US5158582A
Expired / Lapsed
US
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Method of removing NOx by adsorption, NOx adsorbent and apparatus for purifying NOx-containing gas
Assignee: Kanadevia Corp
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Filing: 1991-04-22
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Granted: 1992-10-27
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Expires: 2011-04-22
Abstract
Abstract The invention provides a method of removing NOx by adsorption wherein a gas containing NOx at a low concentration is brought into contact with an adsorbent comprising a copper salt supported on zeolite serving as a carrier, whereby the NOx is adsorbed and removed efficiently. The adsorbent for use in this method comprises at least one copper salt supported on natural or synthetic zeolite, the copper salt being selected from the group consisting of copper chloride, double salt of copper chloride and ammine complex salt of copper chloride. The apparatus of the invention for purifying an NOx-containing gas comprises an adsorptive dehumidifier for dehumidifying the gas with a dehumidifying agent and regenerating the agent with a purified gas, and an adsorptive denitration unit for denitrating the dehumidified gas. The denitration unit has an adsorbent regenerating zone provided with a channel for recycling an NH3-containing regenerating gas and with a channel for withdrawing a portion of the regenerating gas from the recycling channel, passing the withdrawn gas through a denitration reactor and then releasing the denitrated gas into the atmosphere.
Inventors
- 👤 Shigenori Onitsuka
- 👤 Masayoshi Ichiki
- 👤 Takanobu Watanabe
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-03 02:20
CPC Classifications
B; B01; B01D; B01D53/00; B01D53/34; B01D53/92; B01D53/94; B01D53/9481; B01D53/02; B01D53/06; B01D53/74; B01D53/86; B01D53/8621; B01D53/8625; B01D53/8628; F; F24; F24F; F24F3/00; F24F3/12; F24F3/14; F24F3/1411; F24F3/1423; B01D2253/00; B01D2253/10; B01D2253/106; B01D2253/108; B01D2253/112; B01D2253/25; B01D2253/30; B01D2253/302; B01D2253/304; B01D2257/00; B01D2257/40; B01D2257/404; B01D2259/00; B01D2259/40; B01D2259/40083; B01D2259/40088; B01D2259/4009; F24F2203/00; F24F2203/10; F24F2203/1032; F24F2203/1036; F24F2203/1056; F24F2203/106; F24F2203/1072; F24F2203/1084; F24F2203/1092
Claims Analysis
Total Claims: 16
Claim 1
Independent Claim
75 words
A method of removing NOx from a gas containing NOx at a low concentration, comprising contacting said gas with an adsorbent which comprises at least one copper salt supported on natural or synthetic zeolite, wherein said adsorbent is prepared by immersing said natural of synthetic zeolite in a solution of said copper salt in a solvent and then drying off the solvent so that the copper salt in dried form is supported on the zeolite.
Claim 2
Independent Claim
75 words
A method of removing NOx from a gas containing NOx at a low concentration, comprising contacting said gas with an adsorbent which comprises at least one copper salt supported on natural or synthetic zeolite, wherein said adsorbent is prepared by immersing said natural of synthetic zeolite in a solution of said copper salt in a solvent and then drying off the solvent so that the copper salt in dried form is supported on the zeolite.
Claim 3
Dependent Claim
31 words
A method according to claim 1, wherein said copper salt is selected from the group consisting of copper chloride, double salts of copper chloride, and ammine complex salts of copper chloride.
Claim 4
Dependent Claim
18 words
A method according to claim 1, wherein said copper salt is an ammine complex salt of copper chloride.
Claim 5
Independent Claim
159 words
An apparatus for purifying an NOx-containing gas comprising: (1) an adsorptive dehumidifier for dehumidifying said NOx-containing gas with a dehumidifying agent and regenerating the dehumidifying agent with purified gas produced by said apparatus; (2) an adsorptive denitration unit provided with an NOx adsorbent for denitrating the dehumidified NOx-containing gas; and (3) a denitration reactor; wherein said adsorptive denitration unit comprises an adsorbent regenerating zone wherein the used NOx adsorbent is regenerated with a regenerating gas containing NH 3 , said adsorbent regenerating zone being provided with a gas recycling channel for recycling a portion of said regenerating gas containing NH 3 after its exit from the adsorbent regenerating zone back to the adsorptive denitration unit, and with a gas withdrawing channel for withdrawing another portion of said regenerating gas containing NH 3 from said gas recycling channel, passing the withdrawn gas through said denitration reactor and then releasing the denitrated gas produced by the denitration reactor into the atmosphere.
Claim 6
Independent Claim
159 words
An apparatus for purifying an NOx-containing gas comprising: (1) an adsorptive dehumidifier for dehumidifying said NOx-containing gas with a dehumidifying agent and regenerating the dehumidifying agent with purified gas produced by said apparatus; (2) an adsorptive denitration unit provided with an NOx adsorbent for denitrating the dehumidified NOx-containing gas; and (3) a denitration reactor; wherein said adsorptive denitration unit comprises an adsorbent regenerating zone wherein the used NOx adsorbent is regenerated with a regenerating gas containing NH 3 , said adsorbent regenerating zone being provided with a gas recycling channel for recycling a portion of said regenerating gas containing NH 3 after its exit from the adsorbent regenerating zone back to the adsorptive denitration unit, and with a gas withdrawing channel for withdrawing another portion of said regenerating gas containing NH 3 from said gas recycling channel, passing the withdrawn gas through said denitration reactor and then releasing the denitrated gas produced by the denitration reactor into the atmosphere.
Claim 7
Dependent Claim
40 words
An apparatus as defined in claim 4 wherein each of the adsorptive dehumidifier and the adsorptive denitration unit is a rotary adsorber for continuously moving the dehumidifying agent or NOx adsorbent therein at right angles with the flow of gas.
Claim 8
Dependent Claim
79 words
An apparatus as defined in claim 5 wherein the rotary adsorptive dehumidifier comprises a dehumidifying rotor, and the rotor is an assembly of dehumidifying plates comprising silica gel as a water adsorbent and arranged in layers with a suitable spacer interposed between adjacent plates, an assembly of flat dehumidifying plates and corrugated dehumidifying plates alternately arranged in layers and comprising silica gel as a water adsorbent, or a unitary honeycomb dehumidifying structure comprising silica gel as a water adsorbent.
Claim 9
Dependent Claim
71 words
An apparatus as defined in claim 5 wherein the rotary adsorptive dehumidifier comprises a dehumidifying rotor, and the rotor is provided with an NOx-containing gas channel so that the NOx-containing gas before dehumidification flows locally through the rotor and with a purified gas channel so that the regenerating dry gas flows through the rotor at a portion thereof other than the portion for the NOx-containing gas to flow through before dehumidification.
Claim 10
Dependent Claim
76 words
An apparatus as defined in claim 7 wherein the rotary adsorptive denitration unit comprises an NOx adsorbent rotor, and the adsorbent rotor has the NOx-containing gas channel so that the NOx-containing gas after dehumidification flows locally through the adsorbent rotor and the gas recycling channel so that the NH 3 -containing regenerating recycle gas flows through the adsorbent rotor at a portion thereof other than the portion for the NOx-containing gas to flow through after dehumidification.
Claim 11
Dependent Claim
99 words
An apparatus as defined in claim 5 wherein the rotary adsorptive denitration unit comprises an NOx adsorbent rotor, and the rotor is an assembly of plates of an adsorbent comprising a copper salt supported on a zeolite carrier and arranged in layers with a suitable spacer interposed between the adjacent plates, an assembly of flat adsorbent plates and corrugated adsorbent plates arranged alternately in layers and made of an adsorbent comprising a copper salt supported on a zeolite carrier, or an adsorbent comprising a copper salt supported on a zeolite carrier in the form of a unitary honeycomb structure.
Claim 12
Dependent Claim
71 words
An agent for removing NOx by adsorption from a gas containing NOx at a low concentration, said agent comprising at least one copper salt supported on natural or synthetic zeolite, wherein said agent is prepared by immersing said natural or synthetic zeolite in a solution of said copper salt in a solvent and then drying off the solvent so that the copper salt in dried form is supported on the zeolite.
Claim 13
Dependent Claim
71 words
An agent for removing NOx by adsorption from a gas containing NOx at a low concentration, said agent comprising at least one copper salt supported on natural or synthetic zeolite, wherein said agent is prepared by immersing said natural or synthetic zeolite in a solution of said copper salt in a solvent and then drying off the solvent so that the copper salt in dried form is supported on the zeolite.
Claim 14
Dependent Claim
31 words
An agent according to claim 10, wherein said copper salt is selected from the group consisting of copper chloride, double salts of copper chloride, and ammine complex salts of copper chloride.
Claim 15
Dependent Claim
18 words
An agent according to claim 10, wherein said copper salt is an ammine complex salt of copper chloride.
Claim 16
Dependent Claim
35 words
An agent according to claim 10, wherein the amount of said copper salt supported on the zeolite is 0.1 to 20% by weight, calculated as copper metal and based on the weight of the agent.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1995-10-27 | 1996-04-27 | 1996-10-27 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1999-10-27 | 2000-04-27 | 2000-10-27 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 2003-10-27 | 2004-04-27 | 2004-10-27 | $7700.00 | Window Closed / Lapsed |