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Process for the preparation of an olefin polymer using metallocenes containing specifically substituted indenyl ligands

Assignee: Targor GmbH
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Filing: 1993-08-03
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Granted: 1995-10-03
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Expires: 2013-08-03
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Abstract

Abstract Process for the preparation of an olefin polymer using metallocenes containing specifically substituted indenyl ligands A highly effective catalyst system for the polymerization of olefins comprises a cocatalyst, preferably an aluminoxane, and a metallocene of the formula I ##STR1## in which, preferably M 1 is Zr or Hf, R 1 and R 2 are alkyl or halogen, R 5 is hydrogen or alkyl, R 3 and R 4 are alkyl, where R 3 , R 4 and R 5 may be halogenated, --(CR 7 R 8 ) m --R 6 --(CR 7 R 8 ) n -- is a single- or multi-membered chain in which R 6 may also be a (substituted) heteroatom, and m+n is zero or 1.

Inventors

  • 👤 Andreas Winter
  • 👤 Frank Kueber
  • 👤 Walter Spaleck
  • 👤 Herbert Riepl
  • 👤 Wolfgang A. Herrmann
  • 👤 Volker Dolle
  • 👤 Juergen Rohrmann

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-02 20:55
CPC Classifications
C; C07; C07F; C07F17/00; C08; C08F; C08F10/00; C08F4/00; C08F4/42; C08F4/44; C08F4/60; C08F4/62; C08F4/639; C08F4/63912; C08F4/6392; C08F4/63922; C08F4/63927

Claims Analysis

Total Claims: 8
Claim 1
Independent Claim 365 words
A compound of the formula I ##STR9## in which M 1 is a metal from group IVb, Vb or VIb of the Periodic Table, R 1 and R 2 are identical or different and are a hydrogen atom, a C 1 -C 10 -alkyl group, a C 1 -C 10 -alkoxy group, a C 6 -C 10 -aryl group, a C 6 -C 10 -aryloxy group, a C 2 -C 10 -alkenyl group, a C 7 -C 40 -arylalkyl group, a C 7 -C 40 -alkylaryl group, a C 8 -C 40 -arylalkenyl group or a halogen atom, R 3 , R 4 and R 5 are identical or different and R 3 and R 4 and/or R 5 are other than hydrogen and are a C 1 -C 20 -alkyl group, a C 6 -C 20 -aryl group, a C 2 -C 10 -alkenyl group, a C 7 -C 40 -arylalkyl group, a C 7 -C 40 -alkylaryl group or a C 8 -C 40 -arylalkenyl group, these radicals optionally being halogenated, R 5 may alternatively be hydrogen, R 6 is ##STR10## ═BR 9 , ═AlR 9 , --Ge--, --Sn--, --O--, --S--, ═SO , ═SO 2 , ═NR 9 , ═CO, ═PR 9 or ═P(O)R 9 , where R 9 , R 10 and R 11 are identical or different and are a hydrogen atom, a halogen atom, a C 1 -C 10 -alkyl group, a C 1 -C 10 -fluoroalkyl group, a C 6 -C 10 -aryl group, a C 6 -C 10 -fluoroaryl group, a C 1 -C 10 -alkoxy group, a C 2 -C 10 -alkenyl group, a C 7 -C 40 -arylalkyl group, a C 8 -C 40 -arylalkenyl group or a C 7 -C 40 -alkylaryl group, or R 9 and R 10 or R 9 and R 11 , in each case together with the atoms connecting them, form a ring, M 2 is silicon, germanium or tin, R 7 and R 8 are identical or different and are as defined for R 9 , and m and n are identical or different and are zero, 1 or 2, where m plus n is zero, 1 or 2.
Claim 2
Dependent Claim 365 words
A compound of the formula I ##STR9## in which M 1 is a metal from group IVb, Vb or VIb of the Periodic Table, R 1 and R 2 are identical or different and are a hydrogen atom, a C 1 -C 10 -alkyl group, a C 1 -C 10 -alkoxy group, a C 6 -C 10 -aryl group, a C 6 -C 10 -aryloxy group, a C 2 -C 10 -alkenyl group, a C 7 -C 40 -arylalkyl group, a C 7 -C 40 -alkylaryl group, a C 8 -C 40 -arylalkenyl group or a halogen atom, R 3 , R 4 and R 5 are identical or different and R 3 and R 4 and/or R 5 are other than hydrogen and are a C 1 -C 20 -alkyl group, a C 6 -C 20 -aryl group, a C 2 -C 10 -alkenyl group, a C 7 -C 40 -arylalkyl group, a C 7 -C 40 -alkylaryl group or a C 8 -C 40 -arylalkenyl group, these radicals optionally being halogenated, R 5 may alternatively be hydrogen, R 6 is ##STR10## ═BR 9 , ═AlR 9 , --Ge--, --Sn--, --O--, --S--, ═SO , ═SO 2 , ═NR 9 , ═CO, ═PR 9 or ═P(O)R 9 , where R 9 , R 10 and R 11 are identical or different and are a hydrogen atom, a halogen atom, a C 1 -C 10 -alkyl group, a C 1 -C 10 -fluoroalkyl group, a C 6 -C 10 -aryl group, a C 6 -C 10 -fluoroaryl group, a C 1 -C 10 -alkoxy group, a C 2 -C 10 -alkenyl group, a C 7 -C 40 -arylalkyl group, a C 8 -C 40 -arylalkenyl group or a C 7 -C 40 -alkylaryl group, or R 9 and R 10 or R 9 and R 11 , in each case together with the atoms connecting them, form a ring, M 2 is silicon, germanium or tin, R 7 and R 8 are identical or different and are as defined for R 9 , and m and n are identical or different and are zero, 1 or 2, where m plus n is zero, 1 or 2.
Claim 3
Dependent Claim 100 words
A compound as claimed in claim 1, wherein, in the formula I, M 1 is Zr or Hf, R 1 and R 2 are identical or different and are (C 1 -C 3 )-alkyl or chlorine, R 3 and R 4 are identical or different and are (C 1 -C 10 )-alkyl, which is optionally halogenated, R 5 is hydrogen or (C 1 -C 10 )-alkyl, which is optionally halogenated, R 6 is a ##STR11## radical, and R 9 and R 10 are identical or different and are (C 1 -C 10 )-alkyl or (C 6 -C 10 ) -aryl.
Claim 4
Dependent Claim 12 words
A compound as claimed in claim 1, wherein R 5 is hydrogen.
Claim 5
Dependent Claim 12 words
A compound as claimed in claim 2, wherein R 5 is hydrogen.
Claim 6
Dependent Claim 194 words
A compound of the formula I ##STR12## in which M 1 is a metal from group IVb of the Periodic Table, R 1 and R 2 are identical or different and are a hydrogen atom, a C 1 -C 10 -alkyl group, a C 1 -C 10 -alkoxy group, a C 6 -C 10 -aryl group, a C 6 -C 10 -aryloxy group, a C 2 -C 10 -alkenyl group, a C 7 -C 40 -arylalkyl group, a C 7 -C 40 -alkylaryl group, a C 8 -C 40 -arylalkenyl group or a halogen atom, R 3 and R 4 are identical or different and are C 1 -C 10 -alkyl, which is optionally halogenated, is hydrogen, C 6 -C 10 -aryl or C 1 -C 10 -alkyl, which is optionally halogenated, R 9 and R 10 are identical or different and are C 1 -C 10 -alkyl or C 6 -C 10 -aryl, R 7 and R 8 are identical or different and are as defined for R 9 , and m and n are identical or different and are zero, 1 or 2, where m plus n is zero, 1 or 2.
Claim 7
Dependent Claim 194 words
A compound of the formula I ##STR12## in which M 1 is a metal from group IVb of the Periodic Table, R 1 and R 2 are identical or different and are a hydrogen atom, a C 1 -C 10 -alkyl group, a C 1 -C 10 -alkoxy group, a C 6 -C 10 -aryl group, a C 6 -C 10 -aryloxy group, a C 2 -C 10 -alkenyl group, a C 7 -C 40 -arylalkyl group, a C 7 -C 40 -alkylaryl group, a C 8 -C 40 -arylalkenyl group or a halogen atom, R 3 and R 4 are identical or different and are C 1 -C 10 -alkyl, which is optionally halogenated, is hydrogen, C 6 -C 10 -aryl or C 1 -C 10 -alkyl, which is optionally halogenated, R 9 and R 10 are identical or different and are C 1 -C 10 -alkyl or C 6 -C 10 -aryl, R 7 and R 8 are identical or different and are as defined for R 9 , and m and n are identical or different and are zero, 1 or 2, where m plus n is zero, 1 or 2.
Claim 8
Dependent Claim 12 words
A compound as claimed in claim 5, wherein R 5 is hydrogen.

References Cited (Backward Citations)

EP0320762B1 Cited
US5120867A Cited
US5004820A Cited
US5145819A Cited
US5329033A Cited
EP0530908A1 Cited
US5329031A Cited
US5374752A Cited

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