Toner for developing electrostatic images, image forming method and process cartridge

Claim 2

A toner for developing electrostatic images, comprising: (i) a binder resin; (ii) a colorant; and (iii) a compound made by a reaction of a monohydroxylic compound having a long-chain alkyl group having an alkylene group with 40 or more carbon atoms and a hydroxyl group with a carboxylic acid having a molecular weight of 1,000 or less, said carboxylic acid being selected from the group consisting of formic acid, acetic acid, propionic acid, lactic acid, isolactic acid, valeric acid, pivalic acid, lauric acid, myristic acid, palmitic acid, stearic acid, acrylic acid, propionic acid, methacrylic acid, crotonic acid, oleic acid, furoic acid, nicotinic acid, isonicotinic acid, fumaric acid, maleic acid, citraconic acid, itaconic acid, succinic acid, adipic acid, sebacic acid, azelaic acid, benzoic acid, toluic acid, naphthoic acid, cinnamic acid, phthalic acid, terephthalic acid, trimellitic acid, pyromellitic acid, and acid anhydrides thereof, or a compound made by a reaction of a monocarboxylic compound having a long-chain alkyl group having an alkylene group with 40 or more carbon atoms and a carboxyl group with an alcohol having a molecular weight of 1,000 or less, said alcohol being selected from the group consisting of methyl alcohol, ethyl alcohol, propyl alcohol, isopropyl alcohol, butyl alcohol, isobutyl alcohol, sec-butyl alcohol, tert-butyl alcohol, n-amyl alcohol, isoamyl alcohol, hexyl alcohol, heptyl alcohol, octyl alcohol, capryl alcohol, allyl alcohol, crotyl alcohol, propargyl alcohol, cyclopentanol, cyclohexanol, benzyl alcohol, cinnamyl alcohol, furfuryl alcohol, ethylene glycol, propylene glycol, 1, 3-butanediol, 1,4-butanediol, 2,3-butanediol, diethylene glycol, dipropylene glycol, triethylene glycol, 1,5-pentanediol, 1,6-hexanediol, neopentyl glycol, pentaerythritol diallyl ether, trimethylene glycol, 2-ethyl-1, 3-hexanediol, hydrogenated bisphenol A and a bisphenol derivative represented by the formula: ##STR30## wherein R is an ethylene group or a propylene group and x and y are each an integer of 1 or more, and total 2 to 10.

Claim 3

The toner according to claim 1, wherein the alkylene group has carbon atoms of from 40 to 200.

Claim 4

The toner according to claim 1, wherein the alkylene group has carbon atoms of from 50 to 150.

Claim 5

The toner according to claim 1, wherein the monohydroxylic compound has a number average molecular weight (Mn) of 592 or more.

Claim 6

The toner according to claim 1, wherein the monohydroxylic compound has a number average molecular weight (Mn) of from 592 to 2,832.

Claim 7

The toner according to claim 1, wherein the monocarboxylic compound has a number average molecular weight (Mn) of 620 or more.

Claim 8

The toner according to claim 1, wherein the monocarboxylic compound has a number average molecular weight (Mn) of from 620 to 2,860.

Claim 9

The toner according to claim 1, wherein the compound made by the reaction of the monohydroxylic compound with the carboxylic acid has a number average molecular weight (Mn) of 1,550 or more, and a weight average molecular weight (Mw) of 1,550 or more.

Claim 10

The toner according to claim 1, wherein the compound made by the reaction of the monohydroxylic compound with the carboxylic acid has a number average molecular weight (Mn) of from 1,550 to 7,000 or more, and a weight average molecular weight (Mw) of from 1,550 to 7,000.

Claim 11

The toner according to claim 1, wherein the compound made by the reaction of the monocarboxylic compound with the alcohol has a number average molecular weight (Mn) of 1,550 or more, and a weight average molecular weight (Mw) of 1,550 or more.

Claim 12

The toner according to claim 1, wherein the compound made by the reaction of the monocarboxylic compound with the alcohol has a number average molecular weight (Mn) of from 1,550 to 7,000 or more, and a weight average molecular weight (Mw) of from 1,550 to 7,000.

Claim 13

The toner according to claim 1, wherein the compound made by the reaction of the monohydroxylic compound with the carboxylic acid is contained in the toner in an amount of from 1% to 20% by weight based on 100% by weight of the binder resin.

Claim 14

The toner according to claim 1, wherein the compound made by the reaction of the monohydroxylic compound with the carboxylic acid is contained in the toner in an amount of from 2% to 15% by weight based on 100% by weight of the binder resin.

Claim 15

The toner according to claim 1, wherein the compound made by the reaction of the monocarboxylic compound with the alcohol is contained in the toner in an amount of from 1% to 20% by weight based on 100% by weight of the binder resin.

Claim 16

The toner according to claim 1, wherein the compound made by the reaction of the monocarboxylic compound with the alcohol is contained in the toner in an amount of from 2% to 15% by weight based on 100% by weight of the binder resin.

Claim 17

The toner according to claim 1, wherein the monohydroxylic compound is selected from the compounds represented by the following formulas (I) to (IV): ##STR31##

Claim 18

The toner according to claim 1, wherein the monohydroxylic compound is a reaction product of a long-chain alkyl alcohol with a compound having an epoxy group in a molecule.

Claim 19

The toner according to claim 17, wherein the monohydroxylic compound is represented by the following formula: ##STR32## wherein n represents a number of 40 or more, p represents a number of from 1 to 10, and R" represents a hydrogen atom, a hydrocarbon group with carbon atoms of from 1 to 20 or R 4 --CH 2 -- where R 4 represents an ether group or an ester group.

Claim 20

The toner according to claim 1, wherein the monohydroxylic compound is selected from the compounds represented by the following formulas (I) to (IV): ##STR33##

Claim 21

The toner according to claim 1, wherein the carboxylic acid is a polycarboxylic acid.

Claim 22

The toner according to claim 1, wherein the carboxylic acid has a molecular weight of from 50 to 1,000.

Claim 23

The toner according to claim 1, wherein the carboxylic acid has a molecular weight of from 100 to 1,000.

Claim 24

The toner according to claim 1, wherein the alcohol is a polyhydric alcohol.

Claim 25

The toner according to claim 1, wherein the alcohol has a molecular weight of from 50 to 1,000.

Claim 26

The toner according to claim 1, wherein the alcohol has a molecular weight of from 100 to 1,000.

Claim 27

The toner according to claim 1, wherein the binder resin has a polyester resin.

Claim 28

The toner according to claim 1, wherein the binder resin has a styrene-acryl resin.

Claim 29

The toner according to claim 1, wherein the colorant comprises a magnetic material.

Claim 30

The toner according to claim 28, wherein the magnetic toner constitutes a magnetic one-component developer.

Claim 31

The toner according to claim 1, wherein the toner comprises a pigment or a dye.

Claim 32

The toner according to claim 30, wherein the color toner constitutes a non-magnetic one-component developer.

Claim 33

The toner according to claim 30, wherein the color toner is mixed with a carrier to constitute a two-component developer.

Claim 34

The toner according to claim 1, wherein the toner comprises toner particles and silica fine powder.

Claim 35

The toner according to claim 1, wherein the toner comprises particles with a volume average particle diameter of from 3 to 8 μm.

Claim 36

The toner according to claim 1, wherein the toner is a heat fixing toner.

Claim 37

An image forming method comprising: forming an electrostatic latent image on an electrostatic latent image bearing member; developing the electrostatic latent image through a developing means in a developing zone to form a toner image on the electrostatic latent image bearing member; wherein the developing means holds a toner, the toner comprising: (i) a binder resin; (ii) a colorant; and (iii) a compound made by a reaction of a monohydroxylic compound having a long-chain alkyl group having an alkylene group with 40 or more carbon atoms and a hydroxyl group with a carboxylic acid having a molecular weight of 1,000 or less, said carboxylic acid being selected from the group consisting of formic acid, acetic acid, propionic acid, lactic acid, isolactic acid, valeric acid, pivalic acid, lauric acid, myristic acid, palmitic acid, stearic acid, acrylic acid, propionic acid, methacrylic acid, crotonic acid, oleic acid, furoic acid, nicotinic acid, isonicotinic acid, fumaric acid, maleic acid, citraconic acid, itaconic acid, succinic acid, adipic acid, sebacic acid, azelaic acid, benzoic acid, toluic acid, naphthoic acid, cinnamic acid, phthalic acid, terephthalic acid, trimellitic acid, pyromellitic acid, and acid anhydrides thereof, or a compound made by a reaction of a monocarboxylic compound having a long-chain alkyl group having an alkylene group with 40 or more carbon atoms and a carboxyl group with an alcohol having a molecular weight of 1,000 or less, said alcohol being selected from the group consisting of methyl alcohol, ethyl alcohol, propyl alcohol, isopropyl alcohol, butyl alcohol, isobutyl alcohol, sec-butyl alcohol, tert-butyl alcohol, n-amyl alcohol, isoamyl alcohol, hexyl alcohol, heptyl alcohol, octyl alcohol, capryl alcohol, allyl alcohol, crotyl alcohol, propargyl alcohol, cyclopentanol, cyclohexanol, benzyl alcohol, cinnamyl alcohol, furfuryl alcohol, ethylene glycol, propylene glycol, 1,3-butanediol, 1,4-butanediol, 2,3-butanediol, diethylene glycol, dipropylylene glycol, triethylene glycol, 1,5-pentanediol, 1,6-hexanediol, neopentyl glycol, pentaerythritol diallyl ether, trimethylene glycol, 2-ethyl-1, 3-hexanediol, hydrogenated bisphenol A and a bisphenol derivative represented by the formula. ##STR34## wherein r is an ethylene group or a propylene group and x and y are each an integer of 1 or more, and total 2 to 10; transferring the toner image to a recording medium; and fixing the transferred toner image to the recording medium.

Claim 38

An image forming method comprising: forming an electrostatic latent image on an electrostatic latent image bearing member; developing the electrostatic latent image through a developing means in a developing zone to form a toner image on the electrostatic latent image bearing member; wherein the developing means holds a toner, the toner comprising: (i) a binder resin; (ii) a colorant; and (iii) a compound made by a reaction of a monohydroxylic compound having a long-chain alkyl group having an alkylene group with 40 or more carbon atoms and a hydroxyl group with a carboxylic acid having a molecular weight of 1,000 or less, said carboxylic acid being selected from the group consisting of formic acid, acetic acid, propionic acid, lactic acid, isolactic acid, valeric acid, pivalic acid, lauric acid, myristic acid, palmitic acid, stearic acid, acrylic acid, propionic acid, methacrylic acid, crotonic acid, oleic acid, furoic acid, nicotinic acid, isonicotinic acid, fumaric acid, maleic acid, citraconic acid, itaconic acid, succinic acid, adipic acid, sebacic acid, azelaic acid, benzoic acid, toluic acid, naphthoic acid, cinnamic acid, phthalic acid, terephthalic acid, trimellitic acid, pyromellitic acid, and acid anhydrides thereof, or a compound made by a reaction of a monocarboxylic compound having a long-chain alkyl group having an alkylene group with 40 or more carbon atoms and a carboxyl group with an alcohol having a molecular weight of 1,000 or less, said alcohol being selected from the group consisting of methyl alcohol, ethyl alcohol, propyl alcohol, isopropyl alcohol, butyl alcohol, isobutyl alcohol, sec-butyl alcohol, tert-butyl alcohol, n-amyl alcohol, isoamyl alcohol, hexyl alcohol, heptyl alcohol, octyl alcohol, capryl alcohol, allyl alcohol, crotyl alcohol, propargyl alcohol, cyclopentanol, cyclohexanol, benzyl alcohol, cinnamyl alcohol, furfuryl alcohol, ethylene glycol, propylene glycol, 1,3-butanediol, 1,4-butanediol, 2,3-butanediol, diethylene glycol, dipropylylene glycol, triethylene glycol, 1,5-pentanediol, 1,6-hexanediol, neopentyl glycol, pentaerythritol diallyl ether, trimethylene glycol, 2-ethyl-1, 3-hexanediol, hydrogenated bisphenol A and a bisphenol derivative represented by the formula. ##STR34## wherein r is an ethylene group or a propylene group and x and y are each an integer of 1 or more, and total 2 to 10; transferring the toner image to a recording medium; and fixing the transferred toner image to the recording medium.

Claim 39

The method according to claim 36, which is carried out at a process speed of 380 mm/sec or more.

Claim 40

A process cartridge which is detachable from the body of an image forming apparatus, comprising: an electrostatic latent image bearing member and a developing means; wherein the developing means holds a toner, the toner comprising; (i) a binder resin; (ii) a colorant; and (iii) a compound made by a reaction of a monohydroxylic compound having a long-chain alkyl group having an alkylene group with 40 or more carbon atoms and a hydroxyl group with a carboxylic acid having a molecular weight of 1,000 or less, said carboxylic acid being selected from the group consisting of formic acid, acetic acid, propionic acid, lactic acid, isolactic acid, valeric acid, pivalic acid, lauric acid, myristic acid, palmitic acid, stearic acid, acrylic acid, propionic acid, methacrylic acid, crotonic acid, oleic acid, furoic acid, nicotinic acid, isonicotinic acid, fumaric acid, maleic acid, citraconic acid, itaconic acid, succinic acid, adipic acid, sebacic acid, azelaic acid, benzoic acid, toluic acid, naphthoic acid, cinnamic acid, phthalic acid, terephthalic acid, trimellitic acid, pyromellitic acid, and acid anhydrides thereof, or a compound made by a reaction of a monocarboxylic compound having a long-chain alkyl group having an alkylene group with 40 or more carbon atoms and a carboxyl group with an alcohol having a molecular weight of 1,000 or less, said alcohol being selected from the group consisting of methyl alcohol, ethyl alcohol, propyl alcohol, isopropyl alcohol, butyl alcohol, isobutyl alcohol, sec-butyl alcohol, tert-butyl alcohol, n-amyl alcohol, isoamyl alcohol, hexyl alcohol, heptyl alcohol, octyl alcohol, capryl alcohol, allyl alcohol, crotyl alcohol, propargyl alcohol, cyclopentanol, cyclohexanol, benzyl alcohol, cinnamyl alcohol, furfuryl alcohol, ethylene glycol, propylene glycol, 1,3-butanediol, 1,4-butanediol, 2,3-butanediol, diethylene glycol, dipropylene glycol, triethylene glycol, 1,5-pentanediol, 1,6-hexanediol, neopentyl glycol, pentaerythritol diallyl ether, trimethylene glycol, 2-ethyl-1,3-hexanediol, hydrogenated bisphenol A, and a bisphenol derivative represented by the formula: ##STR35## wherein R is an ethylene group or a propylene group and x and y are each an integer of 1 or more, and total 2 to 10.

Claim 41

A process cartridge which is detachable from the body of an image forming apparatus, comprising: an electrostatic latent image bearing member and a developing means; wherein the developing means holds a toner, the toner comprising; (i) a binder resin; (ii) a colorant; and (iii) a compound made by a reaction of a monohydroxylic compound having a long-chain alkyl group having an alkylene group with 40 or more carbon atoms and a hydroxyl group with a carboxylic acid having a molecular weight of 1,000 or less, said carboxylic acid being selected from the group consisting of formic acid, acetic acid, propionic acid, lactic acid, isolactic acid, valeric acid, pivalic acid, lauric acid, myristic acid, palmitic acid, stearic acid, acrylic acid, propionic acid, methacrylic acid, crotonic acid, oleic acid, furoic acid, nicotinic acid, isonicotinic acid, fumaric acid, maleic acid, citraconic acid, itaconic acid, succinic acid, adipic acid, sebacic acid, azelaic acid, benzoic acid, toluic acid, naphthoic acid, cinnamic acid, phthalic acid, terephthalic acid, trimellitic acid, pyromellitic acid, and acid anhydrides thereof, or a compound made by a reaction of a monocarboxylic compound having a long-chain alkyl group having an alkylene group with 40 or more carbon atoms and a carboxyl group with an alcohol having a molecular weight of 1,000 or less, said alcohol being selected from the group consisting of methyl alcohol, ethyl alcohol, propyl alcohol, isopropyl alcohol, butyl alcohol, isobutyl alcohol, sec-butyl alcohol, tert-butyl alcohol, n-amyl alcohol, isoamyl alcohol, hexyl alcohol, heptyl alcohol, octyl alcohol, capryl alcohol, allyl alcohol, crotyl alcohol, propargyl alcohol, cyclopentanol, cyclohexanol, benzyl alcohol, cinnamyl alcohol, furfuryl alcohol, ethylene glycol, propylene glycol, 1,3-butanediol, 1,4-butanediol, 2,3-butanediol, diethylene glycol, dipropylene glycol, triethylene glycol, 1,5-pentanediol, 1,6-hexanediol, neopentyl glycol, pentaerythritol diallyl ether, trimethylene glycol, 2-ethyl-1,3-hexanediol, hydrogenated bisphenol A, and a bisphenol derivative represented by the formula: ##STR35## wherein R is an ethylene group or a propylene group and x and y are each an integer of 1 or more, and total 2 to 10.

Claim 42

The process cartridge according to claim 38, wherein, in addition to the developing means and an electrophotographic photosensitive member as the electrostatic latent image bearing member, at least one of a charging means and a cleaning means is provided, and the developing means, the electrostatic latent image bearing member and at least one of the charging means and the cleaning means are integrally joined as one cartridge which is detachable from the body of the image forming apparatus.

Claim 43

The method according to claim 36, wherein the toner is any one of the toners of claims 2-35.

Claim 44

The process cartridge according to claim 38, wherein the toner is any one of the toners of claims 2-35.