US5548404A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Multiple wavelength polarization-modulated ellipsometer with phase-generated carrier
Assignee: Sunshine Medical Instruments Inc
•
Filing: 1994-09-23
•
Granted: 1996-08-20
•
Expires: 2014-09-23
Abstract
Abstract A method and apparatus for analyzing a sample wherein at least two orthogonally polarized, intensity and phase modulated laser beams with different wavelengths and frequencies of intensity and phase modulation are directed onto the sample, and the signals derived from the laser beams which interact with the sample are synchronously demodulated to determine characteristics of the sample such as index of refraction, absorption coefficient and film thickness. A reference beam can be provided to correct for noise and drift.
Inventors
- 👤 Vladimir Kupershmidt
- 👤 Mikhail Kouchnir
- 👤 Robert Petersen
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-30 22:38
CPC Classifications
G; G01; G01N; G01N21/00; G01N21/17; G01N21/21; G01N21/211
Claims Analysis
Total Claims: 63
Claim 1
Independent Claim
136 words
A method of analyzing a sample comprising: generating a first laser beam having a first wavelength, a first optical frequency modulation and a first intensity modulation by applying current modulation to a laser diode at a first wavelength; generating a second laser beam having a second wavelength, a second optical frequency modulation and a second intensity modulation by applying current modulation to a laser diode at a second wavelength; polarizing the first laser beam in a first direction and polarizing the second laser beam in a second direction perpendicular to the first direction; modulating the optical phase difference between the polarized components of the first and second laser beams; directing the intensity and optical phase difference modulated laser beams onto a sample; synchronously demodulating signals derived from the detected laser beams; and analyzing the demodulated signals.
Claim 2
Independent Claim
136 words
A method of analyzing a sample comprising: generating a first laser beam having a first wavelength, a first optical frequency modulation and a first intensity modulation by applying current modulation to a laser diode at a first wavelength; generating a second laser beam having a second wavelength, a second optical frequency modulation and a second intensity modulation by applying current modulation to a laser diode at a second wavelength; polarizing the first laser beam in a first direction and polarizing the second laser beam in a second direction perpendicular to the first direction; modulating the optical phase difference between the polarized components of the first and second laser beams; directing the intensity and optical phase difference modulated laser beams onto a sample; synchronously demodulating signals derived from the detected laser beams; and analyzing the demodulated signals.
Claim 3
Dependent Claim
16 words
The method of claim 1, further comprising rotating the direction of polarization of each laser beam.
Claim 4
Dependent Claim
27 words
The method of claim 2, wherein the direction of polarization of each laser beam is rotated 45° in a plane perpendicular to the direction of beam propagation.
Claim 5
Dependent Claim
36 words
The method of claim 1, wherein the optical phase difference modulation is provided by a birefringent polarization element which provides optical path differences for components of laser beams of different directions of polarization and different wavelengths.
Claim 6
Dependent Claim
22 words
The method of claim 1, wherein the analysis step comprises measuring the amplitudes and phases of the harmonics of the detected signal.
Claim 7
Dependent Claim
48 words
The method of claim 1, wherein the optical phase difference between the polarized components of the first and second laser beams are modulated at first and second frequencies, the method further comprising detecting the laser beams at their frequencies of intensity and optical phase difference modulation essentially simultaneously.
Claim 8
Dependent Claim
24 words
The method of claim 1, wherein the intensity modulations are provided by driving a first and second laser diode by a ramp current waveform.
Claim 9
Dependent Claim
24 words
The method of claim 1, wherein the intensity modulations are provided by driving a first and second laser diode by a sine current waveform.
Claim 10
Dependent Claim
34 words
The method of claim 1, further comprising separating the modulated laser beams into a probe beam which is directed onto the sample and a reference beam, and separately detecting the probe and reference beams.
Claim 11
Dependent Claim
28 words
The method of claim 1, further comprising splitting the laser beam reflected from the sample into two laser beams with different polarizations and separately detecting each laser beam.
Claim 12
Dependent Claim
17 words
The method of claim 1, wherein the detection step comprises detecting laser beams reflected from the sample.
Claim 13
Dependent Claim
16 words
The method of claim 1, wherein the detecting step comprises detecting beams transmitted by the sample.
Claim 14
Dependent Claim
58 words
The method of claim 1, further comprising generating a third laser beam having a third wavelength, a third optical frequency modulation and a third intensity modulation, polarizing the third laser beam in a third direction perpendicular to the first and second directions of polarization, and modulating the optical phase difference between the polarized components of the third beam.
Claim 15
Dependent Claim
15 words
The method of claim 1, wherein the first and second laser beams are generated simultaneously.
Claim 16
Dependent Claim
16 words
The method of claim 1, wherein the first and second laser beams are generated in sequence.
Claim 17
Dependent Claim
35 words
The method of claim 1, further comprising computing the ratio of the amplitudes of the harmonics corresponding to the frequencies of intensity modulation and the frequencies of optical phase difference modulation for each laser beam.
Claim 18
Independent Claim
94 words
A method of analyzing a thin film on a substrate comprising: generating at least two polarized laser beams each having different wavelengths, optical frequency modulations and intensity modulations; modulating the optical phase difference between the polarized components of each laser beam; splitting the laser beams into a reference beam and a probe beam; detecting the reference beam; directing the probe beam onto a sample; detecting the probe beam after it interacts with the sample; synchronously demodulating signals derived from the detected beams; and determining characteristics of the thin film based on the demodulated signals.
Claim 19
Independent Claim
94 words
A method of analyzing a thin film on a substrate comprising: generating at least two polarized laser beams each having different wavelengths, optical frequency modulations and intensity modulations; modulating the optical phase difference between the polarized components of each laser beam; splitting the laser beams into a reference beam and a probe beam; detecting the reference beam; directing the probe beam onto a sample; detecting the probe beam after it interacts with the sample; synchronously demodulating signals derived from the detected beams; and determining characteristics of the thin film based on the demodulated signals.
Claim 20
Dependent Claim
28 words
The method of claim 17, further comprising splitting the probe beam after it interacts with the sample into two beams with different polarizations and separately detecting each beam.
Claim 21
Dependent Claim
22 words
The method of claim 18, further comprising splitting the reference beam into two beams with different polarizations and separately detecting each beam.
Claim 22
Dependent Claim
46 words
The method of claim 17, further comprising generating a third polarized laser beam having a wavelength, an optical frequency modulation and an intensity modulation different than the at least two laser beams and modulating the optical phase difference between the polarized components of the third beam.
Claim 23
Independent Claim
59 words
A method of analyzing a sample comprising: directing at least two orthogonally polarized, intensity and frequency modulated laser beams whose optical phase difference between polarized components is modulated, the laser beams having different wavelengths, different intensity modulation and optical phase difference modulation onto a surface; and synchronously demodulating signals derived from the laser beams which interact with the surface.
Claim 24
Independent Claim
59 words
A method of analyzing a sample comprising: directing at least two orthogonally polarized, intensity and frequency modulated laser beams whose optical phase difference between polarized components is modulated, the laser beams having different wavelengths, different intensity modulation and optical phase difference modulation onto a surface; and synchronously demodulating signals derived from the laser beams which interact with the surface.
Claim 25
Independent Claim
125 words
A method of analyzing a sample comprising: driving a first laser diode with a first modulated current to generate a first intensity modulated and optical frequency modulated laser beam having a first wavelength; driving a second laser diode with a second modulated current to generate a second intensity and optical frequency modulated laser beam having a second wavelength; orthogonally polarizing the laser beams; subjecting the laser beams to optical path differences to modulate the optical phase difference between the polarized components of the laser beams at different frequencies of modulation; directing the modulated optical phase difference laser beams onto a sample; synchronously demodulating signals derived from the laser beams which interact with the sample; and analyzing characteristics of the sample based on the demodulated signals.
Claim 26
Independent Claim
125 words
A method of analyzing a sample comprising: driving a first laser diode with a first modulated current to generate a first intensity modulated and optical frequency modulated laser beam having a first wavelength; driving a second laser diode with a second modulated current to generate a second intensity and optical frequency modulated laser beam having a second wavelength; orthogonally polarizing the laser beams; subjecting the laser beams to optical path differences to modulate the optical phase difference between the polarized components of the laser beams at different frequencies of modulation; directing the modulated optical phase difference laser beams onto a sample; synchronously demodulating signals derived from the laser beams which interact with the sample; and analyzing characteristics of the sample based on the demodulated signals.
Claim 27
Dependent Claim
66 words
The method of claim 22, wherein the first and second modulated currents are derived by: determining the desired output of the laser diodes; determining a theoretical signal required to achieve the desired output; estimating the distortions which can modify the desired output; determining an adjustment to the theoretical signal to compensate for the known distortions; further adjusting the theoretical signal until the desired output is achieved.
Claim 28
Dependent Claim
15 words
The method of claim 22, wherein the first and second modulated currents are empirically determined.
Claim 29
Dependent Claim
16 words
The method of claim 22, wherein the synchronous demodulation step comprises a plurality of demodulation techniques.
Claim 30
Dependent Claim
73 words
The method of claim 22, further comprising: after the subjecting step, splitting the laser beams into a reference beam and a probe beam, wherein the probe beam is directed onto the sample; separately detecting the reference beam; comparing signals derived from the detected reference beam with expected reference values; and adjusting the synchronously demodulated signals based on the difference between the signals derived from the detected reference beam and the expected reference values.
Claim 31
Independent Claim
179 words
An apparatus for analyzing a sample comprising: a first laser diode which emits a first intensity and optical frequency modulated laser beam at a first wavelength and a first frequency of modulation; a first polarizer located downstream of the first laser diode, the first polarizer polarizing the first laser beam in a first direction; a second laser diode which emits a second intensity and optical frequency modulated laser beam at a second wavelength and a second frequency of modulation; a second polarizer located downstream of the second laser diode, the second polarizer polarizing the second laser beam in a second direction perpendicular to the first direction; a birefringent polarization element which introduces an optical path difference between perpendicular components of the polarized laser beams passing through it, to modulate the optical phase difference of the polarized components of the laser beams; coupling optics coupling the polarized laser beams to the birefringent element; a photodetector proximate the sample; a synchronous demodulator operatively connected to the photodetector; and an analyzer which analyzes the demodulated signals to derive characteristics of the sample.
Claim 32
Independent Claim
179 words
An apparatus for analyzing a sample comprising: a first laser diode which emits a first intensity and optical frequency modulated laser beam at a first wavelength and a first frequency of modulation; a first polarizer located downstream of the first laser diode, the first polarizer polarizing the first laser beam in a first direction; a second laser diode which emits a second intensity and optical frequency modulated laser beam at a second wavelength and a second frequency of modulation; a second polarizer located downstream of the second laser diode, the second polarizer polarizing the second laser beam in a second direction perpendicular to the first direction; a birefringent polarization element which introduces an optical path difference between perpendicular components of the polarized laser beams passing through it, to modulate the optical phase difference of the polarized components of the laser beams; coupling optics coupling the polarized laser beams to the birefringent element; a photodetector proximate the sample; a synchronous demodulator operatively connected to the photodetector; and an analyzer which analyzes the demodulated signals to derive characteristics of the sample.
Claim 33
Dependent Claim
19 words
The apparatus of claim 27, further comprising at least one controller which modulates a current driving the laser diodes.
Claim 34
Dependent Claim
44 words
The apparatus of claim 27, wherein the coupling optics comprises a half-wave plate between the first and second polarizers and the birefringent polarization element such that the first and second polarized laser beams pass through the half-wave plate prior to passing through the element.
Claim 35
Dependent Claim
93 words
The apparatus of claim 29, wherein the coupler optics comprises: a beam folding prism between the first polarizer and the birefringent element; a polarizing beam splitter cube between the second polarizer and the birefringent element and between the prism and the birefringent element, such that the prism reflects the first polarized laser beam through the cube, to the element, and the cube reflects the second polarized laser beam to the element, such that the first and second laser beams propagate in the same direction and coincide in space when they exit the cube.
Claim 36
Dependent Claim
32 words
The apparatus of claim 27, wherein the coupler optics comprises a quarter-wave plate, wherein the first and second polarized laser beams pass through the quarter-wave plate prior to passing through the element.
Claim 37
Dependent Claim
94 words
The apparatus of claim 31, wherein the coupler optics comprises: a beam folding prism between the first polarizer and the infringement element; a polarizing beam splitter cube between the second polarizer and the birefringent element and between the prism and the birefringent element, such that the prism reflects the first polarized laser beam through the cube, to the element, and the cube reflects the second polarized laser beam to the element, such that the first and second laser beams propagate in the same optical direction and coincide in space when they exit the cube.
Claim 38
Dependent Claim
95 words
The apparatus of claim 27, wherein the coupling optics comprises: a beam folding prism between the first polarizer and the birefringement element; and a polarizing beam splitter cube between the second polarizer and the birefringent element and between the prism and the birefringent element, such that the prism reflects the first polarized laser beam through the cube, to the element, and the cube reflects the second polarized laser beam to the element, such that the first and second laser beams propagate in the same optical direction and coincide in space when they exit the cube.
Claim 39
Dependent Claim
16 words
The apparatus of claim 33, wherein the birefringent element is rotated with respect to the cube.
Claim 40
Dependent Claim
46 words
The apparatus of claim 27, further comprising a beam splitter cube downstream of the birefringent element in the direction of beam propagation, the beam splitting cube splitting the laser beams output from the element into a probe beam directed toward the sample and a reference beam.
Claim 41
Dependent Claim
32 words
The apparatus of claim 35, wherein the detector proximate the sample collects the laser beams which interact with the sample, the apparatus further comprising a second detector for collecting the reference beam.
Claim 42
Dependent Claim
12 words
The apparatus of claim 27, wherein the detector is a balanced photodetector.
Claim 43
Dependent Claim
32 words
The apparatus of claim 37, wherein the balanced photodetector comprises a polarizing beam splitter cube and a second and third detector to collect the laser beams at a first and second angle.
Claim 44
Dependent Claim
15 words
The apparatus of claim 38, wherein the polarizing beam splitter cube is a Wollaston prism.
Claim 45
Dependent Claim
65 words
The apparatus of claim 27, wherein the birefringent element comprises a first polarizing beam splitter cube, a second polarizing beam splitter cube, and a prism, arranged such that laser beams with the first direction of polarization pass through the first and second cube and laser beams with the second direction of polarization are reflected from the first cube, through the prism, to the second cube.
Claim 46
Dependent Claim
12 words
The apparatus of claim 27, wherein the birefringent element is one piece.
Claim 47
Dependent Claim
242 words
An ellipsometer comprising: a first laser diode which emits a first laser beam at a first wavelength; a second laser diode which emits a second laser beam at a second wavelength; at least one current controller driving the first and second laser diodes with modulated current at first and second frequencies, respectively; a first polarizer positioned downstream of the first laser diode having a first direction of polarization; a second polarizer positioned downstream of the second laser diode having a second direction of polarization, the first and second directions of polarization being perpendicular to each other; a beam turning prism located downstream of the first polarizer; a polarizing beam splitting cube positioned downstream of the second polarizer; a birefringent element; the prism and the cube being positioned between the polarizing beam splitting cube and the birefringent element, such that the prism reflects the first laser beam through the cube and the cube reflects the second laser beam in the same direction as the first laser beam, wherein the first and second optical beams coincide in space and each have first and second polarized components with respect to the optical axis of the birefringent element; the birefringent element introducing an optical path difference between the first and second polarized components of each laser beam; a detector, wherein the laser beam output from the element interacts with a sample and is collected by the detector; and a synchronous demodulator operatively connected to the detector.
Claim 48
Dependent Claim
242 words
An ellipsometer comprising: a first laser diode which emits a first laser beam at a first wavelength; a second laser diode which emits a second laser beam at a second wavelength; at least one current controller driving the first and second laser diodes with modulated current at first and second frequencies, respectively; a first polarizer positioned downstream of the first laser diode having a first direction of polarization; a second polarizer positioned downstream of the second laser diode having a second direction of polarization, the first and second directions of polarization being perpendicular to each other; a beam turning prism located downstream of the first polarizer; a polarizing beam splitting cube positioned downstream of the second polarizer; a birefringent element; the prism and the cube being positioned between the polarizing beam splitting cube and the birefringent element, such that the prism reflects the first laser beam through the cube and the cube reflects the second laser beam in the same direction as the first laser beam, wherein the first and second optical beams coincide in space and each have first and second polarized components with respect to the optical axis of the birefringent element; the birefringent element introducing an optical path difference between the first and second polarized components of each laser beam; a detector, wherein the laser beam output from the element interacts with a sample and is collected by the detector; and a synchronous demodulator operatively connected to the detector.
Claim 49
Dependent Claim
16 words
The apparatus of claim 42, further comprising a half-wave plate between the cube and the element.
Claim 50
Dependent Claim
16 words
The apparatus of claim 42, further comprising a quarter-wave plate between the cube and the element.
Claim 51
Dependent Claim
16 words
The apparatus of claim 42, wherein the birefringent element is rotated with respect to the cube.
Claim 52
Dependent Claim
52 words
The apparatus of claim 42, further comprising a beam splitting cube downstream of the element, the beam splitting cube splitting the laser beam exiting the element into a first portion which is directed onto the sample and a second portion, the apparatus further comprising a second detector for collecting the second portion.
Claim 53
Dependent Claim
65 words
The apparatus of claim 42, wherein the birefringent element comprises a first polarizing beam splitter cube, a second polarizing beam splitter cube, and a prism, arranged such that laser beams with the first direction of polarization pass through the first and second cube and laser beams with the second direction of polarization are reflected from the first cube, through the prism, to the second cube.
Claim 54
Independent Claim
108 words
An apparatus for analyzing a sample comprising; at least two laser diodes providing at least two laser beams having different wavelengths, different optical frequency modulations and different intensity modulations; at least two polarizers to orthogonally polarize the laser beams; a birefringent polarization element which introduces an optical path difference between perpendicular components of the laser beams passing through it, to modulate the optical phase difference between the polarized components of the laser beams; coupling optics coupling the polarized laser beams to the birefringent element; wherein the modulated laser beams are directed onto the sample; a photodetector proximate the sample; and a synchronous demodulator operatively connected to the photodetector.
Claim 55
Independent Claim
108 words
An apparatus for analyzing a sample comprising; at least two laser diodes providing at least two laser beams having different wavelengths, different optical frequency modulations and different intensity modulations; at least two polarizers to orthogonally polarize the laser beams; a birefringent polarization element which introduces an optical path difference between perpendicular components of the laser beams passing through it, to modulate the optical phase difference between the polarized components of the laser beams; coupling optics coupling the polarized laser beams to the birefringent element; wherein the modulated laser beams are directed onto the sample; a photodetector proximate the sample; and a synchronous demodulator operatively connected to the photodetector.
Claim 56
Dependent Claim
38 words
The apparatus of claim 48, further comprising; a third laser diode providing a third laser beam at a different wavelength, different optical frequency modulation and different intensity modulation than the first two laser beams; and a third polarizer.
Claim 57
Dependent Claim
49 words
The apparatus of claim 49, further comprising a beam splitter cube downstream of the birefringent element, to split the laser beam output from the birefringent element into a probe beam directed toward the sample and a reference beam, the apparatus further comprising a detector to detect the reference beam.
Claim 58
Independent Claim
138 words
An apparatus for analyzing a sample comprising: means for generating a first laser beam at a first wavelength, having a first optical frequency modulation and intensity modulation; means for generating a second laser beam at a second wavelength, having a second optical frequency modulation and intensity modulation; means for orthogonally polarizing the first and second laser beams; means for modulating the optical phase difference between polarized components of the first and second laser beams at different frequencies; means for coupling the orthogonally polarized laser beams to the means for modulating the optical phase difference; means for directing the modulated laser beams onto a sample; means for detecting laser beams which interact with the sample; means for synchronously demodulating signals derived from the detected laser beams; and means for analyzing the demodulated signals to derive characteristics of the sample.
Claim 59
Independent Claim
138 words
An apparatus for analyzing a sample comprising: means for generating a first laser beam at a first wavelength, having a first optical frequency modulation and intensity modulation; means for generating a second laser beam at a second wavelength, having a second optical frequency modulation and intensity modulation; means for orthogonally polarizing the first and second laser beams; means for modulating the optical phase difference between polarized components of the first and second laser beams at different frequencies; means for coupling the orthogonally polarized laser beams to the means for modulating the optical phase difference; means for directing the modulated laser beams onto a sample; means for detecting laser beams which interact with the sample; means for synchronously demodulating signals derived from the detected laser beams; and means for analyzing the demodulated signals to derive characteristics of the sample.
Claim 60
Dependent Claim
28 words
The apparatus of claim 51, further comprising means for splitting the modulated laser beams into a probe beam which is directed onto the sample, and a reference beam.
Claim 61
Dependent Claim
22 words
The apparatus of claim 52, wherein the means for synchronously demodulating the detected signals demodulates the sample signal with the reference signal.
Claim 62
Dependent Claim
14 words
The apparatus of claim 51, further comprising means for separately detecting the reference beam.
Claim 63
Dependent Claim
22 words
The apparatus of claim 54, wherein the means for synchronously demodulating the detected signals demodulates the sample signal with the reference signal.
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| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1999-08-20 | 2000-02-19 | 2000-08-20 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 2003-08-20 | 2004-02-19 | 2004-08-20 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 2007-08-20 | 2008-02-19 | 2008-08-20 | $7700.00 | Window Closed / Lapsed |