Patent US4717975A successfully refreshed from Google Patents.
Patent US5827928A successfully refreshed from Google Patents.
US5827928A
Expired / Lapsed
US
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One-component, thermosetting resin composition for coating use
Assignee: Nippon Paint Co Ltd
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Filing: 1996-04-11
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Granted: 1998-10-27
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Expires: 2016-04-11
Abstract
Abstract A one-component, thermosetting resin composition curable through a Michael reaction between (a) a component having a plurality of alpha , beta -unsaturated carbonyl groups and (b) a component having a plurality of activated methylene of activated methyne groups is disclosed. The curing reaction is catalyzed with a quaternary ammonium, quaternary phosphonium or tertiary sulfonium salt in the presence of a five-membered cyclic carbonate compound independently added to the composition or covalently attached to either component (a) or component (b).
Inventors
- 👤 Hideo Morimoto
- 👤 Takashi Irie
- 👤 Kei Aoki
- 👤 Haruhiko Sawada
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-02 13:40
CPC Classifications
C; C09; C09D; C09D133/00; C09D133/04; C09D133/06; C08; C08F; C08F290/00; C08F290/02; C08F290/06; B; B05; B05D; B05D7/00; B05D7/50; C08F290/08; C08F290/14
Claims Analysis
Total Claims: 15
Claim 1
Independent Claim
97 words
A one-component, thermosetting resin composition for coating use comprising: (a) a component containing of α, β-ethylenically unsaturated carbonyl groups in the molecule; (b) a component containing a plurality of an activated methylene group or an activated methyne group in the molecule; (c) a quaternary ammonium salt, a quaternary phosphonium salt or a tertiary sulfonium salt, having a halide monobasic carboxylate, polybasis carboxylate, nitrate, nitrite, sulfonate, sulfite, phosphate or acid phosphate ester counter anion; (d) a five-membered cyclic compound as an independent component or covalently attached to at least one of said component (a) and said component (b).
Claim 2
Dependent Claim
97 words
A one-component, thermosetting resin composition for coating use comprising: (a) a component containing of α, β-ethylenically unsaturated carbonyl groups in the molecule; (b) a component containing a plurality of an activated methylene group or an activated methyne group in the molecule; (c) a quaternary ammonium salt, a quaternary phosphonium salt or a tertiary sulfonium salt, having a halide monobasic carboxylate, polybasis carboxylate, nitrate, nitrite, sulfonate, sulfite, phosphate or acid phosphate ester counter anion; (d) a five-membered cyclic compound as an independent component or covalently attached to at least one of said component (a) and said component (b).
Claim 3
Dependent Claim
48 words
The composition according to claim 1, wherein said component (a) is a polyol poly(meth)acrylate, an unsaturated polyester resin, a polyester acrylate resin, an epoxy acrylate resin, a urethane acrylate resin, a polyether acrylate resin, an α, β-unsaturated carbonyl group-containing acrylic resin, or a silicone oligomer having (meth)acryloyl groups.
Claim 4
Dependent Claim
55 words
The composition according to claim 1, wherein said component (b) is an ester of an activated methylene- or methynecarboxylic acid with a nonpolymeric or polymeric polyol, a reaction product of a polyamine with diketene, a polymer of an activated methylene group-containing acrylic monomer, or an adduct of an isocyanate compound with an activated methylene compound.
Claim 5
Dependent Claim
23 words
The composition according to claim 1, wherein the onium cation of said component (c) is a tetraalkylammonium, trialkylaralkylammonium, alkylpyridinium, tetraalkylphosphonium or trialkylsulfonium cation.
Claim 6
Dependent Claim
22 words
The composition according to claim 1, wherein said component (d) is a cyclic 1,2-alkylenecarbonate or glycerine carbonate independently added to the composition.
Claim 7
Dependent Claim
44 words
The composition according to claim 1, wherein at least one of said component (a) and said component (b) is an acrylic resin or polymer, and wherein said component (d) is glycerine carbonate (meth)acrylate copolymerized with a monomeric constituent of said acrylic resin or polymer.
Claim 8
Dependent Claim
52 words
In a method of forming a multi-layer coating film on a substrate comprising the steps of applying onto the substrate a colored base coat composition, applying a clear top coat composition thereon wet-on-wet, and baking both coats simultaneously, the improvement wherein said clear top coat composition is the composition of claim 1.
Claim 9
Dependent Claim
19 words
The composition of claim 1, wherein component (a) is a resin having a molecular weight between 400 and 100,000.
Claim 10
Dependent Claim
19 words
The composition of claim 1, wherein component (b) is a resin having a molecular weight between 400 and 100,000.
Claim 11
Dependent Claim
44 words
The composition of claim 1, wherein the counteranion for the quaternary ammonium salt, quaternary phosphonium salt or tertiary sulfonium salt, component (c), is acetate, laurate, glycolate, benzoate, salicylate, phthalate, chloride, bromide, iodide, methanesulfonate, p-toluenesulfonate, dodecylbenzene sulfonate, triflate, nitrate, sulfate, methosulfate, phoshphate or acid t-dibutylphosphate.
Claim 12
Dependent Claim
79 words
The composition of claim 1, wherein the proportion of components (a) and (b) is between 2:1 and 1:2 on the basis of the number ethylenically unsaturated carbonyl groups in (a) to activated methylene or methyne groups in (b), the proportion of component (c) is between 0.1 and 10.0 equivalent % based on the sum of (a) and (b), and the proportion of component (d) is between 0.5 and 100 equivalent % based on the sum of (a) and (b).
Claim 13
Dependent Claim
79 words
The composition of claim 1, wherein the proportion of components (a) and (b) is between 1.5:1 and 1:1.5 on the basis of the number ethylenically unsaturated carbonyl groups in (a) to activated methylene or methyne groups in (b), the proportion of component (c) is between 0.2 and 5.0 equivalent % based on the sum of (a) and (b), and the proportion of component (d) is between 5.0 and 40 equivalent % based on the sum of (a) and (b).
Claim 14
Dependent Claim
104 words
A one-component, thermosetting resin composition for coating formed from a mixture comprising: (a) a component containing a plurality of α, β-ethylenically unsaturated carbonyl groups in the molecule; (b) a component containing a plurality of an activated methylene group or an activated methyne group in the molecule; (c) a quaternary ammonium salt, a quaternary phosphonium salt or a tertiary sulfonium salt, having a halide, monobasic carboxylate, polybasic carboxylate, nitrate, nitrite, sulfonate, sulfate, sulfite, phosphate or acid phosphate ester counter anion; (d) a five-membered cyclic carbonate compound as an independent component or covalently attached to at least one of said component (a) and said component (b).
Claim 15
Dependent Claim
104 words
A one-component, thermosetting resin composition for coating formed from a mixture comprising: (a) a component containing a plurality of α, β-ethylenically unsaturated carbonyl groups in the molecule; (b) a component containing a plurality of an activated methylene group or an activated methyne group in the molecule; (c) a quaternary ammonium salt, a quaternary phosphonium salt or a tertiary sulfonium salt, having a halide, monobasic carboxylate, polybasic carboxylate, nitrate, nitrite, sulfonate, sulfate, sulfite, phosphate or acid phosphate ester counter anion; (d) a five-membered cyclic carbonate compound as an independent component or covalently attached to at least one of said component (a) and said component (b).
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 2001-10-26 | 2002-04-27 | 2002-10-27 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 2005-10-26 | 2006-04-27 | 2006-10-27 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 2009-10-26 | 2010-04-27 | 2010-10-27 | $7700.00 | Window Closed / Lapsed |