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US5512083A Expired / Lapsed US ⏱️ 0.0 years remaining

Process and apparatus for dehumidification and VOC odor remediation

Assignee: Honeywell UOP LLC
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Filing: 1995-01-17
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Granted: 1996-04-30
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Expires: 2015-01-17
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Abstract

Abstract A process and apparatus for the dehumidification and VOC odor remediation of an air stream withdrawn from the passenger compartment of a transportation vehicle is disclosed which employs a continuously rotating wheel support and adsorbent selective for the adsorption of water and VOCs. The wheel is coated with zeolite adsorbent selected from the group consisting of zeolite Y-74, zeolite Y-84, zeolite Y-85, a low cerium rare earth exchanged zeolite Y-84, a rare earth exchanged zeolite LZ-210 and mixtures thereof. A surprisingly significant increase in the thermal efficiency is possible as a result of the lower regeneration temperature of the adsorbent and the use of novel process steps.

Inventors

  • 👤 Stephen R. Dunne

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-28 02:06
CPC Classifications
F; F24; F24F; F24F3/00; F24F3/12; F24F3/14; F24F3/1411; F24F3/1423; B; B01; B01D; B01D53/00; B01D53/02; B01D53/06; B01D53/26; B01D53/261; B60; B60H; B60H3/00; B60H3/02; B60H3/024; B01D2253/00; B01D2253/10; B01D2253/106; B01D2253/108; B01D2253/25; B01D2253/30; B01D2253/302; B01D2253/306; B01D2257/00; B01D2257/70; B01D2257/708; B01D2257/80; B01D2257/90; B01D2259/00; B01D2259/40; B01D2259/40011; B01D2259/40077; B01D2259/40079; B01D2259/40081; B01D2259/40083; B01D2259/40088; B01D2259/4009; B01D2259/45; B01D2259/4566; B01D2259/4575; B60H2003/028; F24F2003/1458; F24F2003/1464; F24F2203/00; F24F2203/10; F24F2203/1032; F24F2203/1036; F24F2203/1048; F24F2203/1056; F24F2203/1068; F24F2203/1088

Claims Analysis

Total Claims: 27
Claim 1
Independent Claim 238 words
A process for dehumidification and VOC odor remediation of a cabin air stream withdrawn from a passenger compartment of a transportation vehicle comprising the following steps: (a) continuously passing the cabin air stream to a first portion of a face area of an adsorbent wheel, said wheel supporting a solid adsorbent selected from the group consisting of zeolite Y-74, zeolite Y-84, zeolite Y-85, a low cerium rare earth exchanged zeolite Y-84, a rare earth exchanged zeolite LZ-210, and mixtures thereof said solid adsorbent being selective for the adsorption of water and VOCs to adsorb water and VOCs at an adsorption temperature and permitting the passage of said cabin air stream therethrough to provide a conditioned air stream; (b) passing at least a portion of said conditioned air stream to a second portion of said adsorbent wheel in a direction countercurrent to the passing of said cabin air stream in step (a) to cool said second portion of said adsorbent wheel and provide an intermediate air stream; (c) heating said intermediate air stream to a regeneration temperature to provide a heated intermediate air stream; (d) passing said heated intermediate stream in a direction cocurrent to said air stream in step (a) to a third portion of said adsorbent wheel to desorb said water and VOCs, forming an exhaust stream, and exhausting said stream; and (e) returning at least a portion of said conditioned air stream to the passenger compartment.
Claim 2
Dependent Claim 238 words
A process for dehumidification and VOC odor remediation of a cabin air stream withdrawn from a passenger compartment of a transportation vehicle comprising the following steps: (a) continuously passing the cabin air stream to a first portion of a face area of an adsorbent wheel, said wheel supporting a solid adsorbent selected from the group consisting of zeolite Y-74, zeolite Y-84, zeolite Y-85, a low cerium rare earth exchanged zeolite Y-84, a rare earth exchanged zeolite LZ-210, and mixtures thereof said solid adsorbent being selective for the adsorption of water and VOCs to adsorb water and VOCs at an adsorption temperature and permitting the passage of said cabin air stream therethrough to provide a conditioned air stream; (b) passing at least a portion of said conditioned air stream to a second portion of said adsorbent wheel in a direction countercurrent to the passing of said cabin air stream in step (a) to cool said second portion of said adsorbent wheel and provide an intermediate air stream; (c) heating said intermediate air stream to a regeneration temperature to provide a heated intermediate air stream; (d) passing said heated intermediate stream in a direction cocurrent to said air stream in step (a) to a third portion of said adsorbent wheel to desorb said water and VOCs, forming an exhaust stream, and exhausting said stream; and (e) returning at least a portion of said conditioned air stream to the passenger compartment.
Claim 3
Dependent Claim 16 words
The process of claim 1 further comprising cooling said conditioned air stream prior to step (e).
Claim 4
Dependent Claim 18 words
The process of claim 1 wherein said adsorption temperature ranges from about -18° C. to about 50° C.
Claim 5
Dependent Claim 18 words
The process of claim 1 wherein said regeneration temperature ranges between about 65° C. and about 80° C.
Claim 6
Dependent Claim 47 words
The process of claim 1 further comprising admixing at least a portion of said cabin air stream with said at least a portion of said conditioned air stream prior to the passing of the at least a portion of said conditioned air stream to said second portion.
Claim 7
Dependent Claim 39 words
The process of claim 1 wherein said second portion of said adsorbent wheel is between said third portion and said first portion whereby said second portion of said adsorbent wheel is returned to the adsorption temperature following step (d).
Claim 8
Dependent Claim 18 words
The process of claim 1 wherein said adsorbent wheel supporting said solid adsorbent comprises an aluminum substrate surface.
Claim 9
Dependent Claim 32 words
The process of claim 1 wherein said second portion of said adsorbent wheel ranges from about 20% to about 60% of the face area of said first portion of said adsorbent wheel.
Claim 10
Dependent Claim 32 words
The process of claim 1 wherein said third portion of said adsorbent wheel ranges from about 20% to about 60% of the face area of said first portion of said adsorbent wheel.
Claim 11
Dependent Claim 186 words
A process for the dehumidification and VOC odor remediation of a cabin air stream withdrawn from a passenger compartment of an automobile comprising the following steps: (a) passing the cabin air stream through a first portion of a continuously rotating adsorbent wheel, said wheel supporting a solid adsorbent selective for the adsorption of water and VOCs, said adsorbent selected from the group consisting of zeolite Y-74, zeolite Y-84, zeolite Y-85, a low cerium rare earth exchanged zeolite Y-84, a rare earth exchanged zeolite LZ-210, and mixtures thereof to provide a conditioned air stream; (b) passing a cooling air stream through a second portion of said wheel to a cool said second portion and to provide an intermediate air stream; (c) heating said intermediate air stream to provide a heated air stream and passing said heated air stream to a third portion of said wheel to desorb said water and VOCs from said adsorbent and provide an exhaust stream; and (d) cooling said conditioned air stream to provide a cooled air stream and returning at least a portion of said cooled air stream to said passenger compartment.
Claim 12
Dependent Claim 186 words
A process for the dehumidification and VOC odor remediation of a cabin air stream withdrawn from a passenger compartment of an automobile comprising the following steps: (a) passing the cabin air stream through a first portion of a continuously rotating adsorbent wheel, said wheel supporting a solid adsorbent selective for the adsorption of water and VOCs, said adsorbent selected from the group consisting of zeolite Y-74, zeolite Y-84, zeolite Y-85, a low cerium rare earth exchanged zeolite Y-84, a rare earth exchanged zeolite LZ-210, and mixtures thereof to provide a conditioned air stream; (b) passing a cooling air stream through a second portion of said wheel to a cool said second portion and to provide an intermediate air stream; (c) heating said intermediate air stream to provide a heated air stream and passing said heated air stream to a third portion of said wheel to desorb said water and VOCs from said adsorbent and provide an exhaust stream; and (d) cooling said conditioned air stream to provide a cooled air stream and returning at least a portion of said cooled air stream to said passenger compartment.
Claim 13
Dependent Claim 18 words
The process of claim 10 wherein said cooled air stream comprises a portion of the conditioned air stream.
Claim 14
Dependent Claim 27 words
The process of claim 11 wherein said cooled air stream is passed through said wheel in a direction which is countercurrent to said cabin air stream passing.
Claim 15
Dependent Claim 25 words
The process of claim 12 wherein said heated air stream is passed through said wheel in a direction which is cocurrent to said stream passing.
Claim 16
Dependent Claim 20 words
The process of claim 10 wherein said cooled air stream comprises at least a portion of said cabin air stream.
Claim 17
Dependent Claim 27 words
The process of claim 14 wherein said heated air stream is passed through said wheel in a direction which is countercurrent to said cabin air stream passing.
Claim 18
Dependent Claim 65 words
A process for dehumidification of an air stream comprising: (a) contacting the air stream with a solid adsorbent selected from the group consisting of zeolite Y-74, zeolite Y-84, low cerium rare earth exchanged zeolite Y-84, zeolite Y-85, rare earth exchanged zeolite LZ-210 and mixtures thereof; and (b) regenerating said solid adsorbent by contacting said solid adsorbent with a heated gas stream at a regeneration temperature.
Claim 19
Dependent Claim 65 words
A process for dehumidification of an air stream comprising: (a) contacting the air stream with a solid adsorbent selected from the group consisting of zeolite Y-74, zeolite Y-84, low cerium rare earth exchanged zeolite Y-84, zeolite Y-85, rare earth exchanged zeolite LZ-210 and mixtures thereof; and (b) regenerating said solid adsorbent by contacting said solid adsorbent with a heated gas stream at a regeneration temperature.
Claim 20
Dependent Claim 15 words
The process of claim 16 wherein the regeneration temperature is less than about 100° C.
Claim 21
Dependent Claim 15 words
The process of claim 16 wherein the regeneration temperature is less than about 80° C.
Claim 22
Dependent Claim 80 words
An improved adsorbent wheel for the dehumidification and VOC odor remediation of an air stream comprising: a substrate surface formed into a rotatable wheel having axially parallel apertures therethrough said substrate surface having a coating of a selective adsorbent for the adsorption of water and VOCs, said selective adsorbent selected from the group consisting of a zeolite Y-74, zeolite Y-84, a zeolite Y-85, a low cerium rare earth exchanged zeolite Y-84, a rare earth exchanged zeolite LZ-210 and mixtures thereof.
Claim 23
Dependent Claim 80 words
An improved adsorbent wheel for the dehumidification and VOC odor remediation of an air stream comprising: a substrate surface formed into a rotatable wheel having axially parallel apertures therethrough said substrate surface having a coating of a selective adsorbent for the adsorption of water and VOCs, said selective adsorbent selected from the group consisting of a zeolite Y-74, zeolite Y-84, a zeolite Y-85, a low cerium rare earth exchanged zeolite Y-84, a rare earth exchanged zeolite LZ-210 and mixtures thereof.
Claim 24
Dependent Claim 28 words
The improved adsorbent wheel of claim 19 wherein said substrate surface is selected from the group consisting of ceramic, glass, plastic, aluminum, steel, aluminized steel, and mixtures thereof.
Claim 25
Dependent Claim 22 words
The improved adsorbent wheel of claim 19 wherein said coating has a thickness ranging from about 0.05 mm to about 0.2 mm.
Claim 26
Dependent Claim 34 words
The improved adsorbent wheel of claim 19 further comprising a plurality of pie-shaped dividers formed in said rotatable wheel and extending axially therethrough separating said axially parallel apertures into a plurality of separated zones.
Claim 27
Dependent Claim 25 words
The improved adsorbent wheel of claim 19 wherein said wheel ranges from about 200 mm (8 inches) to about 610 mm (2 feet) in diameter.

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1999-04-30 1999-10-30 2000-04-30 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 2003-04-30 2003-10-30 2004-04-30 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2007-04-30 2007-10-30 2008-04-30 $7700.00 Window Closed / Lapsed

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