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US5773174A Expired / Lapsed US ⏱️ 0.0 years remaining

Method of forming a resist pattern utilizing correlation between latent image height, resist pattern linewidth and surface modification layer width

Assignee: Panasonic Holdings Corp
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Filing: 1997-07-09
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Granted: 1998-06-30
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Expires: 2017-07-09
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Abstract

Abstract A first correlation is obtained which is a correlation between latent image height produced after exposure on a resist layer, and resist pattern linewidth for a given length of develop time. Additionally, a second correlation is obtained which is a correlation between develop time for each exposure energy dose and resist pattern linewidth. The height of a latent image produced on an actually exposed resist layer is determined. From the first correlation, an estimated resist pattern linewidth, which is a resist pattern linewidth corresponding to a latent image height and to a given length of develop time, is found. From the second correlation, an estimated exposure energy dose, which is an exposure energy dose corresponding to a given length of develop time and to an estimated resist patten linewidth, is found. Additionally, also from the second correlation, develop time corresponding to a target resist pattern linewidth and to an estimated exposure energy dose is found, and according to the develop time found, a resist pattern is formed.

Inventors

  • 👤 Taichi Koizumi
  • 👤 Takahiro Matsuo
  • 👤 Masayuki Endo

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-01 20:38
CPC Classifications
G; G03; G03F; G03F7/00; G03F7/70; G03F7/70483; G03F7/70605; G03F7/70653; G03F7/70658; H; H10; H10P; H10P76/00; G03F7/004; G03F7/038; G03F7/20; G03F7/26; G03F7/265; G03F7/30; G03F7/38; G03F7/70675

Claims Analysis

Total Claims: 11
Claim 1
Independent Claim 267 words
A method of forming a resist pattern comprising the steps of: (a) forming a resist layer on a substrate; (b) exposing said resist layer to light to form a predetermined pattern; (c) performing a modification layer formation process to form a surface modification layer locally on said resist layer; and (d) developing said pattern-exposed resist layer for resist pattern formation; (1) determining a height of a latent image formed on said resist layer after said resist layer is exposed to said light: (2) determining a relationship between the height of said latent image and an exposing parameter: (3) determining a relationship between a surface modification layer-width and said exposing parameter: (4) correlating the height of said latent image and surface modification layer-width based on relationships determined in steps (2) and (3) above; (5) determining a first correlation between said height of said latent image and surface modification layer-width: (6) determining a second correlation between the exposing parameter and surface modification layer-width: (7) determining an actual latent-image height produced on an exposed resist layer; (8) estimating from said first correlation a surface modification layer-width that corresponds to said determined actual latent-image height and to a given value of said exposing parameter; (9) estimating from said second correlation an exposing parameter that corresponds to said given value of said exposing parameter and to said estimated resist pattern modification layer-width; (10) determining from said second correlation, a value of said exposing parameter that corresponds to a target surface modification layer-width and to said estimated exposing parameter: and (11) forming, based on said exposing parameter value found, a surface modification layer.
Claim 2
Independent Claim 267 words
A method of forming a resist pattern comprising the steps of: (a) forming a resist layer on a substrate; (b) exposing said resist layer to light to form a predetermined pattern; (c) performing a modification layer formation process to form a surface modification layer locally on said resist layer; and (d) developing said pattern-exposed resist layer for resist pattern formation; (1) determining a height of a latent image formed on said resist layer after said resist layer is exposed to said light: (2) determining a relationship between the height of said latent image and an exposing parameter: (3) determining a relationship between a surface modification layer-width and said exposing parameter: (4) correlating the height of said latent image and surface modification layer-width based on relationships determined in steps (2) and (3) above; (5) determining a first correlation between said height of said latent image and surface modification layer-width: (6) determining a second correlation between the exposing parameter and surface modification layer-width: (7) determining an actual latent-image height produced on an exposed resist layer; (8) estimating from said first correlation a surface modification layer-width that corresponds to said determined actual latent-image height and to a given value of said exposing parameter; (9) estimating from said second correlation an exposing parameter that corresponds to said given value of said exposing parameter and to said estimated resist pattern modification layer-width; (10) determining from said second correlation, a value of said exposing parameter that corresponds to a target surface modification layer-width and to said estimated exposing parameter: and (11) forming, based on said exposing parameter value found, a surface modification layer.
Claim 3
Dependent Claim 36 words
A method of forming a resist pattern according to claim 1, wherein said exposing parameter is either one of a surface modification layer formation process time parameter or a surface modification layer formation process temperature parameter.
Claim 4
Dependent Claim 83 words
A method of forming a resist pattern according to claim 1 wherein said resist layer is composed of a resist which generates an acid when pattern-exposed to light, and wherein said surface modification layer is a metallic oxide layer which is formed such that an exposed portion of said resist layer is made to absorb moisture and then moisture and metallic alkoxide are applied onto a surface of said moisture-containing exposed portion for forming said metallic oxide layer on said exposed portion surface.
Claim 5
Dependent Claim 34 words
A method of forming a resist pattern according to claim 1 wherein said surface modification layer is a silylated layer which is formed on a surface of an unexposed portion of said resist pattern.
Claim 6
Dependent Claim 23 words
A method of forming a resist pattern according to claim 1 wherein said latent image height is determined using an atomic force microscope.
Claim 7
Independent Claim 188 words
A method of forming a resist patten comprising the steps of: (a) pre-obtaining a correlation between the width of a surface modification layer formed on a resist layer and the linewidth of a resist pattern resulting from developing said resist layer having thereon said surface modification layer; (b) forming an actual resist layer on a substrate; (c) exposing said actual resist layer to light to a predetermined pattern; (d) forming an actual surface modification layer on said actual resist layer having said predetermined pattern; (e) determining the width of said actual surface modification layer, and obtaining from said pre-found correlation an estimated linewidth which is a resist pattern-linewidth corresponding to said actual surface modification layer width determined; (f) determining whether said estimated linewidth falls in a range of tolerance limits of a target linewidth, wherein if said estimated linewidth is found to fall in said range a develop process is performed on said actual resist layer to form a resist pattern, while on the other hand if said estimated linewidth is found not to fall in said range said actual resist layer is removed away from said substrate.
Claim 8
Independent Claim 188 words
A method of forming a resist patten comprising the steps of: (a) pre-obtaining a correlation between the width of a surface modification layer formed on a resist layer and the linewidth of a resist pattern resulting from developing said resist layer having thereon said surface modification layer; (b) forming an actual resist layer on a substrate; (c) exposing said actual resist layer to light to a predetermined pattern; (d) forming an actual surface modification layer on said actual resist layer having said predetermined pattern; (e) determining the width of said actual surface modification layer, and obtaining from said pre-found correlation an estimated linewidth which is a resist pattern-linewidth corresponding to said actual surface modification layer width determined; (f) determining whether said estimated linewidth falls in a range of tolerance limits of a target linewidth, wherein if said estimated linewidth is found to fall in said range a develop process is performed on said actual resist layer to form a resist pattern, while on the other hand if said estimated linewidth is found not to fall in said range said actual resist layer is removed away from said substrate.
Claim 9
Dependent Claim 83 words
A method of forming a resist pattern according to claim 6 wherein said resist layer is composed of a resist which generates an acid when pattern-exposed to light, and wherein said surface modification layer is a metallic oxide layer which is formed such that an exposed portion of said resist layer is made to absorb moisture and then moisture and metallic alkoxide are applied onto a surface of said moisture-containing exposed portion for forming said metallic oxide layer on said exposed portion surface.
Claim 10
Dependent Claim 34 words
A method of forming a resist pattern according to claim 6 wherein said surface modification layer is a silylated layer which is formed on a surface of an unexposed portion of said resist pattern.
Claim 11
Dependent Claim 26 words
A method of forming a resist pattern according to claim 6 wherein the width of said surface modification layer is determined using an atomic force microscope.

References Cited (Backward Citations)

US4670650A Cited
JPH03248414A Cited
JPH06267824A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 2001-06-29 2001-12-29 2002-06-30 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 2005-06-29 2005-12-29 2006-06-30 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2009-06-29 2009-12-29 2010-06-30 $7700.00 Window Closed / Lapsed

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