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US5360707A Expired / Lapsed US ⏱️ 0.0 years remaining

Photographic printing paper support

Assignee: Fujifilm Holdings Corp
•
Filing: 1993-12-20
•
Granted: 1994-11-01
•
Expires: 2013-12-20
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Abstract

Abstract Disclosed is a photographic printing paper support comprising a waterproof substrate constituted of raw paper and polyolefin resin coats covering the both surfaces thereof, which further has on the back side of the substrate a backing layer containing at least (a) colloidal silica, (b) an aqueous dispersion of a styrene-acrylate copolymer prepared by the polymerization in the presence of a water-soluble high-molecular compound, (c) at least one substance selected from a group consisting of carboxyl or sulfo group-containing water-soluble high-molecular compounds, the metal salts thereof and hydrophilic organic high-molecular colloidal substances and (d) an aqueous dispersion of a polyolefin resin having a melting point below 100°C.

Inventors

  • 👤 Atsushi Kato
  • 👤 Sei Kawahara
  • 👤 Yasuo Iwasaki

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-25 19:56
CPC Classifications
G; G03; G03C; G03C1/00; G03C1/76; G03C1/7614; D; D21; D21H; D21H19/00; D21H19/80; D21H19/84; G03C1/775; G03C1/79; G03C1/95; Y; Y10; Y10T; Y10T428/00; Y10T428/25; Y10T428/256; Y10T428/258; Y10T428/26; Y10T428/31504; Y10T428/31855; Y10T428/3188; Y10T428/31895

Claims Analysis

Total Claims: 20
Claim 1
Independent Claim 106 words
A photographic printing paper support comprising a waterproof substrate constituted of raw paper and polyolefin resin coats covering the both surfaces thereof, said support further having on the back side of the substrate a backing layer containing at least (a) colloidal silica, (b) an aqueous dispersion of a styrene-acrylate copolymer prepared by the polymerization in the presence of a water-soluble high-molecular compound, (c) at least one substance selected from a group consisting of carboxyl or sulfo group-containing water-soluble high-molecular compounds, the metal salts thereof and hydrophilic organic high-molecular colloidal substances and (d) an aqueous dispersion of a polyolefin resin having a melting point below 100° C.
Claim 2
Dependent Claim 106 words
A photographic printing paper support comprising a waterproof substrate constituted of raw paper and polyolefin resin coats covering the both surfaces thereof, said support further having on the back side of the substrate a backing layer containing at least (a) colloidal silica, (b) an aqueous dispersion of a styrene-acrylate copolymer prepared by the polymerization in the presence of a water-soluble high-molecular compound, (c) at least one substance selected from a group consisting of carboxyl or sulfo group-containing water-soluble high-molecular compounds, the metal salts thereof and hydrophilic organic high-molecular colloidal substances and (d) an aqueous dispersion of a polyolefin resin having a melting point below 100° C.
Claim 3
Dependent Claim 29 words
The photographic printing paper support of claim 1, said backing layer further containing as a hardener a compound having at least two ethyleneimino or glycidyl ether groups per molecule.
Claim 4
Dependent Claim 32 words
The photographic printing paper support of claim 1, wherein the coverage of colloidal silica as the component (a) is in the range of 0.04 to 1.0 g/m 2 on a solids basis.
Claim 5
Dependent Claim 33 words
The photographic printing paper support of claim 1, wherein the coverage of the aqueous dispersion as the component (b) is in the range of 0.05 to 2.0 g/m 2 on a solids basis.
Claim 6
Dependent Claim 32 words
The photographic printing paper support of claim 1, wherein the coverage of the substance as the component (c) is in the range of 0.01 to 1.0 g/m 2 on a solids basis.
Claim 7
Dependent Claim 33 words
The photographic printing paper support of claim 1, wherein the coverage of the aqueous dispersion as the component (d) is in the range of 0.01 to 1.0 g/m 2 on a solids basis.
Claim 8
Dependent Claim 25 words
The photographic printing paper support of claim 1, wherein the components (a), (b), (c) and (d) are contained at the ratio of (a)/(b)/(c)/(d)=(2-10)/(4-15)/(1-3)/(1-3) by weight.
Claim 9
Dependent Claim 26 words
The photographic printing paper support of claim 1, wherein the ratio of styrene to acrylate in the styrene-acrylate copolymer ranges from 90/10 to 10/90 by mole.
Claim 10
Dependent Claim 31 words
The photographic printing paper support of claim 1, wherein the acrylate in the styrene-acrylate copolymer is an ester of acrylic acid and an aliphatic alcohol containing 1 to 8 carbon atoms.
Claim 11
Dependent Claim 22 words
The photographic printing paper support of claim 1, wherein the water-soluble high-molecular compound present in the polymerization is a styrene-maleic acid copolymer.
Claim 12
Dependent Claim 20 words
The photographic printing paper support of claim 1, wherein the copolymer has a molecular weight of from 2,000 to 150,000.
Claim 13
Dependent Claim 32 words
The photographic printing paper support of claim 11, wherein the carboxyl group-containing water-soluble high-molecular compound is a copolymer of maleic anhydride and an unsaturated copolymerizable monomer containing at least 4 carbon atoms.
Claim 14
Dependent Claim 20 words
The photographic printing paper support of claim 1, wherein the high-molecular compound has a molecular weight of 5,000 to 1,000,000.
Claim 15
Dependent Claim 27 words
The photographic printing paper support of claim 13, wherein the sulfo group-containing water-soluble high-molecular compound is polystyrenesulfonic acid, polyvinylbenzylsulfonic acid or the sodium or potassium salt thereof.
Claim 16
Dependent Claim 34 words
The photographic printing paper support of claim 1, wherein the hydrophilic organic high-molecular colloidal substance is an aqueous solution or dispersion of a carboxyl-modified polyethylene or the alkali metal, ammonium or amine salt thereof.
Claim 17
Dependent Claim 52 words
The photographic printing paper support of claim 1, wherein the polyolefin resin having a melting point below 100° C. is selected from among an ethylene-acrylic acid copolymer resin, an ethylene-maleic acid copolymer resin, an ethylene-acrylate copolymer resin and polyolefin resins modified by hydroxyl, carboxyl, amino, amido, epoxy, alkoxysilane, urethane or isocyanate groups.
Claim 18
Dependent Claim 18 words
The photographic printing paper support of claim 16, wherein the polyolefin resin is an ethylene-acrylic acid copolymer resin.
Claim 19
Dependent Claim 35 words
The photographic printing paper support of claim 1, wherein the polyolefin resin having a melting point of below 100° C. has a particle size of from 0.01 to 0.5 μm in the aqueous dispersion thereof.
Claim 20
Dependent Claim 19 words
The photographic printing paper support of claim 1, the backing layer having a thickness of 0.1 to 3 μm.

References Cited (Backward Citations)

US4220471A Cited
US4675295A Cited
US4705746A Cited
JPS626256A Cited
US4858773A Cited
JPH0328696A Cited
US5156707A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1997-10-31 1998-05-02 1998-11-01 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 2001-10-31 2002-05-02 2002-11-01 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2005-10-31 2006-05-02 2006-11-01 $7700.00 Window Closed / Lapsed

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