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US5718995A Expired / Lapsed US ⏱️ 0.0 years remaining

Composite support for an imaging element, and imaging element comprising such composite support

Assignee: Eastman Kodak Co
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Filing: 1996-06-12
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Granted: 1998-02-17
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Expires: 2016-06-12
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Abstract

Abstract A composite support for an imaging element is described, which composite support comprises a polymeric film and an electrically conductive layer, wherein the polymeric film comprises a surface which has been activated by energetic treatment, the electrically conductive layer comprises an electrically conductive agent dispersed in an aqueous dispersible polymeric binder comprising an aliphatic, anionic polyurethane having an ultimate elongation to break of at least 350 percent, and the electrically conductive layer is in contiguous contact with the activated surface of the polymeric film. Imaging elements for use in an image-forming process are also described, which element comprise such composite supports and at least one image-forming layer. The invention provides composite supports and imaging elements containing an electrically conductive antistatic layer having excellent adhesion to energetic surface-treated polymer film supports, and of auxiliary layers to the electrically conductive antistatic layer.

Inventors

  • 👤 Dennis John Eichorst
  • 👤 Cathy Ann Fleischer
  • 👤 Jeremy Grace
  • 👤 Paul Daniel Yocobucci

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-27 12:35
CPC Classifications
G; G03; G03G; G03G5/00; G03G5/10; G03G5/104; B; B41; B41M; B41M5/00; B41M5/26; B41M5/40; B41M5/41; G03C; G03C1/00; G03C1/76; G03C1/85

Claims Analysis

Total Claims: 35
Claim 1
Independent Claim 79 words
A composite support for an imaging element, comprising a polymeric film and an electrically conductive layer, wherein the polymeric film comprises a surface which has been activated by energetic treatment, the electrically conductive layer comprises an electrically conductive agent dispersed in an aqueous dispersible polymeric binder comprising an aliphatic, anionic polyurethane having an ultimate elongation to break of at least 350 percent, and the electrically conductive layer is in contiguous contact with the activated surface of the polymeric film.
Claim 2
Dependent Claim 79 words
A composite support for an imaging element, comprising a polymeric film and an electrically conductive layer, wherein the polymeric film comprises a surface which has been activated by energetic treatment, the electrically conductive layer comprises an electrically conductive agent dispersed in an aqueous dispersible polymeric binder comprising an aliphatic, anionic polyurethane having an ultimate elongation to break of at least 350 percent, and the electrically conductive layer is in contiguous contact with the activated surface of the polymeric film.
Claim 3
Dependent Claim 25 words
A composite support according to claim 1 in which the electrically conductive layer is overcoated with at least one auxiliary layer comprising a polymeric binder.
Claim 4
Dependent Claim 36 words
A composite support according to claim 2 wherein the polymeric binder of the auxiliary layer comprises cellulose or a cellulose derivative, a polyurethane, an acrylic or acrylamide polymer, a polycarbonate, a polyester, a polystyrene, or gelatin.
Claim 5
Dependent Claim 26 words
A composite support according to claim 3 wherein the polymeric binder of the auxiliary layer comprises cellulose nitrate, cellulose diacetate, cellulose triacetate, or cellulose acetate butyrate.
Claim 6
Dependent Claim 18 words
A composite support according to claim 3 wherein the polymeric binder of the auxiliary layer comprises a polyurethane.
Claim 7
Dependent Claim 21 words
A composite support according to claim 3 wherein the polymeric binder of the auxiliary layer comprises an acrylic or acrylamide polymer.
Claim 8
Dependent Claim 18 words
A composite support according to claim 3 wherein the polymeric binder of the auxiliary layer comprises a polycarbonate.
Claim 9
Dependent Claim 18 words
A composite support according to claim 3 wherein the polymeric binder of the auxiliary layer comprises a polyester.
Claim 10
Dependent Claim 18 words
A composite support according to claim 3 wherein the polymeric binder of the auxiliary layer comprises a polystyrene.
Claim 11
Dependent Claim 18 words
A composite support according to claim 2 in which the auxiliary layer is a transparent magnetic recording layer.
Claim 12
Dependent Claim 30 words
A composite support according to claim 10 wherein the transparent magnetic recording layer comprises Fe 2 O 3 or Fe 3 O 4 magnetic particles dispersed in a polymeric binder.
Claim 13
Dependent Claim 49 words
A composite support according to claim 1 wherein the electrically conductive agent comprises fine particles of ZnO, TiO 2 , SnO 2 , Al 2 O 3 , In 2 O 3 , SiO 2 , MgO, BaO, MOO 3 , WO 3 , or a compound oxide thereof.
Claim 14
Dependent Claim 73 words
A composite support according to claim 1 wherein the electrically conductive agent comprises: ZnO which contains from 0.01 mole % to 30 mole % of a dopant comprising Al or In; SnO 2 which contains from 0.01 mole % to 30 mole % of a dopant comprising Sb, Nb, or a halogen atom; or TiO 2 which contains from 0.01 mole % to 30 mole % of a dopant comprising Nb or Ta.
Claim 15
Dependent Claim 56 words
A composite support according to claim 1 wherein the electrically conductive agent comprises antimony doped SnO 2 at an antimony doping level of at least 8 atom % and having an X-ray crystallite size less than 100 Å and an average equivalent circular diameter less than 15 nm but no less than the X-ray crystallite size.
Claim 16
Dependent Claim 18 words
A composite support according to claim 1 wherein the electrically conductive agent comprises electrically conductive metal antimonate particles.
Claim 17
Dependent Claim 18 words
A composite support according to claim 15 wherein the electrically conductive agent comprises zinc antimonate or indium antimonate.
Claim 18
Dependent Claim 16 words
A composite support according to claim 1 wherein the electrically conductive agent comprises vanadium oxide gel.
Claim 19
Dependent Claim 17 words
A composite support according to claim 17 wherein the vanadium oxide gel comprises silver doped vanadium pentoxide.
Claim 20
Dependent Claim 16 words
A composite support according to claim 1 wherein the electrically conductive agent comprises conductive carbon fibers.
Claim 21
Dependent Claim 15 words
A composite support according to claim 1 wherein the polymeric film is a polyester film.
Claim 22
Dependent Claim 17 words
A composite support according to claim 20 wherein the polymeric film comprises polyethylene terephthalate or polyethylene naphthalate.
Claim 23
Dependent Claim 16 words
A composite support according to claim 1 wherein the polymeric film has been surface-treated by corona-discharge.
Claim 24
Dependent Claim 16 words
A composite support according to claim 1 wherein the polymeric film has been surface-treated by glow-discharge.
Claim 25
Dependent Claim 22 words
A composite support according to claim 23 wherein the glow-discharge atmosphere comprised oxygen, nitrogen, helium, argon, carbon dioxide, ammonia, or water vapor.
Claim 26
Dependent Claim 15 words
A composite support according to claim 23 wherein the glow-discharge atmosphere comprised oxygen or nitrogen.
Claim 27
Dependent Claim 19 words
A composite support according to claim 1 wherein the polymeric film has been surface-treated by exposure to ultraviolet radiation.
Claim 28
Dependent Claim 86 words
An imaging element for use in an image-forming process, comprising a support, an image-forming layer, and an electrically conductive layer, wherein the support comprises a polymeric film having a surface which has been activated by energetic treatment, the the electrically conductive layer comprises an electrically conductive agent dispersed in an aqueous dispersible polymeric binder comprising an aliphatic, anionic polyurethane having an ultimate elongation to break of at least 350 percent, and the electrically conductive layer is in contiguous contact with the activated surface of the support.
Claim 29
Dependent Claim 86 words
An imaging element for use in an image-forming process, comprising a support, an image-forming layer, and an electrically conductive layer, wherein the support comprises a polymeric film having a surface which has been activated by energetic treatment, the the electrically conductive layer comprises an electrically conductive agent dispersed in an aqueous dispersible polymeric binder comprising an aliphatic, anionic polyurethane having an ultimate elongation to break of at least 350 percent, and the electrically conductive layer is in contiguous contact with the activated surface of the support.
Claim 30
Dependent Claim 26 words
An imaging element according to claim 27 in which the electrically conductive layer and the image forming layer are on the same side of the support.
Claim 31
Dependent Claim 24 words
An imaging element according to claim 27 in which the electrically conductive layer and image forming layer are on opposite sides of the support.
Claim 32
Dependent Claim 20 words
An imaging element according to claim 27 in which the image forming layer comprises silver halide grains dispersed in gelatin.
Claim 33
Dependent Claim 120 words
A photographic imaging element comprising a polyester film support, at least one photographic image recording layer comprised of silver halide grains dispersed in a gelatin binder on one side of the support, an electrically conductive layer on the side of the support opposite to the image recording layer, and a transparent magnetic recording layer overlying the electrically conductive layer, wherein the support comprises a surface which has been activated by energetic treatment, the electrically conductive layer comprises an electrically conductive agent dispersed in an aqueous dispersible polymeric binder comprising an aliphatic, anionic polyurethane having an ultimate elongation to break of at least 350 percent, and the electrically conductive layer is in contiguous contact with the activated surface of the support.
Claim 34
Dependent Claim 120 words
A photographic imaging element comprising a polyester film support, at least one photographic image recording layer comprised of silver halide grains dispersed in a gelatin binder on one side of the support, an electrically conductive layer on the side of the support opposite to the image recording layer, and a transparent magnetic recording layer overlying the electrically conductive layer, wherein the support comprises a surface which has been activated by energetic treatment, the electrically conductive layer comprises an electrically conductive agent dispersed in an aqueous dispersible polymeric binder comprising an aliphatic, anionic polyurethane having an ultimate elongation to break of at least 350 percent, and the electrically conductive layer is in contiguous contact with the activated surface of the support.
Claim 35
Dependent Claim 30 words
A photographic imaging element according to claim 31, further comprising a permeability control layer for reduced water permeability coated between the electrically conductive layer and the transparent magnetic recording layer.

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Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 2001-02-16 2001-08-18 2002-02-17 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 2005-02-16 2005-08-18 2006-02-17 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2009-02-16 2009-08-18 2010-02-17 $7700.00 Window Closed / Lapsed

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