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US5459002A Expired / Lapsed US ⏱️ 0.0 years remaining

Photomask blanks

Assignee: DU PONT CHEMICAL AND ENERGY OPERATIONS Inc
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Filing: 1994-03-28
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Granted: 1995-10-17
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Expires: 2014-03-28
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Abstract

Abstract Transmissive embedded phase shifter-photomask blanks are disclosed which comprise an optically inhomogeneous attenuating film which has a transmission of at least 0.001 and consists essentially of a combination of a metallic component and a dielectric component. One surface of the film has a higher content of metallic component than the other surface and the profile of change in extinction coefficient is gradual through the film thickness. The profile of change in extinction coefficient and the film thickness are selected to provide a phase shift of about 180 DEG (or an odd multiple thereof) at a selected wavelength.

Inventors

  • 👤 Hakki U. Alpay
  • 👤 Roger H. French
  • 👤 Franklin D. Kalk

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-08 11:32
CPC Classifications
G; G03; G03F; G03F1/00; G03F1/26; G03F1/32; G03F1/54

Claims Analysis

Total Claims: 9
Claim 1
Independent Claim 99 words
A transmissive embedded phase shifter-photomask blank for a selected wavelength comprising an optically inhomogeneous attenuating film having a transmission of at least 0.001 and consisting essentially of a combination of a metallic component and a dielectric component; wherein one surface of the film has a higher content of metallic component than the other surface, and the profile of change in the extinction coefficient is gradual through the film thickness; and wherein said profile of change and the film thickness are selected to provide a phase shift of about 180° , or an odd multiple thereof, at the selected wavelength.
Claim 2
Dependent Claim 99 words
A transmissive embedded phase shifter-photomask blank for a selected wavelength comprising an optically inhomogeneous attenuating film having a transmission of at least 0.001 and consisting essentially of a combination of a metallic component and a dielectric component; wherein one surface of the film has a higher content of metallic component than the other surface, and the profile of change in the extinction coefficient is gradual through the film thickness; and wherein said profile of change and the film thickness are selected to provide a phase shift of about 180° , or an odd multiple thereof, at the selected wavelength.
Claim 3
Dependent Claim 17 words
The transmissive embedded phase shifter-photomask blank of claim 1 wherein the phase shift is about 180° .
Claim 4
Dependent Claim 21 words
The transmissive embedded phase shifter-photomask blank of claim 2 wherein the reflectivity is within the range of from 0 to 0.5.
Claim 5
Dependent Claim 38 words
The transmissive embedded phase shifter-photomask blank of claim 3 wherein the metallic component is from 85% to 5% of the film by volume and wherein the dielectric component is from 15% to 95% of the film by volume.
Claim 6
Dependent Claim 27 words
The transmissive embedded phase shifter-photomask blank of claim 1, claim 2, claim 3, or claim 4 wherein the selected wavelength is from 110 nm to 1000 nm.
Claim 7
Dependent Claim 48 words
The transmissive embedded phase shifter-photomask blank of claim 5 wherein the metallic component and dielectric component are M--O--C--N materials, M--Cl--O--C--N materials, M--Cl--F--O--C--N materials or M--F--O--C--N materials where M is selected from the group consisting of Cr, Fe, Mo, Zn, Co, Nb, Ta, W, Ti, Al, Mg, and Si.
Claim 8
Dependent Claim 13 words
The transmissive embedded phase shifter-photomask blank of claim 6 wherein M is Cr.
Claim 9
Dependent Claim 19 words
The transmissive embedded phase shifter-photomask blank of claim 7 wherein the metallic component and dielectric component are Cr-0-C--N materials.

References Cited (Backward Citations)

US4415262A Cited
EP0203563A2 Cited
US4890309A Cited
JPH02242252A Cited
JPH04125643A Cited
US5230971A Cited
US5187726A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1998-10-16 1999-04-17 1999-10-17 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 2002-10-16 2003-04-17 2003-10-17 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2006-10-16 2007-04-17 2007-10-17 $7700.00 Window Closed / Lapsed

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