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US5635425A Expired / Lapsed US ⏱️ 0.0 years remaining

In-situ N2 plasma treatment for PE TEOS oxide deposition

Assignee: Industrial Technology Research Institute
•
Filing: 1995-05-25
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Granted: 1997-06-03
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Expires: 2015-05-25
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Abstract

Abstract A method for avoiding separation between a TEOS layer and the underlying dielectric layer is described, A first dielectric layer is deposited over semiconductor device structures in and on a semiconductor substrate and planarized. A conducting layer is deposited overlying the first dielectric layer and patterned thereby exposing portions of the first dielectric layer, The exposed portions of the first dielectric layer are treated with N 2 plasma, A second dielectric layer is deposited overlying the patterned conducting layer and the exposed portions of the first dielectric layer, The treating of the exposed portions of the first dielectric layer with N 2 plasma improves adhesion between the second dielectric layer and the exposed portions of the first dielectric layer,

Inventors

  • 👤 Lai-Juh Chen

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-03 12:24
CPC Classifications
H; H10; H10W; H10W20/00; H10W20/01; H10W20/071; H10P; H10P95/00; H10W20/074; H10W20/093; H10W20/096

Claims Analysis

Total Claims: 33
Claim 1
Independent Claim 115 words
A method of improving dielectric to dielectric adhesion in the manufacture of an integrated circuit comprising: providing semiconductor device structures in and on a semiconductor substrate; depositing a first dielectric layer overlying said semiconductor device structures and planarizing said first dielectric layer; depositing a conducting layer overlying said first dielectric layer and patterning said conducting layer wherein portions of said first dielectric layer are exposed; depositing a second dielectric layer overlying said patterned conducting layer and said exposed portions of said first dielectric layer wherein a simultaneous N 2 plasma treatment improves adhesion between said second dielectric layer and said exposed portions of said first dielectric layer; and completing the fabrication of said integrated circuit.
Claim 2
Independent Claim 115 words
A method of improving dielectric to dielectric adhesion in the manufacture of an integrated circuit comprising: providing semiconductor device structures in and on a semiconductor substrate; depositing a first dielectric layer overlying said semiconductor device structures and planarizing said first dielectric layer; depositing a conducting layer overlying said first dielectric layer and patterning said conducting layer wherein portions of said first dielectric layer are exposed; depositing a second dielectric layer overlying said patterned conducting layer and said exposed portions of said first dielectric layer wherein a simultaneous N 2 plasma treatment improves adhesion between said second dielectric layer and said exposed portions of said first dielectric layer; and completing the fabrication of said integrated circuit.
Claim 3
Dependent Claim 14 words
A method according to claim 1 wherein said first dielectric layer comprises borophosphosilicate glass.
Claim 4
Dependent Claim 37 words
A method according to claim 2 wherein said first dielectric layer is planarized by flowing said layer at a temperature of between about 900° to 1100° C. for a duration of between about 30 to 60 minutes.
Claim 5
Dependent Claim 14 words
A method according to claim 1 wherein said first dielectric layer comprises phosphosilicate glass.
Claim 6
Dependent Claim 37 words
A method according to claim 4 wherein said first dielectric layer is planarized by flowing said layer at a temperature of between about 900° to 1100° C. for a duration of between about 30 to 60 minutes.
Claim 7
Dependent Claim 13 words
A method according to claim 1 wherein said first dielectric layer comprises spin-on-glass.
Claim 8
Dependent Claim 20 words
A method according to claim 6 wherein said first dielectric layer is planarized by etching back said first dielectric layer.
Claim 9
Dependent Claim 37 words
A method according to claim 1 wherein said planarizing of said first dielectric layer produces impurities on the surface of said first dielectric layer and wherein said impurities impede adhesion between said first and second dielectric layers.
Claim 10
Dependent Claim 18 words
A method according to claim 8 wherein said impurities are removed by said simultaneous N 2 plasma treatment.
Claim 11
Dependent Claim 74 words
A method according to claim 1 wherein said second dielectric layer is deposited by flowing O 2 at the rate of 200 to 600 sccm, TEOS at the rate of 600 to 1000 sccm, and N 2 at the rate of 200 to 400 sccm at a temperature of between about 350° to 450° C. under pressure of between about 7 to 9 Torr for a duration of between about 30 to 50 seconds.
Claim 12
Dependent Claim 55 words
A method according to claim 10 wherein said second dielectric layer is deposited anisotropically whereby the thickness of said second dielectric layer is relatively greater on the horizontal surfaces of said patterned conducting layer and said exposed portions of said first dielectric layer than it is on the vertical surfaces of said patterned conducting layer.
Claim 13
Independent Claim 200 words
A method of improving dielectric to dielectric adhesion in the manufacture of an integrated circuit comprising: providing semiconductor device structures in and on a semiconductor substrate; depositing a first dielectric layer overlying said semiconductor device structures and planarizing said first dielectric layer wherein said planarizing produces impurities on the surface of said first dielectric layer and wherein said impurities impede adhesion between said first dielectric layer and a second dielectric layer; depositing a conducting layer overlying said first dielectric layer and patterning said conducting layer wherein portions of said first dielectric layer are exposed; depositing said second dielectric layer overlying said patterned conducting layer and said exposed portions of said first dielectric layer wherein a simultaneous N 2 plasma treatment removes said impurities and consequently improves said adhesion between said second dielectric layer and said exposed portions of said first dielectric layer and wherein said second dielectric layer is deposited anisotropically whereby the thickness of said second dielectric layer is relatively greater on the horizontal surfaces of said patterned conducting layer and said exposed portions of said first dielectric layer than it is on the vertical surfaces of said patterned conducting layer; and completing the fabrication of said integrated circuit.
Claim 14
Independent Claim 200 words
A method of improving dielectric to dielectric adhesion in the manufacture of an integrated circuit comprising: providing semiconductor device structures in and on a semiconductor substrate; depositing a first dielectric layer overlying said semiconductor device structures and planarizing said first dielectric layer wherein said planarizing produces impurities on the surface of said first dielectric layer and wherein said impurities impede adhesion between said first dielectric layer and a second dielectric layer; depositing a conducting layer overlying said first dielectric layer and patterning said conducting layer wherein portions of said first dielectric layer are exposed; depositing said second dielectric layer overlying said patterned conducting layer and said exposed portions of said first dielectric layer wherein a simultaneous N 2 plasma treatment removes said impurities and consequently improves said adhesion between said second dielectric layer and said exposed portions of said first dielectric layer and wherein said second dielectric layer is deposited anisotropically whereby the thickness of said second dielectric layer is relatively greater on the horizontal surfaces of said patterned conducting layer and said exposed portions of said first dielectric layer than it is on the vertical surfaces of said patterned conducting layer; and completing the fabrication of said integrated circuit.
Claim 15
Dependent Claim 13 words
The method of claim 12 wherein said first dielectric layer comprises borophosphosilicate glass.
Claim 16
Dependent Claim 36 words
The method of claim 13 wherein said first dielectric layer is planarized by flowing said layer at a temperature of between about 900° to 1100° C. for a duration of between about 30 to 60 minutes.
Claim 17
Dependent Claim 13 words
The method of claim 12 wherein said first dielectric layer comprises phosphosilicate glass.
Claim 18
Dependent Claim 36 words
The method of claim 15 wherein said first dielectric layer is planarized by flowing said layer at a temperature of between about 900° to 1100° C. for a duration of between about 30 to 60 minutes.
Claim 19
Dependent Claim 13 words
A method according to claim 12 wherein said first dielectric layer comprises spin-on-glass.
Claim 20
Dependent Claim 20 words
A method according to claim 17 wherein said first dielectric layer is planarized by etching back said first dielectric layer.
Claim 21
Dependent Claim 74 words
A method according to claim 12 wherein said second dielectric layer is deposited by flowing O 2 at the rate of 200 to 600 sccm, TEOS at the rate of 600 to 1000 sccm, and N 2 at the rate of 200 to 400 sccm at a temperature of between about 350° to 450° C. under pressure of between about 7 to 9 Torr for a duration of between about 30 to 50 seconds.
Claim 22
Independent Claim 194 words
A method of improving dielectric to dielectric adhesion in the manufacture of an integrated circuit comprising: providing semiconductor device structures in and on a semiconductor substrate; depositing a first dielectric layer overlying said semiconductor device structures and planarizing said first dielectric layer; depositing a conducting layer overlying said first dielectric layer and patterning said conducting layer wherein portions of said first dielectric layer are exposed; treating said exposed portions of said first dielectric layer with N 2 plasma thereby forming a depletion surface layer in said first dielectric layer wherein said treating with said N 2 plasma is performed at a temperature of between about 350° to 450° C.; thereafter depositing a second dielectric layer overlying said patterned conducting layer and said exposed portions of said first dielectric layer at a temperature of between about 350° to 450° C. wherein said temperature is 10° to 20° C. lower than previous said treating with said N 2 plasma and wherein said treating with said N 2 plasma and said depletion layer improve adhesion between said second dielectric layer and said exposed portions of said first dielectric layer; and completing the fabrication of said integrated circuit.
Claim 23
Independent Claim 194 words
A method of improving dielectric to dielectric adhesion in the manufacture of an integrated circuit comprising: providing semiconductor device structures in and on a semiconductor substrate; depositing a first dielectric layer overlying said semiconductor device structures and planarizing said first dielectric layer; depositing a conducting layer overlying said first dielectric layer and patterning said conducting layer wherein portions of said first dielectric layer are exposed; treating said exposed portions of said first dielectric layer with N 2 plasma thereby forming a depletion surface layer in said first dielectric layer wherein said treating with said N 2 plasma is performed at a temperature of between about 350° to 450° C.; thereafter depositing a second dielectric layer overlying said patterned conducting layer and said exposed portions of said first dielectric layer at a temperature of between about 350° to 450° C. wherein said temperature is 10° to 20° C. lower than previous said treating with said N 2 plasma and wherein said treating with said N 2 plasma and said depletion layer improve adhesion between said second dielectric layer and said exposed portions of said first dielectric layer; and completing the fabrication of said integrated circuit.
Claim 24
Dependent Claim 14 words
A method according to claim 20 wherein said first dielectric layer comprises borophosphosilicate glass.
Claim 25
Dependent Claim 37 words
A method according to claim 21 wherein said first dielectric layer is planarized by flowing said layer at a temperature of between about 900° to 1100° C. for a duration of between about 30 to 60 minutes.
Claim 26
Dependent Claim 14 words
A method according to claim 20 wherein said first dielectric layer comprises phosphosilicate glass.
Claim 27
Dependent Claim 37 words
A method according to claim 23 wherein said first dielectric layer is planarized by flowing said layer at a temperature of between about 900° to 1100° C. for a duration of between about 30 to 60 minutes.
Claim 28
Dependent Claim 13 words
A method according to claim 20 wherein said first dielectric layer comprises spin-on-glass.
Claim 29
Dependent Claim 20 words
A method according to claim 25 wherein said first dielectric layer is planarized by etching back said first dielectric layer.
Claim 30
Dependent Claim 37 words
A method according to claim 20 wherein said planarizing of said first dielectric layer produces impurities on the surface of said first dielectric layer and wherein said impurities impede adhesion between said first and second dielectric layers.
Claim 31
Dependent Claim 27 words
A method according to claim 20 wherein said impurities are removed by said treating of said exposed portions of said first dielectric layer with N 2 plasma.
Claim 32
Dependent Claim 51 words
A method according to claim 20 wherein said treating with N 2 plasma comprises flowing said N 2 plasma at a rate of between about 100 to 400 sccm at a temperature of between about 10° to 20° C. greater than the temperature of subsequent depositing of said second dielectric layer.
Claim 33
Dependent Claim 54 words
A method according to claim 20 wherein said second dielectric layer is deposited by flowing O 2 at the rate of 200 to 600 sccm and TEOS at the rate of 600 to 1000 sccm under pressure of between about 7 to 9 Torr for a duration of between about 30 to 50 seconds.

References Cited (Backward Citations)

US4872947A Cited
US5219774A Cited
US4894352A Cited
US5013691A Cited
US5334554A Cited
US5356722A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 2000-06-02 2000-12-02 2001-06-03 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 2004-06-02 2004-12-02 2005-06-03 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2008-06-02 2008-12-02 2009-06-03 $7700.00 Window Closed / Lapsed

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