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US4906684A Expired / Lapsed US ⏱️ 0.0 years remaining

Ambient temperature curing polymer compositions containing acetoacetoxyethyl methacrylate, glycidyl methacrylate and a polymerizable acid

Assignee: Rhodia Ltd
•
Filing: 1988-12-09
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Granted: 1990-03-06
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Expires: 2008-12-09
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Abstract

Abstract Ambient curing coating compositions are made from aqueous dispersions of copolymers of acetoacetoxyethyl acrylate or methacrylate, glycidyl arcylate or methacrylate, and ethylenically unsaturated polymerizable acid and a different monomer copolymerizable therewith.

Inventors

  • 👤 Terence E. Say

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-28 09:09
CPC Classifications
C; C09; C09D; C09D133/00; C09D133/04; C09D133/06; C09D133/062; C09D133/068

Claims Analysis

Total Claims: 10
Claim 1
Independent Claim 122 words
A thermosetting coating composition comprising an aqueous dispersion of a copolymer of (a) acetoacetoxy ethyl acrylate or methacrylate, (b) glycidyl acrylate or methacrylate, (c) an ethylenically unsaturated polymerizable acid, and (d) a monomer copolymerizable therewith wherein (a) and (b) are present in the weight ratio of less than or equal to 0.5 or greater than 1.5, wherein (b) and (c) are present in the weight ratio of greater than 1.5, wherein the total weight percent of (a), (b) and (c) in the polymer is at least about 8 and not more than about 60 weight percent, wherein (d) is present in the amount of about 40 to about cm 92 weight percents and wherein the pH is about 8.5 to about 10.
Claim 2
Dependent Claim 122 words
A thermosetting coating composition comprising an aqueous dispersion of a copolymer of (a) acetoacetoxy ethyl acrylate or methacrylate, (b) glycidyl acrylate or methacrylate, (c) an ethylenically unsaturated polymerizable acid, and (d) a monomer copolymerizable therewith wherein (a) and (b) are present in the weight ratio of less than or equal to 0.5 or greater than 1.5, wherein (b) and (c) are present in the weight ratio of greater than 1.5, wherein the total weight percent of (a), (b) and (c) in the polymer is at least about 8 and not more than about 60 weight percent, wherein (d) is present in the amount of about 40 to about cm 92 weight percents and wherein the pH is about 8.5 to about 10.
Claim 3
Dependent Claim 17 words
The composition of claim 1 wherein the ethylenically unsaturated polymerizable acid is acrylic acid or methacrylic acid.
Claim 4
Dependent Claim 27 words
The composition of claim 1 wherein the monomer polymerizable therewith is an alkyl acrylate or alkyl methacrylate wherein the alkyl group contains 1 to 8 carbon atoms.
Claim 5
Dependent Claim 13 words
The composition of claim 3 wherein the monomers are methylmethacrylate and butyl acrylate.
Claim 6
Dependent Claim 15 words
The composition of claim 1 wherein the pH is adjusted with a water soluble base.
Claim 7
Dependent Claim 10 words
The composition of claim 5 wherein the base is ammonia.
Claim 8
Dependent Claim 11 words
The composition of claim 5 wherein the base is sodium hydroxide.
Claim 9
Dependent Claim 13 words
The composition of claim 5 wherein the base is a quaternary ammonium hydroxide.
Claim 10
Dependent Claim 13 words
The composition of claim 8 wherein the quaternary ammonium hydroxide is tetramethylammonium hydroxide.

References Cited (Backward Citations)

US3223670A Cited
US4408018A Cited
US4435490A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1993-03-05 1993-09-04 1994-03-06 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1997-03-05 1997-09-04 1998-03-06 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2001-03-05 2001-09-04 2002-03-06 $7700.00 Window Closed / Lapsed

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