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US5788915A
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Flame retardant compositions utilizing partially hydrolyzed amino condensation compounds
Assignee: Individual
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Filing: 1997-02-14
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Granted: 1998-08-04
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Expires: 2017-02-14
Abstract
Abstract Flame retardant compositions of this invention are produced by incorporating a partially index (LOI) hydrolyzed amino condensation composition in a more flammable organic material. The partially hydrolyzed amino condensation compounds are produced by heating urea or heating urea with other nitrogen containing compounds that will condensate with or react with isocyanic acid and/or cyanic acid thereby producing an amino condensation compound which is then partially hydrolysis is done by reacting it with a limited amount of water. The partially hydrolyzed amino condensation compounds may be used alone or may be mixed with or reacted with carbonization auxiliaries, aldehydes and fillers to produce a partially hydrolyzed amino condensation composition which is incorporated in more flammable organic compositions such as polyurethanes, polyester resins, epoxy resins, vinyl resins and other resins. The partially hydrolyzed amino condensation salts of phosphorus, boron or sulfur containing compounds and the partially hydrolyzed amino condensation-aldehyde resins may also be used as the flame retardant compound in this invention. For example, polyurethane foams can be rendered less flammable with the partially hydrolyzed amino condensation compounds or compositions and utilized as cushion and insulating materials.
Inventors
- 👤 David H. Blount
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-08 15:36
CPC Classifications
C; C08; C08G; C08G18/00; C08G18/06; C08G18/28; C08G18/65; C08G18/66; C08G18/6603; C08G18/6614; C08G18/30; C08G18/38; C08G18/3819; C08G18/3823; C08G18/3831; C09; C09K; C09K21/00; C09K21/06; C09K21/10; Y; Y10; Y10S; Y10S428/00; Y10S428/92; Y10S428/921
Claims Analysis
Total Claims: 37
Claim 1
Independent Claim
146 words
A flame retardant composition produced by incorporating a partially hydrolyzed amino condensation composition and/or partially hydrolyzed amino condensation salt of phosphorus and/or boron containing compounds and/or partially hydrolyzed amino condensation-aldehyde resin comdensation in an organic material, under reaction conditions and in an amount sufficient to reduce the combustibility of the organic material, said partially hydrolyzed amino condensation composition is produced by the process comprising of mixing, heating, and reacting the following components: (A) urea (B) nitrogen containing compound that will condensate and/or react with urea; (C) water; (D) aldehyde; (E) carbonization auxiliaries; (F) filler; components A and B are first reacted to produce an amino condensation compound, then component C is added, mixed and reacted, thereby producing a partially hydrolyzed amino condensation compound then component D is added and reacted thereby producing a partially hydrolyzed amino condensation-aldehyde resin and then component E and F are added.
Claim 2
Dependent Claim
146 words
A flame retardant composition produced by incorporating a partially hydrolyzed amino condensation composition and/or partially hydrolyzed amino condensation salt of phosphorus and/or boron containing compounds and/or partially hydrolyzed amino condensation-aldehyde resin comdensation in an organic material, under reaction conditions and in an amount sufficient to reduce the combustibility of the organic material, said partially hydrolyzed amino condensation composition is produced by the process comprising of mixing, heating, and reacting the following components: (A) urea (B) nitrogen containing compound that will condensate and/or react with urea; (C) water; (D) aldehyde; (E) carbonization auxiliaries; (F) filler; components A and B are first reacted to produce an amino condensation compound, then component C is added, mixed and reacted, thereby producing a partially hydrolyzed amino condensation compound then component D is added and reacted thereby producing a partially hydrolyzed amino condensation-aldehyde resin and then component E and F are added.
Claim 3
Dependent Claim
80 words
A flame retardant composition of claim 1 wherein the nitrogen containing compound that will condensate and/or react with isocyanic acid and/or cyanic acid, produced by heating urea, is selected from the group consisting of amino compounds, amines, polyamines, urea derivatives, thiourea, thiourea derivatives, guanidine carbonate, urea carbonates, ammonium carbamic acid, ammonium bicarbonate, polyamides, amino borates, alkylanolamines, nitrites, amides, amino phosphates and mixtures thereof; in an amount of 10 to 300 percent by weight, percentage based on the weight of urea.
Claim 4
Dependent Claim
39 words
The flame retardant composition of claim 1 wherein the carbonization auxiliaries are selected from the group consisting of phosphorus containing compounds, boron containing compounds, boron-phosphate containing compounds and sulfur containing compounds that produce acidic components in the pyrolysis mixture.
Claim 5
Dependent Claim
73 words
The flame retardant composition of claim 1 wherein the filler is selected from the group consisting of urea, melamine, dicyandiamide, melamine cyanurate, amino phosphates, aminopolyphosphates, aminoplasts, phenoplasts, powdered synthetic resins, sawdust, carbohydrates, bituminous additives, graphite, graphite compounds, cyanuric derivatives or their formaldehyde resins, powdered coke, silica, alkali metal silicates, alkaline earth metal silicates, metals, metal silicates, oxides, carbonates, sulphates, phosphates and borates, glass beads, hollow glass beads, hydrated aluminum oxide and mixtures thereof.
Claim 6
Dependent Claim
14 words
The flame retardant composition of claim 1 wherein the aldehyde is an aqueous formaldehyde.
Claim 7
Dependent Claim
22 words
The flame retardant composition of claim 1 wherein the partiallly hydrolyzed amino condensation compound is a partially hydrolyzed urea-ammonium carbamate condensation compound.
Claim 8
Dependent Claim
21 words
The flame retardant composition of claim 1 wherein the partially hydrolyzed amino condensation compound is a partially hydrolyzed urea-melamine condensation compound.
Claim 9
Dependent Claim
21 words
The flame retardant composition of claim 1 wherein the partially hydrolyzed amino condensation compound is a partially hydrolyzed urea-dicyandiamide condensation compound.
Claim 10
Dependent Claim
16 words
The flame retardant composition of claim 1 wherein the carbonization auxiliaries is a phosphorus containing compound.
Claim 11
Dependent Claim
17 words
The flame retardant composition of claim 9 wherein the phosphorus containing compound is an acidic phosphorus compound.
Claim 12
Dependent Claim
18 words
The flame retardant composition of claim 9 wherein the phosphorus containing compound is an organic phosphorus containing compound.
Claim 13
Dependent Claim
35 words
The flame retardant composition of claim 1 wherein the partially hydrolyzed amino condensation composition is utilized in an amount of 10 to 200 percent by weight, percentage based on the weight of the organic material.
Claim 14
Dependent Claim
18 words
The flame retardant composition of claim 1 wherein the partially hydrolyzed amino condensation composition is urea-guanidine condensation compound.
Claim 15
Dependent Claim
16 words
The flame retardant composition of claim 11 wherein the organic phosphorus compound is dimethyl methyl phosphonate.
Claim 16
Dependent Claim
15 words
The flame retardant composition of claim 10 wherein the acidic phosphorus compound is phosphoric acid.
Claim 17
Dependent Claim
15 words
The flame retardant composition of claim 1 wherein the organic material is a polyurethane material.
Claim 18
Dependent Claim
20 words
The flame retardant composition of claim 1 wherein the organic material is an unsaturated polyester resin and a polyester catalyst.
Claim 19
Dependent Claim
19 words
The flame retardant composition of claim 1 wherein the organic material is a polyepoxy resin and a polyepoxy catalyst.
Claim 20
Dependent Claim
15 words
The flame retardant composition of claim 1 wherein the organic material is a thermoplastic resin.
Claim 21
Independent Claim
177 words
A method of reducing the combustibility of an organic material comprising incorporating a partially hydrolyzed amino condensation composition with the organic material, under reaction conditions of the organic material, said partially amino condensation composition produced by the method comprising of mixing, heating and reacting the following components: (A) urea; in the amount of 100 parts by weight; (B) nitrogen containing compound that will condensate and/or react with isocyanic and/or cyanic acid produced by heating a urea compound; in the amount of 10 to 300 percent by weight, percentage based on the weight of urea; (C) water; in the amount of 10 to 40 parts by weight; (D) aldehyde; (E) carbonization auxiliaries; (F) filler; component A with itself or component A and B are first reacted to produce an amino condensation compound, then component C is added, mixed, heated and reacted thereby producing a partially hydrolyzed amino condensation compound, then component D is added and reacted thereby producing a partially hydrolyzed amino condensation-aldehyde resin, then component E is added then mixed and/or reacted, then component F is added.
Claim 22
Independent Claim
177 words
A method of reducing the combustibility of an organic material comprising incorporating a partially hydrolyzed amino condensation composition with the organic material, under reaction conditions of the organic material, said partially amino condensation composition produced by the method comprising of mixing, heating and reacting the following components: (A) urea; in the amount of 100 parts by weight; (B) nitrogen containing compound that will condensate and/or react with isocyanic and/or cyanic acid produced by heating a urea compound; in the amount of 10 to 300 percent by weight, percentage based on the weight of urea; (C) water; in the amount of 10 to 40 parts by weight; (D) aldehyde; (E) carbonization auxiliaries; (F) filler; component A with itself or component A and B are first reacted to produce an amino condensation compound, then component C is added, mixed, heated and reacted thereby producing a partially hydrolyzed amino condensation compound, then component D is added and reacted thereby producing a partially hydrolyzed amino condensation-aldehyde resin, then component E is added then mixed and/or reacted, then component F is added.
Claim 23
Dependent Claim
39 words
The method of claim 20 wherein the partially hydrolyzed amino condensation composition is a partially hydrolyzed urea condensation compound having the general formula of: (NH.sub.4 OOC--).sub.n (--NHCO--).sub.y wherein n is a number 1-3 and y is a number 1-8.
Claim 24
Dependent Claim
45 words
The method of claim 20 wherein the partially hydrolyzed amino condensation composition is a partially hydrolyzed urea-amino condensation compound having the general formula of: (NH.sub.4 OOC--).sub.n (--NHCO--).sub.y (NHCH--).sub.z wherein n is a number 1-3, y is a number 1-8 and z is a number 0-8.
Claim 25
Dependent Claim
17 words
The method of claim 20 wherein the amino condensation composition is a partially hydrolyzed urea-melamine condensation compound.
Claim 26
Dependent Claim
57 words
A flame retardant composition produced by incorporating a partially hydrolyzed amino condensation compound in an organic material, under reaction conditions and in an amount sufficient to reduce the combustibility of the organic material, said amino condensation compound is produced by reacting 100 parts by weight of urea with 10-40 parts by weight of water under reaction conditions.
Claim 27
Dependent Claim
57 words
A flame retardant composition produced by incorporating a partially hydrolyzed amino condensation compound in an organic material, under reaction conditions and in an amount sufficient to reduce the combustibility of the organic material, said amino condensation compound is produced by reacting 100 parts by weight of urea with 10-40 parts by weight of water under reaction conditions.
Claim 28
Dependent Claim
91 words
A flame retardant partially hydrolyzed amino compound produced by the process comprising of mixing, heating and reacting the following components: (A) urea; in the amount of 100 parts by weight; (B) nitrogen containing compound that will condensate and/or react with heated urea; in an amount of 10 to 300 percent by weight, percentage based on the weight of urea; (C) water; in an amount of 10 to 40 parts by weight; component A and B are first reacted thereby producing an amino condensation compound which is then reacted with component C.
Claim 29
Dependent Claim
91 words
A flame retardant partially hydrolyzed amino compound produced by the process comprising of mixing, heating and reacting the following components: (A) urea; in the amount of 100 parts by weight; (B) nitrogen containing compound that will condensate and/or react with heated urea; in an amount of 10 to 300 percent by weight, percentage based on the weight of urea; (C) water; in an amount of 10 to 40 parts by weight; component A and B are first reacted thereby producing an amino condensation compound which is then reacted with component C.
Claim 30
Dependent Claim
15 words
The flame retardant partially hydrolyzed amino compound of claim 25 wherein component B is urea.
Claim 31
Dependent Claim
15 words
The flame retardant partially hydrolyzed amino compound of claim 25 wherein component B is melamine.
Claim 32
Dependent Claim
117 words
A flame retardant partially hydrolyzed amino condensation-aldehyde resin produced by the process comprising of mixing, heating and reacting the following components: (A) urea; in the amount of 100 parts by weight; (B) nitrogen containing compound that will condensate and/or react with heated urea; in an amount of 10 to 300 percent by weight, percentage based on the weight of urea; (C) water; in an amount of 10 to 40 parts by weight; (D) aldehyde; (E) basic or acidic catalyst; components A and B are first reacted thereby producing an amino condensation compound then component C is added and reacted thereby producing a partially hydrolyzed amino condensation compound, then component D and component E are added and reacted.
Claim 33
Dependent Claim
117 words
A flame retardant partially hydrolyzed amino condensation-aldehyde resin produced by the process comprising of mixing, heating and reacting the following components: (A) urea; in the amount of 100 parts by weight; (B) nitrogen containing compound that will condensate and/or react with heated urea; in an amount of 10 to 300 percent by weight, percentage based on the weight of urea; (C) water; in an amount of 10 to 40 parts by weight; (D) aldehyde; (E) basic or acidic catalyst; components A and B are first reacted thereby producing an amino condensation compound then component C is added and reacted thereby producing a partially hydrolyzed amino condensation compound, then component D and component E are added and reacted.
Claim 34
Dependent Claim
124 words
A flame retardant partially hydrolyzed amino condensation salt of a phosphorus containing compound produced by the process comprising of mixing, heating and reacting the following components: (A) urea; in the amount of 100 parts by weight; (B) nitrogen containing compound that will condensate and/or react with heated urea; in the amount of 10 to 300 percent by weight, percentage based on the weight of urea, (C) water; in an amount of 10 to 40 parts by weight; (D) phosphorus containing compound that will react with partially hydrolyzed amino condensation compound; components A and B are reacted thereby producing an amino condensation compound then component C is added and reacted thereby producing a partially hydrolyses amino condensation compound, then component D is added and reacted.
Claim 35
Dependent Claim
124 words
A flame retardant partially hydrolyzed amino condensation salt of a phosphorus containing compound produced by the process comprising of mixing, heating and reacting the following components: (A) urea; in the amount of 100 parts by weight; (B) nitrogen containing compound that will condensate and/or react with heated urea; in the amount of 10 to 300 percent by weight, percentage based on the weight of urea, (C) water; in an amount of 10 to 40 parts by weight; (D) phosphorus containing compound that will react with partially hydrolyzed amino condensation compound; components A and B are reacted thereby producing an amino condensation compound then component C is added and reacted thereby producing a partially hydrolyses amino condensation compound, then component D is added and reacted.
Claim 36
Dependent Claim
114 words
A flame retardant partially hydrolyzed amino condensation salt of a boron oxyacid compound produced by the process comprising of mixing, heating and reacting the following components: (A) urea; in the amount of 100 parts by weight; (B) nitrogen containing compound that will condensate and/or react with heated urea; in the amount of 10 to 300 percent by weight, percentage based on the weight of urea; (C) water; in an amount of 10 to 40 parts by weight; (D) boron oxyacid; components A and B are reacted thereby producing an amino condensation compound, then component C is added and reacted thereby producing a partially hydrolyzed amino condensation compound, then component D is added and reacted.
Claim 37
Dependent Claim
114 words
A flame retardant partially hydrolyzed amino condensation salt of a boron oxyacid compound produced by the process comprising of mixing, heating and reacting the following components: (A) urea; in the amount of 100 parts by weight; (B) nitrogen containing compound that will condensate and/or react with heated urea; in the amount of 10 to 300 percent by weight, percentage based on the weight of urea; (C) water; in an amount of 10 to 40 parts by weight; (D) boron oxyacid; components A and B are reacted thereby producing an amino condensation compound, then component C is added and reacted thereby producing a partially hydrolyzed amino condensation compound, then component D is added and reacted.
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| 3.5 Years (Year 4) | 2001-08-03 | 2002-02-02 | 2002-08-04 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 2005-08-03 | 2006-02-02 | 2006-08-04 | $3760.00 | Window Closed / Lapsed |
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