Patent US3939665A successfully refreshed from Google Patents.
US5374752A
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Process for the preparation of a high molecular weight olefin polymer
Assignee: Targor GmbH
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Filing: 1994-04-25
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Granted: 1994-12-20
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Expires: 2014-04-25
Abstract
Abstract A very active catalyst system for olefin polymerization comprises a cocatalyst, preferably an aluminoxane, and a metallocene of the formula I ##STR1## in which, preferably, M 1 is Zr or Hf, R 1 and R 2 are alkyl or halogen, R 3 is hydrogen, R 4 to R 6 and alkyl or aryl, --(CR 8 R 9 ) m --R 7 --(CR 8 R 9 ) n is a single- or multi-membered chain, in which R' can also be a (substituted) hetero atom, and m+n is zero or 1.
Inventors
- 👤 Andreas Winter
- 👤 Jurgen Rohrmann
- 👤 Volker Dolle
- 👤 Frank Kuber
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-30 07:20
CPC Classifications
C; C08; C08F; C08F10/00; C08F10/04; C08F10/06; C07; C07C; C07C13/00; C07C13/28; C07C13/32; C07C13/45; C07C13/465; C07C45/00; C07C45/45; C07C45/46; C07C45/61; C07C45/67; C07F; C07F17/00; C07C2602/00; C07C2602/02; C07C2602/04; C07C2602/08; C08F110/00; C08F110/04; C08F110/06; C08F210/00; C08F210/04; C08F210/06; C08F4/00; C08F4/42; C08F4/44; C08F4/60; C08F4/62; C08F4/639; C08F4/63912; C08F4/6392; C08F4/63922; C08F4/63927; C08F4/64; C08F4/659; C08F4/65908; Y; Y10; Y10S; Y10S526/00; Y10S526/943
Claims Analysis
Total Claims: 6
Claim 1
Independent Claim
379 words
A metallocene compound of the formula I ##STR13## in which M 1 is a metal of group IVb, Vb or VIB of the periodic table, R 1 and R 2 are identical or different and are a hydrogen atom, A c 1 -C 10 -alkyl group, a C 1 -C 10 -alkoxy group, aC 6 -C 10 -aryl group, a C 6 -C 10 aryloxy group, a C 2 -C 10 -alkenyl group, a C 7 -C 40 -arlalukd group, a C 7 -C 40 -alkylarly group, a C 8 -C 40 -arylakenyl group or a halogen atom, the radicals R 3 are identical or different and are a hydrogen atom, a halogen atom, A c 1 -C 10 -alkyl group, which can be hydrogenated a C 6 -C 10 -aryl group, which can be halogenaed, or a --NR 2 10 --SR 10 --OSiR 3 10 , --SiR 3 10 or --PR 2 10 radical, in which R 10 is a halogen atom, a C 1 `r a C 6 -C 10 -aryl group, R 4 to R 6 are identical or different and have the meaning gien for R 3 , with the proviso that R 4 and R 6 are not hydrogen, R 7 is ##STR14## ═BR 11 , ═AlR 11 , --Ge--, --Sn--, --O--, --S--, ═SP, ═SO 2 ═NR 11 , ═COm ═PR 11 or ═P(O)R 11 in which R 11 , R 12 and R 13 ar identical or different and are a hydrogen atom, a halogen atom, a C 1 -C 10 -alkyl group, a C 1 -C 10 -fluoroalkyl group, a C 6 -C 10 -aryl grip, a C 6 -C 10 -fluoroaly group, a C 1 -C 10 -alkoxy group, a C 2 -C 10 -akenyl group, a C 7 -C 40 -arylalkyl group, a C 8 -C 4 alkylarly group, or R 11 and R 12 , or R 11 and R 13 , in each case with the atoms joining them, form a ring, M 2 is silicon, germanium or tin, R 8 and R 9 are identical or different and have the meaning given for R 11 and m and n are identical or different and are zero, 1 or 2, m plus n being zero, 1 or 2.
Claim 2
Dependent Claim
379 words
A metallocene compound of the formula I ##STR13## in which M 1 is a metal of group IVb, Vb or VIB of the periodic table, R 1 and R 2 are identical or different and are a hydrogen atom, A c 1 -C 10 -alkyl group, a C 1 -C 10 -alkoxy group, aC 6 -C 10 -aryl group, a C 6 -C 10 aryloxy group, a C 2 -C 10 -alkenyl group, a C 7 -C 40 -arlalukd group, a C 7 -C 40 -alkylarly group, a C 8 -C 40 -arylakenyl group or a halogen atom, the radicals R 3 are identical or different and are a hydrogen atom, a halogen atom, A c 1 -C 10 -alkyl group, which can be hydrogenated a C 6 -C 10 -aryl group, which can be halogenaed, or a --NR 2 10 --SR 10 --OSiR 3 10 , --SiR 3 10 or --PR 2 10 radical, in which R 10 is a halogen atom, a C 1 `r a C 6 -C 10 -aryl group, R 4 to R 6 are identical or different and have the meaning gien for R 3 , with the proviso that R 4 and R 6 are not hydrogen, R 7 is ##STR14## ═BR 11 , ═AlR 11 , --Ge--, --Sn--, --O--, --S--, ═SP, ═SO 2 ═NR 11 , ═COm ═PR 11 or ═P(O)R 11 in which R 11 , R 12 and R 13 ar identical or different and are a hydrogen atom, a halogen atom, a C 1 -C 10 -alkyl group, a C 1 -C 10 -fluoroalkyl group, a C 6 -C 10 -aryl grip, a C 6 -C 10 -fluoroaly group, a C 1 -C 10 -alkoxy group, a C 2 -C 10 -akenyl group, a C 7 -C 40 -arylalkyl group, a C 8 -C 4 alkylarly group, or R 11 and R 12 , or R 11 and R 13 , in each case with the atoms joining them, form a ring, M 2 is silicon, germanium or tin, R 8 and R 9 are identical or different and have the meaning given for R 11 and m and n are identical or different and are zero, 1 or 2, m plus n being zero, 1 or 2.
Claim 3
Dependent Claim
16 words
A metallocene compound as claimed in claim 1, wherein, in formula I, R 3 is hydrogen.
Claim 4
Dependent Claim
71 words
A metallocene compound as claimed in claim 1, wherein in formula I, M 1 is Zr or Hf, R 1 and R 2 are identical or different and are methyl or chlorine, R 4 and R 6 are identical or different and are methyl, isopropyl, phenyl, ethyl or trifluoromethyl, R 5 is hydrogen or has the meanings given for R 4 and R 6 , R 7 is a radical ##STR15##
Claim 5
Dependent Claim
4 words
Rac-dimethylsilyl(2-methyl-4,6-diisopropyl-1-idenyl 2 zirconium dichloride.
Claim 6
Dependent Claim
4 words
Rac-dimethylsilyl(2-methyl-4,6-diisopropyl-1-idenyl 2 zirconium dichloride.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1997-12-19 | 1998-06-20 | 1998-12-20 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 2001-12-19 | 2002-06-20 | 2002-12-20 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 2005-12-19 | 2006-06-20 | 2006-12-20 | $7700.00 | Window Closed / Lapsed |