Storage and delivery system for gaseous hydride, halide, and organometallic group V compounds

Claim 2

A process for supplying a gas, comprising: providing a storage and dispensing vessel containing a solid-phase physical sorbent medium having a physically sorptive affinity for said gas; physically sorptively loading said gas on said solid-phase physical sorbent medium as a sorbate gas, to yield a sorbate gas-loaded physical sorbent medium; and selectively desorbing at least a portion of said sorbate gas from the sorbate gas-loaded physical sorbent medium, by reduced pressure desorption, for dispensing thereof; wherein any water, metals, and oxidic transition metal species present on the solid-phase physical sorbent medium are at a concentration which is insufficient to decompose more than 5% by weight of the sorbate gas in said storage and dispensing vessel after 1 year at 25° C. at said interior gas pressure.

Claim 3

A process according to claim 1, wherein the solid-phase physical sorbent medium contains less than 500 parts-per-million by weight of trace components selected from the group consisting of water and oxidic transition metal species, based on the weight of the physical sorbent medium.

Claim 4

A process according to claim 1, wherein the solid-phase physical sorbent medium contains less than 100 parts-per-million by weight of trace components selected from the group consisting of water and oxidic transition metal species, based on the weight of the physical sorbent medium.

Claim 5

A process according to claim 1, wherein the solid-phase physical sorbent medium contains no more than 1 part-per-million by weight of trace components selected from the group consisting of water and oxidic transition metal species, based on the weight of the physical sorbent medium.

Claim 6

A process according to claim 1, wherein the solid-phase physical sorbent medium concentration of trace components selected from the group consisting of water and oxidic transition metal species, based on the weight of the physical sorbent medium, is insufficient to cause decomposition of the sorbate gas resulting in more than 25% rise in interior pressure after 1 week at 25° C. in said storage and dispensing vessel.

Claim 7

A process according to claim 1, wherein the oxidic transition metal species are selected from the group consisting of oxides, sulfites and nitrates.

Claim 8

A process according to claim 1, wherein the sorbate gas is a hydride gas.

Claim 9

A process according to claim 1, wherein the sorbate gas is selected from the group consisting of arsine and phosphine.

Claim 10

A process according to claim 1, wherein the sorbate gas is boron trifluoride.

Claim 11

A process according to claim 1, further comprising selectively heating the solid-phase physical sorbent medium, to effect thermally-enhanced desorption of the sorbate gas from the solid-phase physical sorbent medium.

Claim 12

A process according to claim 1, wherein the solid-phase physical sorbent medium comprises a material selected from the group consisting of silica, carbon molecular sieves, alumina, macroreticulate polymers, kieselguhr, carbon, and aluminosilicates.

Claim 13

A process according to claim 1, wherein the solid-phase physical sorbent medium comprises a crystalline aluminosilicate composition.

Claim 14

A process according to claim 12, wherein the crystalline aluminosilicate composition has pore size in the range of from about 4 to about 13 Angstroms.

Claim 15

A process according to claim 12, wherein the crystalline aluminosilicate composition comprises 5A molecular sieve.

Claim 16

A process according to claim 12, wherein the crystalline aluminosilicate composition comprises a binderless molecular sieve.

Claim 17

A process according to claim 1, wherein the solid-phase physical sorbent medium is present in said storage and dispensing vessel with a chemisorbent material having a sorptive affinity for contaminants of said sorbate gas therein.

Claim 18

A process according to claim 16, wherein the chemisorbent material has a sorptive affinity for non-inert atmospheric gases.

Claim 19

A process according to claim 16, wherein the chemisorbent material comprises a scavenger selected from the group consisting of: (A) a scavenger including a support having associated therewith, but not covalently bonded thereto, a compound which in the presence of said contaminant provides an anion which is reactive to effect the removal of said contaminant, said compound being selected from one or more members of the group consisting of: (i) carbanion source compounds whose corresponding protonated carbanion compounds have a pK a value of from about 22 to about 36; and (ii) anion source compounds formed by reaction of said carbanion source compounds with the sorbate gas; and (B) a scavenger comprising: (i) an inert support having a surface area in the range of from about 50 to about 1000 square meters per gram, and thermally stable up to at least about 250° C.; and (ii) an active scavenging species, present on the support at a concentration of from about 0.01 to about 1.0 moles per liter of support, and formed by the deposition on the support of a Group IA metal selected from sodium, potassium, rubidium, and cesium and their mixtures and alloys and pyrolysis thereof on said support.

Claim 20

A process according to claim 16, wherein the chemisorbent material is selected from the group consisting of potassium arsenide and trityllithium.

Claim 21

A process according to claim 1, wherein the sorbate gas comprises an impurity component, and the solid-phase physical sorbent medium is provided in the storage and dispensing vessel together with an impurity scavenger for removal of the impurity component from the sorbate gas.

Claim 22

A process for supplying a gas, comprising: providing a storage and dispensing vessel containing a solid-phase physical sorbent medium having a physically sorptive affinity for said gas; physically sorptively loading said gas on said solid-phase physical sorbent medium as a sorbate gas, to yield a sorbate gas-loaded physical sorbent medium; and selectively desorbing at least a portion of said sorbate gas from the sorbate gas-loaded physical sorbent medium, by reduced pressure desorption, for dispensing thereof; wherein the solid-phase physical sorbent medium concentration of trace components selected from the group consisting of water, metals, and oxidic transition metal species, based on the weight of the physical sorbent medium, is insufficient to cause decomposition of the sorbate gas resulting in more than a 10% rise in interior pressure after 1 week at 25° C. in said storage and dispensing vessel.

Claim 23

A process for supplying a gas, comprising: providing a storage and dispensing vessel containing a solid-phase physical sorbent medium having a physically sorptive affinity for said gas; physically sorptively loading said gas on said solid-phase physical sorbent medium as a sorbate gas, to yield a sorbate gas-loaded physical sorbent medium; and selectively desorbing at least a portion of said sorbate gas from the sorbate gas-loaded physical sorbent medium, by reduced pressure desorption, for dispensing thereof; wherein the solid-phase physical sorbent medium concentration of trace components selected from the group consisting of water, metals, and oxidic transition metal species, based on the weight of the physical sorbent medium, is insufficient to cause decomposition of the sorbate gas resulting in more than a 10% rise in interior pressure after 1 week at 25° C. in said storage and dispensing vessel.

Claim 24

A process according to claim 21, wherein the solid-phase physical sorbent medium contains less than 500 parts-per-million by weight of trace components selected from the group consisting of water and oxidic transition metal species, based on the weight of the physical sorbent medium.

Claim 25

A process according to claim 21, wherein the solid-phase physical sorbent medium contains less than 100 parts-per-million by weight of trace components selected from the group consisting of water and oxidic transition metal species, based on the weight of the physical sorbent medium.

Claim 26

A process according to claim 21, wherein the solid-phase physical sorbent medium contains no more than 1 part-per-million by weight of trace components selected from the group consisting of water and oxidic transition metal species, based on the weight of the physical sorbent medium.

Claim 27

A process according to claim 21, wherein the solid-phase physical sorbent medium concentration of trace components selected from the group consisting of water and oxidic transition metal species, based on the weight of the physical sorbent medium, is insufficient to decompose more than 5% by weight of the sorbate gas after 1 year at 25° C. and said interior pressure, in said storage and dispensing vessel.

Claim 28

A process according to claim 21, wherein the oxidic transition metal species are selected from the group consisting of oxides, sulfates, sulfites and nitrates.

Claim 29

A process according to claim 21, wherein the sorbate gas is a hydride gas.

Claim 30

A process according to claim 21, wherein the sorbate gas is selected from the group consisting of arsine and phosphine.

Claim 31

A process according to claim 21, wherein the sorbate gas is boron trifluoride.

Claim 32

An adsorption-desorption process for storage and dispensing of boron trifluoride, said process comprising: providing a storage and dispensing vessel containing a solid-phase physical sorbent medium having a physically sorptive affinity for boron trifluoride; physically sorptively loading boron trifluoride on said solid-phase physical sorbent medium, to yield a boron trifluoride-loaded physical sorbent medium; and selectively desorbing at least a portion of said boron trifluoride from the boron trifluoride-loaded physical sorbent medium, by reduced pressure desorption, for dispensing thereof.

Claim 33

An adsorption-desorption process for storage and dispensing of boron trifluoride, said process comprising: providing a storage and dispensing vessel containing a solid-phase physical sorbent medium having a physically sorptive affinity for boron trifluoride; physically sorptively loading boron trifluoride on said solid-phase physical sorbent medium, to yield a boron trifluoride-loaded physical sorbent medium; and selectively desorbing at least a portion of said boron trifluoride from the boron trifluoride-loaded physical sorbent medium, by reduced pressure desorption, for dispensing thereof.

Claim 34

A process for storage and dispensing of a gas sorbable on a solid-phase physical sorbent medium, said process comprising: providing a storage and dispensing vessel holding a solid-phase physical sorbent medium; adsorbing said gas on said solid-phase physical sorbent medium to yield said gas adsorbed on said solid-phase physical sorbent medium, at an interior pressure in said storage and dispensing vessel; establishing, exteriorly of said storage and dispensing vessel, a pressure below said interior pressure, to effect desorption of at least a portion of said gas from the solid-phase physical sorbent medium as desorbed gas, and flowing said desorbed gas out of the storage and dispensing vessel; cryopumping the desorbed gas from the storage and dispensing vessel to a predetermined pressure, wherein said predetermined pressure is higher than the pressure of the desorbed gas flowed out of the storage and dispensing vessel.

Claim 35

A process for storage and dispensing of a gas sorbable on a solid-phase physical sorbent medium, said process comprising: providing a storage and dispensing vessel holding a solid-phase physical sorbent medium; adsorbing said gas on said solid-phase physical sorbent medium to yield said gas adsorbed on said solid-phase physical sorbent medium, at an interior pressure in said storage and dispensing vessel; establishing, exteriorly of said storage and dispensing vessel, a pressure below said interior pressure, to effect desorption of at least a portion of said gas from the solid-phase physical sorbent medium as desorbed gas, and flowing said desorbed gas out of the storage and dispensing vessel; cryopumping the desorbed gas from the storage and dispensing vessel to a predetermined pressure, wherein said predetermined pressure is higher than the pressure of the desorbed gas flowed out of the storage and dispensing vessel.

Claim 36

An adsorption-desorption apparatus, for storage and dispensing of a gas, said apparatus comprising: a storage and dispensing vessel constructed and arranged for holding a solid-phase physical sorbent medium, and for selectively flowing gas into and out of said vessel; a solid-phase physical sorbent medium disposed in said storage and dispensing vessel at an interior gas pressure; a sorbate gas physically adsorbed on said solid-phase physical sorbent medium; a dispensing assembly coupled in gas flow communication with the storage and dispensing vessel, and constructed and arranged to provide, exteriorly of said storage and dispensing vessel, a pressure below said interior pressure, to effect desorption of at least a portion of said sorbate gas from the solid-phase physical sorbent medium and yield desorbed gas, and gas flow of said desorbed gas through the dispensing assembly; wherein any water, metals, and oxidic transition metal species present on the solid-phase physical sorbent medium are at a concentration which is insufficient to decompose more than 5% by weight of the sorbate gas in said storage and dispensing vessel after 1 year at 25° C. at said interior gas pressure.

Claim 37

An adsorption-desorption apparatus, for storage and dispensing of a gas, said apparatus comprising: a storage and dispensing vessel constructed and arranged for holding a solid-phase physical sorbent medium, and for selectively flowing gas into and out of said vessel; a solid-phase physical sorbent medium disposed in said storage and dispensing vessel at an interior gas pressure; a sorbate gas physically adsorbed on said solid-phase physical sorbent medium; a dispensing assembly coupled in gas flow communication with the storage and dispensing vessel, and constructed and arranged to provide, exteriorly of said storage and dispensing vessel, a pressure below said interior pressure, to effect desorption of at least a portion of said sorbate gas from the solid-phase physical sorbent medium and yield desorbed gas, and gas flow of said desorbed gas through the dispensing assembly; wherein any water, metals, and oxidic transition metal species present on the solid-phase physical sorbent medium are at a concentration which is insufficient to decompose more than 5% by weight of the sorbate gas in said storage and dispensing vessel after 1 year at 25° C. at said interior gas pressure.

Claim 38

Apparatus according to claim 32, wherein the solid-phase physical sorbent medium contains less than 500 parts-per-million by weight of trace components selected from the group consisting of water and oxidic transition metal species, based on the weight of the physical sorbent medium.

Claim 39

Apparatus according to claim 32, wherein the solid-phase physical sorbent medium contains less than 100 parts-per-million by weight of trace components selected from the group consisting of water and oxidic transition metal species, based on the weight of the physical sorbent medium.

Claim 40

Apparatus according to claim 32, wherein the solid-phase physical sorbent medium contains no more than 1 part-per-million by weight of trace components selected from the group consisting of water and oxidic transition metal species, based on the weight of the physical sorbent medium.

Claim 41

Apparatus according to claim 1, wherein the solid-phase physical sorbent medium concentration of trace components selected from the group consisting of water and oxidic transition metal species, based on the weight of the physical sorbent medium, is insufficient to decompose more than 1% by weight of the sorbate gas after 1 year at 25° C. and said interior pressure.

Claim 42

Apparatus according to claim 32, wherein the oxidic transition metal species are selected from the group consisting of oxides, sulfites and nitrates.

Claim 43

Apparatus according to claim 32, wherein the sorbate gas is a hydride gas.

Claim 44

Apparatus according to claim 32, wherein the sorbate gas is selected from the group consisting of arsine and phosphine.

Claim 45

Apparatus according to claim 32, wherein the sorbate gas is boron trifluoride.

Claim 46

Apparatus according to claim 32, further comprising a heater operatively arranged in relation to the storage and dispensing vessel for selective heating of the solid-phase physical sorbent medium, to effect thermally-enhanced desorption of the sorbate gas from the solid-phase physical sorbent medium.

Claim 47

Apparatus according to claim 32, wherein the solid-phase physical sorbent medium comprises a material selected from the group consisting of silica, carbon molecular sieves, alumina, macroreticulate polymers, kieselguhr, carbon, and aluminosilicates.

Claim 48

Apparatus according to claim 32, wherein the solid-phase physical sorbent medium comprises a crystalline aluminosilicate composition.

Claim 49

Apparatus according to claim 43, wherein the crystalline aluminosilicate composition has pore size in the range of from about 4 to about 13 Angstroms.

Claim 50

Apparatus according to claim 43, wherein the crystalline aluminosilicate composition comprises 5A molecular sieve.

Claim 51

Apparatus according to claim 43, wherein the crystalline aluminosilicate composition comprises a binderless molecular sieve.

Claim 52

Apparatus according to claim 32, wherein the solid-phase physical sorbent medium is present in said storage and dispensing vessel with a chemisorbent material having a sorptive affinity for contaminants of said sorbate gas therein.

Claim 53

Apparatus according to claim 47, wherein the chemisorbent material has a sorptive affinity for non-inert atmospheric gases.

Claim 54

Apparatus according to claim 47, wherein the chemisorbent material comprises a scavenger selected from the group consisting of: (A) a scavenger including a support having associated therewith, but not covalently bonded thereto, a compound which in the presence of said contaminant provides an anion which is reactive to effect the removal of said contaminant, said compound being selected from one or more members of the group consisting of. (i) carbanion source compounds whose corresponding protonated carbanion compounds have a pK a value of from about 22 to about 36; and (ii) anion source compounds formed by reaction of said carbanion source compounds with the sorbate gas; and (B) a scavenger comprising: (i) an inert support having a surface area in the range of from about 50 to about 1000 square meters per gram, and thermally stable up to at least about 250° C.; and (ii) an active scavenging species, present on the support at a concentration of from about 0.01 to about 1.0 moles per liter of support, and formed by the deposition on the support of a Group IA metal selected from sodium, potassium, rubidium, and cesium and their mixtures and alloys and pyrolysis thereof on said support.

Claim 55

Apparatus according to claim 47, wherein the chemisorbent material is selected from the group consisting of potassium arsenide and trityllithium.

Claim 56

An adsorption-desorption apparatus, for storage and dispensing of a gas, said apparatus comprising: a storage and dispensing vessel constructed and arranged for holding a solid-phase physical sorbent medium, and for selectively flowing gas into and out of said vessel; a solid-phase physical sorbent medium disposed in said storage and dispensing vessel at an interior gas pressure; a sorbate gas physically adsorbed on said solid-phase physical sorbent medium; a dispensing assembly coupled in gas flow communication with the storage and dispensing vessel, and constructed and arranged to provide, exteriorly of said storage and dispensing vessel, a pressure below said interior pressure, to effect desorption of at least a portion of said sorbate gas from the solid-phase physical sorbent medium and yield desorbed gas, and gas flow of said desorbed gas through the dispensing assembly; wherein the solid-phase physical sorbent medium concentration of trace components selected from the group consisting of water, metals, and oxidic transition metal species, based on the weight of the physical sorbent medium, is insufficient to cause decomposition of the sorbate gas resulting in more than a 5% rise in interior pressure after 1 week at 25° C. in said storage and dispensing vessel.

Claim 57

An adsorption-desorption apparatus, for storage and dispensing of a gas, said apparatus comprising: a storage and dispensing vessel constructed and arranged for holding a solid-phase physical sorbent medium, and for selectively flowing gas into and out of said vessel; a solid-phase physical sorbent medium disposed in said storage and dispensing vessel at an interior gas pressure; a sorbate gas physically adsorbed on said solid-phase physical sorbent medium; a dispensing assembly coupled in gas flow communication with the storage and dispensing vessel, and constructed and arranged to provide, exteriorly of said storage and dispensing vessel, a pressure below said interior pressure, to effect desorption of at least a portion of said sorbate gas from the solid-phase physical sorbent medium and yield desorbed gas, and gas flow of said desorbed gas through the dispensing assembly; wherein the solid-phase physical sorbent medium concentration of trace components selected from the group consisting of water, metals, and oxidic transition metal species, based on the weight of the physical sorbent medium, is insufficient to cause decomposition of the sorbate gas resulting in more than a 5% rise in interior pressure after 1 week at 25° C. in said storage and dispensing vessel.

Claim 58

Apparatus according to claim 51, wherein the solid-phase physical sorbent medium contains less than 500 parts-per-million by weight of trace components selected from the group consisting of water and oxidic transition metal species, based on the weight of the physical sorbent medium.

Claim 59

Apparatus according to claim 51, wherein the solid-phase physical sorbent medium contains less than 100 parts-per-million by weight of trace components selected from the group consisting of water and oxidic transition metal species, based on the weight of the physical sorbent medium.

Claim 60

Apparatus according to claim 51, wherein the solid-phase physical sorbent medium contains no more than 1 part-per-million by weight of trace components selected from the group consisting of water and oxidic transition metal species, based on the weight of the physical sorbent medium.

Claim 61

Apparatus according to claim 51, wherein the solid-phase physical sorbent medium concentration of trace components selected from the group consisting of water and oxidic transition metal species, based on the weight of the physical sorbent medium, is insufficient to decompose more than 5% by weight of the sorbate gas after 1 year at 25° C. and said interior pressure, in said storage and dispensing vessel.

Claim 62

Apparatus according to claim 51, wherein the oxidic transition metal species are selected from the group consisting of oxides, sulfates, sulfites and nitrates.

Claim 63

Apparatus according to claim 51, wherein the sorbate gas is a hydride gas.

Claim 64

Apparatus according to claim 51, wherein the sorbate gas is selected from the group consisting of arsine and phosphine.

Claim 65

Apparatus according to claim 51, wherein the sorbate gas is boron trifluoride.

Claim 66

An adsorption-desorption apparatus, for storage and dispensing of boron trifluoride, said apparatus comprising: a storage and dispensing vessel constructed and arranged for holding a solid-phase physical sorbent medium having a sorptive affinity for boron trifluoride, and for selectively flowing boron trifluoride into and out of said vessel; a solid-phase physical sorbent medium having a sorptive affinity for boron trifluoride, disposed in said storage and dispensing vessel at an interior gas pressure; boron trifluoride gas, physically adsorbed on said solid-phase physical sorbent medium; and a dispensing assembly coupled in gas flow communication with the storage and dispensing vessel, and constructed and arranged to provide, exteriorly of said storage and dispensing vessel, a pressure below said interior pressure, to effect desorption of at least a portion of said boron trifluoride gas from the solid-phase physical sorbent medium to yield desorbed boron trifluoride, and gas flow of said desorbed boron trifluoride gas through the dispensing assembly.

Claim 67

An adsorption-desorption apparatus, for storage and dispensing of boron trifluoride, said apparatus comprising: a storage and dispensing vessel constructed and arranged for holding a solid-phase physical sorbent medium having a sorptive affinity for boron trifluoride, and for selectively flowing boron trifluoride into and out of said vessel; a solid-phase physical sorbent medium having a sorptive affinity for boron trifluoride, disposed in said storage and dispensing vessel at an interior gas pressure; boron trifluoride gas, physically adsorbed on said solid-phase physical sorbent medium; and a dispensing assembly coupled in gas flow communication with the storage and dispensing vessel, and constructed and arranged to provide, exteriorly of said storage and dispensing vessel, a pressure below said interior pressure, to effect desorption of at least a portion of said boron trifluoride gas from the solid-phase physical sorbent medium to yield desorbed boron trifluoride, and gas flow of said desorbed boron trifluoride gas through the dispensing assembly.

Claim 68

An ion implantation system, comprising a reagent source for reagent source material and an ion implantation apparatus coupled in gas flow communication with said reagent source, and wherein the reagent source comprises: an adsorption-desorption apparatus, for storage and dispensing of a gas, said apparatus comprising: a storage and dispensing vessel constructed and arranged for holding a solid-phase physical sorbent medium, and for selectively flowing gas into and out of said vessel; a solid-phase physical sorbent medium disposed in said storage and dispensing vessel at an interior gas pressure; a sorbate gas physically adsorbed on said solid-phase physical sorbent medium; and a dispensing assembly interconnecting the storage and dispensing vessel and said ion implantation apparatus in gas flow communication with one another, and constructed and arranged to provide, exteriorly of said storage and dispensing vessel, a pressure below said interior pressure, to effect desorption of at least a portion of said sorbate gas from the solid-phase physical sorbent medium and yield desorbed gas, and gas flow of said desorbed gas through the dispensing assembly to the ion implantation apparatus; wherein the solid-phase physical sorbent medium is devoid of trace components selected from the group consisting of water, metals and oxidic transition metal species in a sufficient concentration to decompose the sorbate gas in said storage and dispensing vessel.

Claim 69

An ion implantation system, comprising a reagent source for reagent source material and an ion implantation apparatus coupled in gas flow communication with said reagent source, and wherein the reagent source comprises: an adsorption-desorption apparatus, for storage and dispensing of a gas, said apparatus comprising: a storage and dispensing vessel constructed and arranged for holding a solid-phase physical sorbent medium, and for selectively flowing gas into and out of said vessel; a solid-phase physical sorbent medium disposed in said storage and dispensing vessel at an interior gas pressure; a sorbate gas physically adsorbed on said solid-phase physical sorbent medium; and a dispensing assembly interconnecting the storage and dispensing vessel and said ion implantation apparatus in gas flow communication with one another, and constructed and arranged to provide, exteriorly of said storage and dispensing vessel, a pressure below said interior pressure, to effect desorption of at least a portion of said sorbate gas from the solid-phase physical sorbent medium and yield desorbed gas, and gas flow of said desorbed gas through the dispensing assembly to the ion implantation apparatus; wherein the solid-phase physical sorbent medium is devoid of trace components selected from the group consisting of water, metals and oxidic transition metal species in a sufficient concentration to decompose the sorbate gas in said storage and dispensing vessel.

Claim 70

An adsorption-desorption apparatus, for storage and dispensing of a gas sorbable on a solid-phase physical sorbent medium, said apparatus comprising: a storage and dispensing vessel constructed and arranged for holding a solid-phase physical sorbent medium, and for selectively flowing gas into and out of said vessel; a solid-phase physical sorbent medium disposed in said storage and dispensing vessel at an interior gas pressure; a sorbate gas physically adsorbed on said solid-phase physical sorbent medium; a dispensing assembly coupled in gas flow communication with the storage and dispensing vessel, and constructed and arranged to provide, exteriorly of said storage and dispensing vessel, a pressure below said interior pressure, to effect desorption of at least a portion of said sorbate gas from the solid-phase physical sorbent medium and yield desorbed gas, and gas flow of said desorbed gas through the dispensing assembly; a cryopump coupled to said dispensing assembly for pressurizing the desorbed gas and discharging the pressurized gas.

Claim 71

An adsorption-desorption apparatus, for storage and dispensing of a gas sorbable on a solid-phase physical sorbent medium, said apparatus comprising: a storage and dispensing vessel constructed and arranged for holding a solid-phase physical sorbent medium, and for selectively flowing gas into and out of said vessel; a solid-phase physical sorbent medium disposed in said storage and dispensing vessel at an interior gas pressure; a sorbate gas physically adsorbed on said solid-phase physical sorbent medium; a dispensing assembly coupled in gas flow communication with the storage and dispensing vessel, and constructed and arranged to provide, exteriorly of said storage and dispensing vessel, a pressure below said interior pressure, to effect desorption of at least a portion of said sorbate gas from the solid-phase physical sorbent medium and yield desorbed gas, and gas flow of said desorbed gas through the dispensing assembly; a cryopump coupled to said dispensing assembly for pressurizing the desorbed gas and discharging the pressurized gas.