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US4019879A Expired / Lapsed US ⏱️ 0.0 years remaining

Selective adsorption of carbon monoxide from gas streams

Assignee: Union Carbide Corp
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Filing: 1975-09-26
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Granted: 1977-04-26
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Expires: 1995-09-26
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Abstract

Abstract Zeolitic molecular sieves having high SiO 2 /Al 2 O 3 molar ratios and containing Cu + cations are found to exhibit a high degree of selectivity and affinity for CO molecules and are capable of separating CO from gas streams even when water vapor is present.

Inventors

  • 👤 Jule Anthony Rabo
  • 👤 James Nelson Francis
  • 👤 Charles Leslie Angell

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-23 20:44
CPC Classifications
B; B01; B01D; B01D53/00; B01D53/02; B01J; B01J20/00; B01J20/02; B01J20/10; B01J20/16; B01J20/18; B01J20/186; C; C01; C01B; C01B32/00; C01B32/40; Y; Y10; Y10S; Y10S95/00; Y10S95/90; Y10S95/902

Claims Analysis

Total Claims: 7
Claim 1
Independent Claim 98 words
Process for removing carbon monoxide from a gas stream comprising at least 10 ppm CO by volume and at least one other constituent selected from the group consisting of H 2 O and CO 2 which process comprises passing said gas stream at a temperature of from 0 to 300° C. through an adsorbent mass of a crystalline zeolitic molecular sieve having a framework SiO 2 /Al 2 O 3 molar ratio of from 20 to 200 and having as zeolite constituents monovalent copper cations, whereby CO molecules are adsorbed and a CO-depleted effluent gas stream is obtained.
Claim 2
Dependent Claim 98 words
Process for removing carbon monoxide from a gas stream comprising at least 10 ppm CO by volume and at least one other constituent selected from the group consisting of H 2 O and CO 2 which process comprises passing said gas stream at a temperature of from 0 to 300° C. through an adsorbent mass of a crystalline zeolitic molecular sieve having a framework SiO 2 /Al 2 O 3 molar ratio of from 20 to 200 and having as zeolite constituents monovalent copper cations, whereby CO molecules are adsorbed and a CO-depleted effluent gas stream is obtained.
Claim 3
Dependent Claim 21 words
Process according to claim 1 wherein the framework SiO 2 /Al 2 O 3 molar ratio is from 20 to 100.
Claim 4
Dependent Claim 17 words
Process according to claim 2 wherein the CO-containing gas stream comprises at least 5 volume percent CO.
Claim 5
Dependent Claim 19 words
Process according to claim 3 wherein the gas stream comprises CO, water vapor, CO 2 and N 2 .
Claim 6
Dependent Claim 19 words
Process according to claim 3 wherein the gas stream consists essentially of CO, CO 2 and H 2 .
Claim 7
Dependent Claim 18 words
Process according to claim 3 wherein the gas stream is the vent gas stream from a blast furnace.

References Cited (Backward Citations)

US2254799A Cited
DE2130983A1 Cited
US3849340A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1980-04-25 1980-10-25 1981-04-26 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1984-04-25 1984-10-25 1985-04-26 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1988-04-25 1988-10-25 1989-04-26 $7700.00 Window Closed / Lapsed

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