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Thin films of ABO3 with excess B-site modifiers and method of fabricating integrated circuits with same

Assignee: Panasonic Holdings Corp
•
Filing: 1997-01-27
•
Granted: 1998-09-29
•
Expires: 2017-01-27
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Abstract

Abstract A method for fabricating an integrated circuit capacitor having a dielectric layer comprising BST with excess B-site material, such as titanium, added. A polyoxyalkylated metal liquid precursor solution is prepared comprising a stock solution of BST of greater then 99.999% purity blended with excess B-site material such as titanium such that the titanium is in the range of 0-100 mol %. A xylene exchange is then performed to adjust the viscosity of the solution for spin-on application to a substrate. The precursor is spun on a first electrode, dried at 400 DEG C. for 2 minutes, then annealed at 650 DEG C. to 800 DEG C. for about an hour to form a layer of BST with excess titanium. A second electrode is deposited, patterned, and annealed at between 650 DEG C. to 800 DEG C. for about 30 minutes. The resultant capacitor exhibits an enlarged dielectric constant with only a small increase in leakage current.

Inventors

  • 👤 Masamichi Azuma
  • 👤 Carlos A. Paz de Araujo
  • 👤 Michael C. Scott

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-09 01:53
CPC Classifications
H; H10; H10P; H10P14/00; H10P14/60; H10P14/69; H10P14/692; H10P14/6938; H10P14/69398; C; C04; C04B; C04B35/00; C04B35/01; C04B35/46; C04B35/462; C04B35/465; C04B35/468; C04B35/4682; C04B35/47; C04B35/622; C04B35/626; C04B35/62605; C04B35/62625; C04B35/6264; C23; C23C; C23C16/00; C23C16/44; C23C16/4412; C23C16/448; C23C16/4486; C23C16/455; C23C16/45561; C23C16/45563; C23C16/4558; C23C16/46; C23C16/48; C23C16/482; C23C16/52; C23C18/00; C23C18/02; C23C18/12; C23C18/1204; C23C18/1208; C23C18/1216; C23C18/125; C23C18/1275; C23C18/1295; C30; C30B; C30B29/00; C30B29/60; C30B29/68; C30B7/00; H01; H01C; H01C7/00; H01C7/10; H01C7/1013; H10B; H10B12/00; H10B12/30; H10B53/00; H10D; H10D1/00; H10D1/60; H10D1/68; H10D1/682; H10D1/684; H10D1/692; H10P14/66; H10P14/668; C04B2235/00; C04B2235/02; C04B2235/30; C04B2235/32; C04B2235/3201; C04B2235/3203; C04B2235/3205; C04B2235/3206; C04B2235/3208; C04B2235/3213; C04B2235/3217; C04B2235/3224; C04B2235/3227; C04B2235/3229; C04B2235/3231; C04B2235/3232; C04B2235/3234; C04B2235/3241; C04B2235/3243; C04B2235/3251; C04B2235/3262; C04B2235/3268; C04B2235/327; C04B2235/3272; C04B2235/3275; C04B2235/3279; C04B2235/3281; C04B2235/3284; C04B2235/3289; C04B2235/44; C04B2235/441; C04B2235/449; C04B2235/65; C04B2235/658; C04B2235/6583; C04B2235/6585; C04B2235/70; C04B2235/72; C04B2235/74; C04B2235/79; H10P14/63; H10P14/6326; H10P14/6342; H10P14/65; H10P14/6502; H10P14/6506

Claims Analysis

Total Claims: 3
Claim 1
Independent Claim 93 words
An integrated circuit comprising: a substrate, a thin film of barium strontium titanate formed on said substrate, said thin film including excess B-site material in an amount ranging from 0.01 mol % to 100 mol % more than is required to satisfy a formula ABO 3 wherein A is total A-site material, B is total B-site material, and O is oxygen; and wiring layers operably configured to include said thin film of barium strontium titanate as a portion of an integrated circuit, said thin film having a thickness of less than 1600 Å.
Claim 2
Dependent Claim 93 words
An integrated circuit comprising: a substrate, a thin film of barium strontium titanate formed on said substrate, said thin film including excess B-site material in an amount ranging from 0.01 mol % to 100 mol % more than is required to satisfy a formula ABO 3 wherein A is total A-site material, B is total B-site material, and O is oxygen; and wiring layers operably configured to include said thin film of barium strontium titanate as a portion of an integrated circuit, said thin film having a thickness of less than 1600 Å.
Claim 3
Dependent Claim 20 words
The integrated circuit of claim 1 wherein said thin film has a thickness ranging from 700 Å to 1510 Å.

References Cited (Backward Citations)

US4963390A Cited
US5166759A Cited
US5198269A Cited
US5122923A Cited
US5225126A Cited
US5434410A Cited
US5656329A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 2001-09-28 2002-03-30 2002-09-29 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 2005-09-28 2006-03-30 2006-09-29 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2009-09-28 2010-03-30 2010-09-29 $7700.00 Window Closed / Lapsed

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