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Organic polymer and preparation and use thereof

Assignee: Panasonic Holdings Corp
•
Filing: 1995-05-26
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Granted: 1997-01-28
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Expires: 2015-05-26
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Abstract

Abstract An alternating copolymer comprising a repeating unit of the formula:-Z-(X-Y)n-(I)wherein n is at least 2, X is O, S, Se or Te, and Y and Z are independently an aromatic or substituted aromatic group, and at least one other repeating unit, which is useful as a photosensitive material used in a spatial light modulator.

Inventors

  • 👤 Akio Takimoto
  • 👤 Hirofumi Wakemoto
  • 👤 Eiichiro Tanaka
  • 👤 Masanori Watanabe
  • 👤 Junko Asayama
  • 👤 Hisahito Ogawa
  • 👤 Shigehiro Sato
  • 👤 Fumiko Yokotani

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-07 09:51
CPC Classifications
C; C08; C08G; C08G73/00; C08G73/06; C08G73/10; C08G63/00; C08G63/68; C08G63/688; C08G63/6884; C08G63/6886; C08G69/00; C08G69/02; C08G69/26; C08G69/32; C08G69/40; C08G69/42; C08G69/44; C08G73/1046; C08G73/105; C08G73/1057; C08G73/1064; C08G73/1067; C08G73/14; C08G73/16; C09; C09B; C09B69/00; C09B69/10; G; G02; G02F; G02F1/00; G02F1/01; G02F1/13; G02F1/133; G02F1/1333; G02F1/1337; G02F1/133711; G02F1/135; G02F1/1354; G03; G03G; G03G5/00; G03G5/02; G03G5/04; G03G5/06; G03G5/07; G03G5/075; G03G5/076; G03G5/0763; C09K; C09K19/00; C09K19/04; C09K19/06; C09K19/32; C09K2019/328; C09K2323/00; C09K2323/02; C09K2323/027; Y; Y10; Y10T; Y10T428/00; Y10T428/31504; Y10T428/31721

Claims Analysis

Total Claims: 9
Claim 1
Independent Claim 166 words
A process for preparing a polyimide comprising reacting a diamine of the formula: NH.sub.2 --(Y.sub.i -X.sub.i).sub.n --Y.sub.i --NH.sub.2 (III) wherein n is a number of at least 2, i is a positive integer not larger than n, Y is an aromatic or substituted aromatic group, and X is O, S, Se, Te or the divalent group --CH═CH--, and a tetracarboxylic dianhydride of the formula: ##STR7## wherein A is a tetravalent hydrocarbon group in a molar ratio of said diamine to said dianhydride of 1:(1+m) wherein m is a positive number to obtain a polyamic acid, wherein said diamine and said tetracarboxylic dianhydride are reacted in a ratio of said diamine to said dianhydride of 1:(1+m), wherein m is larger than zero and smaller than 1, to form said polyamic acid, and then an additional amount of said carboxylic anhydride is added to said polyamic acid; polymerizing said polyamic acid; and annealing the resultant polymerization product at a temperature of 200° to 400° C. to obtain polyimide.
Claim 2
Dependent Claim 166 words
A process for preparing a polyimide comprising reacting a diamine of the formula: NH.sub.2 --(Y.sub.i -X.sub.i).sub.n --Y.sub.i --NH.sub.2 (III) wherein n is a number of at least 2, i is a positive integer not larger than n, Y is an aromatic or substituted aromatic group, and X is O, S, Se, Te or the divalent group --CH═CH--, and a tetracarboxylic dianhydride of the formula: ##STR7## wherein A is a tetravalent hydrocarbon group in a molar ratio of said diamine to said dianhydride of 1:(1+m) wherein m is a positive number to obtain a polyamic acid, wherein said diamine and said tetracarboxylic dianhydride are reacted in a ratio of said diamine to said dianhydride of 1:(1+m), wherein m is larger than zero and smaller than 1, to form said polyamic acid, and then an additional amount of said carboxylic anhydride is added to said polyamic acid; polymerizing said polyamic acid; and annealing the resultant polymerization product at a temperature of 200° to 400° C. to obtain polyimide.
Claim 3
Dependent Claim 126 words
A process for preparing an organic polymer comprising evaporating a raw material comprising a diamine of the formula: NH.sub.2 --(Y.sub.i -X.sub.i).sub.n --Y.sub.i --NH.sub.2 (III) wherein n is a number of at least 2, i is a positive integer not larger than n, Y is an aromatic or substituted aromatic group, and X is O, S, Se, Te or the divalent group --CH═CH--, and a tetracarboxylic dianhydride of the formula: ##STR8## wherein A is a tetravalent hydrocarbon group, and wherein said diamine and said dianhydride are independently evaporated in an evaporation ratio of said diamine to said dianhydride of 1:(1+m), wherein m is a positive number; and polymerizing them on a substrate, wherein the temperature of said substrate is higher than a melting point of said diamine.
Claim 4
Dependent Claim 126 words
A process for preparing an organic polymer comprising evaporating a raw material comprising a diamine of the formula: NH.sub.2 --(Y.sub.i -X.sub.i).sub.n --Y.sub.i --NH.sub.2 (III) wherein n is a number of at least 2, i is a positive integer not larger than n, Y is an aromatic or substituted aromatic group, and X is O, S, Se, Te or the divalent group --CH═CH--, and a tetracarboxylic dianhydride of the formula: ##STR8## wherein A is a tetravalent hydrocarbon group, and wherein said diamine and said dianhydride are independently evaporated in an evaporation ratio of said diamine to said dianhydride of 1:(1+m), wherein m is a positive number; and polymerizing them on a substrate, wherein the temperature of said substrate is higher than a melting point of said diamine.
Claim 5
Dependent Claim 15 words
The process according to claim 2, wherein said substrate is coated with a polyimide film.
Claim 6
Dependent Claim 15 words
The process according to claim 3, wherein said polyimide film is subjected to rubbing treatment.
Claim 7
Dependent Claim 24 words
The process according to claim 2, wherein after deposition of said polyimide, said substrate is heated to a temperature of 200° C. or higher.
Claim 8
Dependent Claim 16 words
The process according to claim 2, wherein said substrate is coated with a silane coupling agent.
Claim 9
Dependent Claim 15 words
The process according to claim 6, wherein said diamine and said dianhydride are alternately evaporated.

References Cited (Backward Citations)

FR2400224A1 Cited
US4698295A Cited
EP0240249A2 Cited
EP0283636A2 Cited
US5084557A Cited
EP0300326A1 Cited
EP0375165A2 Cited
US5384649A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 2000-01-28 2000-07-29 2001-01-28 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 2004-01-28 2004-07-29 2005-01-28 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2008-01-28 2008-07-29 2009-01-28 $7700.00 Window Closed / Lapsed

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