Patent US5374752A successfully refreshed from Google Patents.
← Back to Patent Explorer
US5374752A Expired / Lapsed US ⏱️ 0.0 years remaining

Process for the preparation of a high molecular weight olefin polymer

Assignee: Targor GmbH
•
Filing: 1994-04-25
•
Granted: 1994-12-20
•
Expires: 2014-04-25
📄 Original PDF 🌐 Google Patents 🔄 Sync Now

Abstract

Abstract A very active catalyst system for olefin polymerization comprises a cocatalyst, preferably an aluminoxane, and a metallocene of the formula I ##STR1## in which, preferably, M 1 is Zr or Hf, R 1 and R 2 are alkyl or halogen, R 3 is hydrogen, R 4 to R 6 and alkyl or aryl, --(CR 8 R 9 ) m --R 7 --(CR 8 R 9 ) n is a single- or multi-membered chain, in which R' can also be a (substituted) hetero atom, and m+n is zero or 1.

Inventors

  • 👤 Andreas Winter
  • 👤 Jurgen Rohrmann
  • 👤 Volker Dolle
  • 👤 Frank Kuber

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-30 14:09
CPC Classifications
C; C08; C08F; C08F10/00; C08F10/04; C08F10/06; C07; C07C; C07C13/00; C07C13/28; C07C13/32; C07C13/45; C07C13/465; C07C45/00; C07C45/45; C07C45/46; C07C45/61; C07C45/67; C07F; C07F17/00; C07C2602/00; C07C2602/02; C07C2602/04; C07C2602/08; C08F110/00; C08F110/04; C08F110/06; C08F210/00; C08F210/04; C08F210/06; C08F4/00; C08F4/42; C08F4/44; C08F4/60; C08F4/62; C08F4/639; C08F4/63912; C08F4/6392; C08F4/63922; C08F4/63927; C08F4/64; C08F4/659; C08F4/65908; Y; Y10; Y10S; Y10S526/00; Y10S526/943

Claims Analysis

Total Claims: 6
Claim 1
Independent Claim 379 words
A metallocene compound of the formula I ##STR13## in which M 1 is a metal of group IVb, Vb or VIB of the periodic table, R 1 and R 2 are identical or different and are a hydrogen atom, A c 1 -C 10 -alkyl group, a C 1 -C 10 -alkoxy group, aC 6 -C 10 -aryl group, a C 6 -C 10 aryloxy group, a C 2 -C 10 -alkenyl group, a C 7 -C 40 -arlalukd group, a C 7 -C 40 -alkylarly group, a C 8 -C 40 -arylakenyl group or a halogen atom, the radicals R 3 are identical or different and are a hydrogen atom, a halogen atom, A c 1 -C 10 -alkyl group, which can be hydrogenated a C 6 -C 10 -aryl group, which can be halogenaed, or a --NR 2 10 --SR 10 --OSiR 3 10 , --SiR 3 10 or --PR 2 10 radical, in which R 10 is a halogen atom, a C 1 `r a C 6 -C 10 -aryl group, R 4 to R 6 are identical or different and have the meaning gien for R 3 , with the proviso that R 4 and R 6 are not hydrogen, R 7 is ##STR14## ═BR 11 , ═AlR 11 , --Ge--, --Sn--, --O--, --S--, ═SP, ═SO 2 ═NR 11 , ═COm ═PR 11 or ═P(O)R 11 in which R 11 , R 12 and R 13 ar identical or different and are a hydrogen atom, a halogen atom, a C 1 -C 10 -alkyl group, a C 1 -C 10 -fluoroalkyl group, a C 6 -C 10 -aryl grip, a C 6 -C 10 -fluoroaly group, a C 1 -C 10 -alkoxy group, a C 2 -C 10 -akenyl group, a C 7 -C 40 -arylalkyl group, a C 8 -C 4 alkylarly group, or R 11 and R 12 , or R 11 and R 13 , in each case with the atoms joining them, form a ring, M 2 is silicon, germanium or tin, R 8 and R 9 are identical or different and have the meaning given for R 11 and m and n are identical or different and are zero, 1 or 2, m plus n being zero, 1 or 2.
Claim 2
Dependent Claim 379 words
A metallocene compound of the formula I ##STR13## in which M 1 is a metal of group IVb, Vb or VIB of the periodic table, R 1 and R 2 are identical or different and are a hydrogen atom, A c 1 -C 10 -alkyl group, a C 1 -C 10 -alkoxy group, aC 6 -C 10 -aryl group, a C 6 -C 10 aryloxy group, a C 2 -C 10 -alkenyl group, a C 7 -C 40 -arlalukd group, a C 7 -C 40 -alkylarly group, a C 8 -C 40 -arylakenyl group or a halogen atom, the radicals R 3 are identical or different and are a hydrogen atom, a halogen atom, A c 1 -C 10 -alkyl group, which can be hydrogenated a C 6 -C 10 -aryl group, which can be halogenaed, or a --NR 2 10 --SR 10 --OSiR 3 10 , --SiR 3 10 or --PR 2 10 radical, in which R 10 is a halogen atom, a C 1 `r a C 6 -C 10 -aryl group, R 4 to R 6 are identical or different and have the meaning gien for R 3 , with the proviso that R 4 and R 6 are not hydrogen, R 7 is ##STR14## ═BR 11 , ═AlR 11 , --Ge--, --Sn--, --O--, --S--, ═SP, ═SO 2 ═NR 11 , ═COm ═PR 11 or ═P(O)R 11 in which R 11 , R 12 and R 13 ar identical or different and are a hydrogen atom, a halogen atom, a C 1 -C 10 -alkyl group, a C 1 -C 10 -fluoroalkyl group, a C 6 -C 10 -aryl grip, a C 6 -C 10 -fluoroaly group, a C 1 -C 10 -alkoxy group, a C 2 -C 10 -akenyl group, a C 7 -C 40 -arylalkyl group, a C 8 -C 4 alkylarly group, or R 11 and R 12 , or R 11 and R 13 , in each case with the atoms joining them, form a ring, M 2 is silicon, germanium or tin, R 8 and R 9 are identical or different and have the meaning given for R 11 and m and n are identical or different and are zero, 1 or 2, m plus n being zero, 1 or 2.
Claim 3
Dependent Claim 16 words
A metallocene compound as claimed in claim 1, wherein, in formula I, R 3 is hydrogen.
Claim 4
Dependent Claim 71 words
A metallocene compound as claimed in claim 1, wherein in formula I, M 1 is Zr or Hf, R 1 and R 2 are identical or different and are methyl or chlorine, R 4 and R 6 are identical or different and are methyl, isopropyl, phenyl, ethyl or trifluoromethyl, R 5 is hydrogen or has the meanings given for R 4 and R 6 , R 7 is a radical ##STR15##
Claim 5
Dependent Claim 4 words
Rac-dimethylsilyl(2-methyl-4,6-diisopropyl-1-idenyl 2 zirconium dichloride.
Claim 6
Dependent Claim 4 words
Rac-dimethylsilyl(2-methyl-4,6-diisopropyl-1-idenyl 2 zirconium dichloride.

References Cited (Backward Citations)

DE3726067A1 Cited
EP0336128B1 Cited
US5017714A Cited
DE3826075A1 Cited
EP0363029A2 Cited
US5132262A Cited
US5243001A Cited
US5296434A Cited
US5278264A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1997-12-19 1998-06-20 1998-12-20 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 2001-12-19 2002-06-20 2002-12-20 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2005-12-19 2006-06-20 2006-12-20 $7700.00 Window Closed / Lapsed

Assigned Categories & Tags

No categories assigned to this patent yet.

Assign Category Tag