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US5589712A Expired / Lapsed US ⏱️ 0.0 years remaining

Semiconductor integrated circuit device and a method of manufacturing the same

Assignee: Ricoh Co Ltd
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Filing: 1994-12-02
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Granted: 1996-12-31
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Expires: 2014-12-02
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Abstract

Abstract A semiconductor integrated circuit device includes a substrate formed with semiconductor elements and a metal wiring having a laminated structure and provided on the substrate. The metal wiring includes a first layer including aluminum as a main component, and a second layer formed on the first layer. The second layer includes titanium and nitrogen as main components. The second layer includes more titanium than nitrogen in number of atoms. A third layer may be formed between the first and second layers. The third layer includes a compound of aluminum and titanium as a main component. A fourth layer may further be formed between the second and third layers. The fourth layer includes titanium as a main component and is free of aluminum.

Inventors

  • 👤 Ikue Kawashima
  • 👤 Katsunari Hanaoka

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-04 18:33
CPC Classifications
H; H10; H10W; H10W20/00; H10W20/01; H10W20/031; H10W20/40; H10W20/41; H10W20/425; Y; Y10; Y10S; Y10S257/00; Y10S257/915; Y10S257/924

Claims Analysis

Total Claims: 21
Claim 1
Independent Claim 93 words
A semiconductor device comprising: a substrate formed with semiconductor elements; and a metal wiring having a laminated structure and provided on said substrate, said metal wiring including: a first layer A having aluminum as a main component; and a second layer D formed on said first layer A, said second layer D having as main components titanium and nitrogen in a given ratio such that a reflectance of said second layer D is 30% or less for a given wavelength of exposing light in a range including wavelengths different from that of i-light.
Claim 2
Dependent Claim 93 words
A semiconductor device comprising: a substrate formed with semiconductor elements; and a metal wiring having a laminated structure and provided on said substrate, said metal wiring including: a first layer A having aluminum as a main component; and a second layer D formed on said first layer A, said second layer D having as main components titanium and nitrogen in a given ratio such that a reflectance of said second layer D is 30% or less for a given wavelength of exposing light in a range including wavelengths different from that of i-light.
Claim 3
Dependent Claim 22 words
The semiconductor device as set forth in claim 1, wherein said ratio is 0.5≦N/Ti<1, where N represents nitrogen and Ti represents titanium.
Claim 4
Dependent Claim 115 words
A semiconductor device comprising: a substrate formed with semiconductor elements; and a metal wiring having a laminated structure and provided on said substrate, said metal wiring including: a first layer A having aluminum as a main component; a second layer B formed on said first layer A and having a compound of aluminum and titanium as a main component; and a third layer D formed on said second layer B, said third layer D having as main components titanium and nitrogen in a given ratio such that a reflectance of said third layer D is 30% or less for a given wavelength of exposing light in a range including wavelengths different from that of i-light.
Claim 5
Dependent Claim 115 words
A semiconductor device comprising: a substrate formed with semiconductor elements; and a metal wiring having a laminated structure and provided on said substrate, said metal wiring including: a first layer A having aluminum as a main component; a second layer B formed on said first layer A and having a compound of aluminum and titanium as a main component; and a third layer D formed on said second layer B, said third layer D having as main components titanium and nitrogen in a given ratio such that a reflectance of said third layer D is 30% or less for a given wavelength of exposing light in a range including wavelengths different from that of i-light.
Claim 6
Dependent Claim 22 words
The semiconductor device as set forth in claim 3, wherein said ratio is 0.5≦N/Ti<1, where N represents nitrogen and Ti represents titanium.
Claim 7
Dependent Claim 139 words
A semiconductor device comprising: a substrate formed with semiconductor elements; and a metal wiring having a laminated structure and provided on said substrate, said metal wiring including: a first layer A having aluminum as a main component; a second layer B formed on said first layer A and having a compound of aluminum and titanium as a main component; a third layer C formed on said second layer B and having titanium as a main component, said third layer C including no aluminum; and a fourth layer D formed on said third layer C, said fourth layer D having as main components titanium and nitrogen in a given ratio such that a reflectance of said fourth layer D is 30% or less for a given wavelength of exposing light in a range including wavelengths different from that of i-light.
Claim 8
Dependent Claim 139 words
A semiconductor device comprising: a substrate formed with semiconductor elements; and a metal wiring having a laminated structure and provided on said substrate, said metal wiring including: a first layer A having aluminum as a main component; a second layer B formed on said first layer A and having a compound of aluminum and titanium as a main component; a third layer C formed on said second layer B and having titanium as a main component, said third layer C including no aluminum; and a fourth layer D formed on said third layer C, said fourth layer D having as main components titanium and nitrogen in a given ratio such that a reflectance of said fourth layer D is 30% or less for a given wavelength of exposing light in a range including wavelengths different from that of i-light.
Claim 9
Dependent Claim 22 words
The semiconductor device as set forth in claim 5, wherein said ratio is 0.5≦N/Ti<1, where N represents nitrogen and Ti represents titanium.
Claim 10
Independent Claim 132 words
A method of manufacturing a semiconductor device including a substrate formed with semiconductor elements and a metal wiring provided on said substrate, said method comprising steps of: forming on said substrate a first film A having aluminum as a main component; forming on said first film A a second film D having titanium and nitrogen as main components, said second film D formed by sputtering a target made of titanium and using a mixed sputtering gas of argon and nitrogen such that a reflectance of said second film D is 30% or less for a given wavelength of exposing light in a range including wavelengths different from that of i-light; and forming said first and second films having a laminated structure into a given pattern of wiring to provide said metal wiring.
Claim 11
Independent Claim 132 words
A method of manufacturing a semiconductor device including a substrate formed with semiconductor elements and a metal wiring provided on said substrate, said method comprising steps of: forming on said substrate a first film A having aluminum as a main component; forming on said first film A a second film D having titanium and nitrogen as main components, said second film D formed by sputtering a target made of titanium and using a mixed sputtering gas of argon and nitrogen such that a reflectance of said second film D is 30% or less for a given wavelength of exposing light in a range including wavelengths different from that of i-light; and forming said first and second films having a laminated structure into a given pattern of wiring to provide said metal wiring.
Claim 12
Dependent Claim 30 words
The method as set forth in claim 7, wherein said second film has a ratio of titanium and nitrogen defined by 0.5≦N/Ti<1, where N represents nitrogen and Ti represents titanium.
Claim 13
Independent Claim 152 words
A method of manufacturing a semiconductor device including a substrate formed with semiconductor elements and a metal wiring provided on said substrate, said method comprising steps of: superposing on said substrate a first film A having aluminum as a main component; superposing titanium as a second film B on said first film A by sputtering A target made of titanium and using a sputtering gas of argon; superposing on said second film B a third film D having titanium and nitrogen as main components by adding nitrogen gas to said argon sputtering gas to form a mixed sputtering gas such that a reflectance of said third film D is 30% or less for a given wavelength of exposing light in a range including wavelengths different from that of i-light; and forming said first, second, and third films having a laminated structure into a given pattern of wiring to provide said metal wiring.
Claim 14
Independent Claim 152 words
A method of manufacturing a semiconductor device including a substrate formed with semiconductor elements and a metal wiring provided on said substrate, said method comprising steps of: superposing on said substrate a first film A having aluminum as a main component; superposing titanium as a second film B on said first film A by sputtering A target made of titanium and using a sputtering gas of argon; superposing on said second film B a third film D having titanium and nitrogen as main components by adding nitrogen gas to said argon sputtering gas to form a mixed sputtering gas such that a reflectance of said third film D is 30% or less for a given wavelength of exposing light in a range including wavelengths different from that of i-light; and forming said first, second, and third films having a laminated structure into a given pattern of wiring to provide said metal wiring.
Claim 15
Dependent Claim 30 words
The method as set forth in claim 9, wherein said third film has a ratio of titanium and nitrogen defined by 0.5≦N/Ti<1, where N represents nitrogen and Ti represents titanium.
Claim 16
Dependent Claim 70 words
A semiconductor device comprising: a substrate formed with semiconductor elements; and a metal wiring having a laminated structure and provided on said substrate, said metal wiring including: a first layer A having aluminum as a main component; and a second layer D formed on said first layer A, said second layer D having as main components titanium and nitrogen in a ratio of atoms N/Ti which is less than 0.8.
Claim 17
Dependent Claim 70 words
A semiconductor device comprising: a substrate formed with semiconductor elements; and a metal wiring having a laminated structure and provided on said substrate, said metal wiring including: a first layer A having aluminum as a main component; and a second layer D formed on said first layer A, said second layer D having as main components titanium and nitrogen in a ratio of atoms N/Ti which is less than 0.8.
Claim 18
Dependent Claim 18 words
A semiconductor device as in claim 11 in which said ratio or atoms N/Ti is 0.6 or less.
Claim 19
Independent Claim 113 words
A method of manufacturing a semiconductor device including a substrate formed with semiconductor elements and a metal wiring provided on said substrate, said method comprising steps of: forming on said substrate a first film A having aluminum as a main component; forming on said first film A a second film D having titanium and nitrogen as main components, in a ratio of atoms N/Ti which is less than 0.8, said second film D formed by sputtering a target made of titanium and using a mixed sputtering gas of argon and nitrogen; and forming said first and second films having a laminated structure into a given pattern of wiring to provide said metal wiring.
Claim 20
Independent Claim 113 words
A method of manufacturing a semiconductor device including a substrate formed with semiconductor elements and a metal wiring provided on said substrate, said method comprising steps of: forming on said substrate a first film A having aluminum as a main component; forming on said first film A a second film D having titanium and nitrogen as main components, in a ratio of atoms N/Ti which is less than 0.8, said second film D formed by sputtering a target made of titanium and using a mixed sputtering gas of argon and nitrogen; and forming said first and second films having a laminated structure into a given pattern of wiring to provide said metal wiring.
Claim 21
Dependent Claim 22 words
A method of manufacturing a semiconductor device as in claim 13 in which said ratio of atoms N/Ti is 0.6 or less.

References Cited (Backward Citations)

US4875088A Cited
US5049975A Cited
US5345108A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1999-12-31 2000-07-01 2000-12-31 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 2003-12-31 2004-07-01 2004-12-31 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2007-12-31 2008-07-01 2008-12-31 $7700.00 Window Closed / Lapsed

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