ether), and poly(1,4-oxybutylene glycol).
Claim 11
Dependent Claim 11 words
The ink composition according to claim 1, further comprising a penetrant.
Claim 12
Dependent Claim 13 words
The ink composition according to claim 10, wherein said penetrant is propylene carbonate.
Claim 13
Dependent Claim 53 words
An ink composition comprising a colorant, an ink vehicle and 0.1 to 5% by weight of a poly(propylene oxide)-poly(ethylene oxide) copolymer selected from the group consisting of (a) poly(propylene oxide)-b-poly(ethylene oxide)-b-poly(propylene oxide) triblock copolymers; and (b) tetrafunctional block copolymers derived from the sequential addition of ethylene oxide and propylene oxide to ethylene diamine.
Claim 14
Dependent Claim 53 words
An ink composition comprising a colorant, an ink vehicle and 0.1 to 5% by weight of a poly(propylene oxide)-poly(ethylene oxide) copolymer selected from the group consisting of (a) poly(propylene oxide)-b-poly(ethylene oxide)-b-poly(propylene oxide) triblock copolymers; and (b) tetrafunctional block copolymers derived from the sequential addition of ethylene oxide and propylene oxide to ethylene diamine.
Claim 15
Dependent Claim 54 words
An ink composition, comprising a colorant, an ink vehicle and 0.1 to 5% by weight of a desizing agent selected from the group consisting of lauryl alcohol ethoxylates, oleyl alcohol ethoxylates, tallow alcohol ethoxylates, nonyl phenol ethoxylate, octyl phenol ethoxylate, oleic acid ethoxylates, dicarboxylic cocoimidazoline sodium salts and diethanol amide of coconut fatty acids.
Claim 16
Dependent Claim 54 words
An ink composition, comprising a colorant, an ink vehicle and 0.1 to 5% by weight of a desizing agent selected from the group consisting of lauryl alcohol ethoxylates, oleyl alcohol ethoxylates, tallow alcohol ethoxylates, nonyl phenol ethoxylate, octyl phenol ethoxylate, oleic acid ethoxylates, dicarboxylic cocoimidazoline sodium salts and diethanol amide of coconut fatty acids.
Claim 17
Dependent Claim 17 words
The ink composition of claim 13, said composition having a pH of about 5 to about 10.
Claim 18
Dependent Claim 16 words
The ink composition of claim 13, comprising 0.1 to 2 wt. % of said desizing agent.
Claim 19
Dependent Claim 21 words
The ink composition of claim 13, said composition having a Hercules sizing value on diazo paper of less than about 6.
Claim 20
Dependent Claim 14 words
The ink composition of claim 13, wherein said desizing agent is nonyl phenol ethoxylate.
Claim 21
Dependent Claim 18 words
The ink composition according to claim 13, wherein said ink vehicle comprises water and said colorant comprises dye.
Claim 22
Dependent Claim 33 words
The ink composition of claim 13, wherein said desizing agent is selected from the group consisting of lauryl alcohol ethoxylates, oleyl alcohol ethoxylates, tallow alcohol ethoxylates, nonyl phenol ethoxylate, and octyl phenol ethoxylate.
Claim 23
Dependent Claim 31 words
The ink composition of claim 17, wherein said desizing agent is present in an amount ranging from about 0.5% to about 2.0% by weight based on weight of the total composition.
Claim 24
Dependent Claim 12 words
The ink composition of claim 17, wherein said colorant is a dye.
Claim 25
Dependent Claim 15 words
The ink composition of claim 17, wherein said ink vehicle comprises water and a cosolvent.
Claim 26
Independent Claim 47 words
A method of ink jet printing, comprising jetting ink onto a substrate, the ink comprising a colorant, an ink vehicle, a penetrant and 0.1 to 5% by weight of a water or alcohol soluble desizing agent, said ink having a pH of about 5 to about 10.
Claim 27
Independent Claim 47 words
A method of ink jet printing, comprising jetting ink onto a substrate, the ink comprising a colorant, an ink vehicle, a penetrant and 0.1 to 5% by weight of a water or alcohol soluble desizing agent, said ink having a pH of about 5 to about 10.
Claim 28
Dependent Claim 21 words
The method of claim 23, wherein said desizing agent is present in an amount between about 0.1 to 2 wt. %.
Claim 29
Dependent Claim 12 words
The method according to claim 23, wherein said penetrant is propylene carbonate.
Claim 30
Dependent Claim 20 words
The method of claim 23, said composition having a Hercules sizing value on diazo paper of less than about 6.
Claim 31
Dependent Claim 13 words
The method of claim 23, wherein said desizing agent is nonyl phenol ethoxylate.
Claim 32
Dependent Claim 17 words
A method of ink jet printing, comprising jetting the ink composition of claim 1 onto a substrate.
Claim 33
Dependent Claim 17 words
A method of ink jet printing, comprising jetting the ink composition of claim 12 onto a substrate.
Claim 34
Dependent Claim 17 words
A method of ink jet printing, comprising jetting the ink composition of claim 13 onto a substrate.
Claim 35
Dependent Claim 17 words
A method of ink jet printing, comprising jetting the ink composition of claim 17 onto a substrate.

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1996-05-17 1996-11-16 1997-05-18 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 2000-05-17 2000-11-16 2001-05-18 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2004-05-17 2004-11-16 2005-05-18 $7700.00 Window Closed / Lapsed

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