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Method for light-assisted curing of coatings

Assignee: Rohm and Haas Co
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Filing: 1994-11-18
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Granted: 1996-10-08
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Expires: 2014-11-18
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Abstract

Abstract This invention relates to a method for light-assisted curing of coatings by providing coatings with an enamine content sufficient to enhance the cure rate of the coatings. The coatings exhibit improved weatherability and gloss retention when exposed to light.

Inventors

  • 👤 Daniel A. Bors
  • 👤 William D. Emmons
  • 👤 Steven S. Edwards

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-29 06:20
CPC Classifications
C; C09; C09D; C09D133/00; C09D133/04; C09D133/06; C09D133/10; C09D133/14; B; B05; B05D; B05D3/00; B05D3/06; B05D3/061; B05D3/065; B05D7/00; B05D7/24; C08; C08F; C08F8/00; C08F8/44; C09D157/00; C09D157/06; C09D157/12; C09D7/00; Y; Y10; Y10T; Y10T428/00; Y10T428/31504; Y10T428/31855; Y10T428/31942

Claims Analysis

Total Claims: 4
Claim 1
Independent Claim 109 words
A process of preparing a cured coating on a surface comprising a) mixing a vinyl polymer having acetoacetyl functional groups with an amount of ammonia or primary amine sufficient to convert the acetoacetyl groups to enamine, b) storing the mixture for a period sufficient to allow the reactants to equilibrate, c) adding a sufficient amount of ammonia or primary amine to raise the pH to about 9, d) maintaining the pH at about 9 until the coating is applied to the substrate, (e) applying the coating to a substrate, and (f) exposing the coated substrate to ultraviolet light for a time sufficient to produce the desired degree of cure.
Claim 2
Dependent Claim 109 words
A process of preparing a cured coating on a surface comprising a) mixing a vinyl polymer having acetoacetyl functional groups with an amount of ammonia or primary amine sufficient to convert the acetoacetyl groups to enamine, b) storing the mixture for a period sufficient to allow the reactants to equilibrate, c) adding a sufficient amount of ammonia or primary amine to raise the pH to about 9, d) maintaining the pH at about 9 until the coating is applied to the substrate, (e) applying the coating to a substrate, and (f) exposing the coated substrate to ultraviolet light for a time sufficient to produce the desired degree of cure.
Claim 3
Dependent Claim 97 words
A process for preparing a coating with improved exterior durability comprising a) mixing a vinyl polymer having acetoacetyl functional groups with an amount of ammonia or primary amine sufficient to convert the acetoacetyl groups to enamine, b) storing the mixture for a period sufficient to allow the reactants to equilibrate, c) adding a sufficient amount of ammonia or primary amine to raise the pH to about 9, and d) maintaining the pH at about 9 until the coating is applied to the substrate, e) applying the coating to a substrate, f) exposing the coating to visible radiation.
Claim 4
Dependent Claim 97 words
A process for preparing a coating with improved exterior durability comprising a) mixing a vinyl polymer having acetoacetyl functional groups with an amount of ammonia or primary amine sufficient to convert the acetoacetyl groups to enamine, b) storing the mixture for a period sufficient to allow the reactants to equilibrate, c) adding a sufficient amount of ammonia or primary amine to raise the pH to about 9, and d) maintaining the pH at about 9 until the coating is applied to the substrate, e) applying the coating to a substrate, f) exposing the coating to visible radiation.

References Cited (Backward Citations)

GB1541891A Cited
US4906684A Cited
EP0492847A2 Cited
WO1993016133A2 Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1999-10-08 2000-04-08 2000-10-08 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 2003-10-08 2004-04-08 2004-10-08 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2007-10-08 2008-04-08 2008-10-08 $7700.00 Window Closed / Lapsed

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