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US5582944A Expired / Lapsed US ⏱️ 0.0 years remaining

Light receiving member

Assignee: Canon Inc
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Filing: 1994-06-22
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Granted: 1996-12-10
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Expires: 2014-06-22
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Abstract

Abstract An electrophotographic light-receiving member comprises a conductive substrate and a light-receiving layer having a photoconductive layer and a surface layer which are successively layered on the conductive substrate, wherein; the photoconductive layer is comprised of a non-monocrystalline material mainly composed of a silicon atom and containing at least a carbon atom, a hydrogen atom and a fluorine atom; the surface layer is mainly composed of a silicon atom and contains a carbon atom, a hydrogen atom and a halogen atom; the carbon atom in the photoconductive layer is in a non-uniform content in the layer thickness direction and in a higher content on the side of the conductive substrate and in a lower content on the side of the surface layer at every point in the layer thickness direction, and is in a content of from 0.5 atomic % to 50 atomic % at, or in the vicinity of, its surface on the side of the conductive substrate and substantially 0% R at, or in the vicinity of, its surface on the side of the surface layer; the fluorine atom in the photoconductive layer is in a content of not more than 95 atomic ppm; and the hydrogen atom in the photoconductive layer is in a content of from 1 to 40 atomic %.

Inventors

  • 👤 Masaaki Yamamura
  • 👤 Toshiyasu Shirasuna
  • 👤 Junichiro Hashizume
  • 👤 Kazuyoshi Akiyama
  • 👤 Shigeru Shirai

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-01 22:21
CPC Classifications
G; G03; G03G; G03G5/00; G03G5/02; G03G5/04; G03G5/08; G03G5/082; G03G5/08214; G03G5/08221; G03G5/08228

Claims Analysis

Total Claims: 22
Claim 1
Independent Claim 213 words
An electrophotographic light-receiving member comprising a conductive substrate and a light receiving layer consisting essentially of a photoconductive layer and a surface layer which are successively layered on said conductive substrate, wherein: said photoconductive layer comprises a non-monocrystalline material containing silicon atoms as a matrix and containing at least carbon atoms, hydrogen atoms and fluorine atoms; said surface layer comprises a non-monocrystalline material comprising silicon atoms, carbon atoms, hydrogen atoms and halogen atoms; said carbon atoms in said photoconductive layer are in a non-uniform content in the layer thickness direction, wherein the concentration of said carbon atoms gradually and continuously decreases from the side of the conductive substrate to the side of the surface layer; and said carbon atoms are present in amounts from 0.5 atomic % to 50 atomic % at a lower region of the photoconductive layer on the side of the conductive substrate and are present at substantially 0% at an upper layer region of said photoconductive layer on the side of the said surface layer; said fluorine atoms in said photoconductive layer are present in amounts not more than 95 atomic ppm and are non-uniformly distributed in the layer thickness direction; and said hydrogen atoms in said photoconductive layer are present in amounts from 1 to 40 atomic %.
Claim 2
Dependent Claim 213 words
An electrophotographic light-receiving member comprising a conductive substrate and a light receiving layer consisting essentially of a photoconductive layer and a surface layer which are successively layered on said conductive substrate, wherein: said photoconductive layer comprises a non-monocrystalline material containing silicon atoms as a matrix and containing at least carbon atoms, hydrogen atoms and fluorine atoms; said surface layer comprises a non-monocrystalline material comprising silicon atoms, carbon atoms, hydrogen atoms and halogen atoms; said carbon atoms in said photoconductive layer are in a non-uniform content in the layer thickness direction, wherein the concentration of said carbon atoms gradually and continuously decreases from the side of the conductive substrate to the side of the surface layer; and said carbon atoms are present in amounts from 0.5 atomic % to 50 atomic % at a lower region of the photoconductive layer on the side of the conductive substrate and are present at substantially 0% at an upper layer region of said photoconductive layer on the side of the said surface layer; said fluorine atoms in said photoconductive layer are present in amounts not more than 95 atomic ppm and are non-uniformly distributed in the layer thickness direction; and said hydrogen atoms in said photoconductive layer are present in amounts from 1 to 40 atomic %.
Claim 3
Dependent Claim 21 words
The electrophotographic light-receiving member according to claim 1, wherein said surface layer further contains an oxygen atom and a nitrogen atom.
Claim 4
Dependent Claim 58 words
The electrophotographic light-receiving member according to claim 2, wherein the total content of the carbon atom, oxygen atom and nitrogen atom in said surface layer is in the range of from 40 atomic % to 90 atomic % based on the total content of the silicon atom, carbon atom, oxygen atom and nitrogen atom in said surface layer.
Claim 5
Dependent Claim 37 words
The electrophotographic light-receiving member according to claim 2, wherein at least one of said carbon atom, oxygen atom, nitrogen atom and halogen atom in said surface layer is in a non-uniform content in the layer thickness direction.
Claim 6
Dependent Claim 35 words
The electrophotographic light-receiving member according to claim 1, wherein said surface layer contains an element belonging to Group III of the periodic table, and at least one of an oxygen atom and a nitrogen atom.
Claim 7
Dependent Claim 46 words
The electrophotographic light-receiving member according to claim 5, wherein at least one of said carbon atom, oxygen atom, nitrogen atom, halogen atom and element belonging to Group III of the periodic table in said surface layer is in a non-uniform content in the layer thickness direction.
Claim 8
Dependent Claim 45 words
The electrophotographic light-receiving member according to claim 5, wherein said carbon atom in said surface layer is in a content of from 63 atomic % to 90 atomic % at, its outermost surface, based on the total content of the silicon atom and carbon atom.
Claim 9
Dependent Claim 23 words
The electrophotographic light-receiving member according to claim 5, wherein said oxygen atom is in a content of not more than 30 atomic %.
Claim 10
Dependent Claim 23 words
The electrophotographic light-receiving member according to claim 5, wherein said nitrogen atom is in a content of not more than 30 atomic %.
Claim 11
Dependent Claim 26 words
The electrophotographic light-receiving member according to claim 5, wherein the total content of said oxygen atom and nitrogen atom is not more than 30 atomic %.
Claim 12
Dependent Claim 27 words
The electrophotographic light-receiving member according to claim 5, wherein said element belonging to Group III of the periodic table is not more than 1×10 5 atomic ppm.
Claim 13
Dependent Claim 31 words
The electrophotographic light-receiving member according to claim 1, wherein said fluorine atom in said photoconductive layer is in a maximum content at, its interface on the side of said surface layer.
Claim 14
Dependent Claim 27 words
The electrophotographic light-receiving member according to claim 1, wherein said halogen atom in said surface layer is in a content of not more than 20 atomic %.
Claim 15
Dependent Claim 36 words
The electrophotographic light-receiving member according to claim 1, wherein the total content of the hydrogen atom and halogen atom in said surface layer is in the range of from 30 atomic % to 70 atomic %.
Claim 16
Dependent Claim 26 words
The electrophotographic light-receiving member according to claim 1, wherein said photoconductive layer contains an element belonging to Group III or Group V of the periodic table.
Claim 17
Dependent Claim 16 words
The electrophotographic light-receiving member according to claim 1, wherein said photoconductive layer contains an oxygen atom.
Claim 18
Dependent Claim 25 words
The electrophotographic light-receiving member according to claim 16, wherein said oxygen atom is in a content of from 10 atomic ppm to 5,000 atomic ppm.
Claim 19
Dependent Claim 29 words
The electrophotographic light-receiving member according to claim 1, wherein said fluorine atom in said photoconductive layer is in a content of from 1 atomic ppm to 50 atomic ppm.
Claim 20
Dependent Claim 25 words
The electrophotographic light-receiving member according to claim 1, wherein said fluorine atom is in a content of from 5 atomic ppm to 50 atomic ppm.
Claim 21
Dependent Claim 44 words
The electrophotographic light-receiving member according to claim 1, wherein said photoconductive layer has a first photoconductive layer and a second photoconductive layer in that order from the side of said conductive substrate, and said first photoconductive layer contains said carbon atom and fluorine atom.
Claim 22
Dependent Claim 24 words
The electrophotographic light-receiving member according to claim 20, wherein said second photoconductive layer has a layer thickness of from 0.5 μm to 15 μm.

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1999-12-10 2000-06-10 2000-12-10 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 2003-12-10 2004-06-10 2004-12-10 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2007-12-10 2008-06-10 2008-12-10 $7700.00 Window Closed / Lapsed

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