US5434878A — Optical gain medium having doped nanocrystals of …

Claim 1

Independent Claim 76 words

A structure that exhibits laser-like activity when excited by a source of excitation energy, the structure comprising in combination: a matrix phase that is substantially transparent at wavelengths of interest; a doped semiconductor nanocrystal electromagnetic radiation emitting and amplifying phase; and a high index of refraction contrast electromagnetic radiation scattering phase, wherein said matrix phase, said electromagnetic radiation emitting and amplifying phase, and said electromagnetic radiation scattering phase are commingled within a volume of said structure.

Claim 2

Dependent Claim 76 words

A structure that exhibits laser-like activity when excited by a source of excitation energy, the structure comprising in combination: a matrix phase that is substantially transparent at wavelengths of interest; a doped semiconductor nanocrystal electromagnetic radiation emitting and amplifying phase; and a high index of refraction contrast electromagnetic radiation scattering phase, wherein said matrix phase, said electromagnetic radiation emitting and amplifying phase, and said electromagnetic radiation scattering phase are commingled within a volume of said structure.

Claim 3

Dependent Claim 33 words

A structure as set forth in claim 1, wherein at least one dimension of said structure is less than or on the order of a scattering length associated with the radiation scattering phase.

Claim 4

Dependent Claim 31 words

A structure as set forth in claim 1 wherein said doped semiconductor nanocrystal electromagnetic radiation emitting and amplifying phase is comprised of semiconductor particles that are doped with a luminescent center.

Claim 5

Dependent Claim 31 words

A structure as set forth in claim 1 wherein said doped semiconductor nanocrystal electromagnetic radiation emitting and amplifying phase is comprised of ZnS particles that are doped with Mn 2+ .

Claim 6

Dependent Claim 26 words

A structure as set forth in claim 1 wherein said high index of refraction contrast electromagnetic radiation scattering phase is comprised of particles of an oxide.

Claim 7

Dependent Claim 25 words

A structure as set forth in claim 1 wherein said high index of refraction contrast electromagnetic radiation scattering phase is comprised of TiO 2 .

Claim 8

Dependent Claim 27 words

A structure as set forth in claim 1 wherein said high index of refraction contrast electromagnetic radiation scattering phase is comprised of Al 2 O 3 .

Claim 9

Dependent Claim 28 words

A structure as set forth in claim 1 wherein said high index of refraction contrast electromagnetic radiation scattering phase is comprised of scattering centers within said matrix phase.

Claim 10

Dependent Claim 29 words

A structure as set forth in claim 1 wherein said matrix phase is comprised of a material selected from the group consisting essentially of a glass and a polymer.

Claim 11

Dependent Claim 18 words

A structure as set forth in claim 1, wherein said structure has the form of a monolithic body.

Claim 12

Dependent Claim 24 words

A structure as set forth in claim 1, wherein said structure has the form of a layer that overlies a surface of a substrate.

Claim 13

Dependent Claim 26 words

A structure as set forth in claim 1, wherein said structure has the form of a region that is formed within a surface of a substrate.

Claim 14

Independent Claim 86 words

A device that outputs electromagnetic radiation within a first band of wavelengths when excited by electromagnetic radiation having wavelengths within a second band of wavelengths, the device comprising: a gain medium comprised of a matrix phase that is substantially transparent at wavelengths of interest, a doped semiconductor nanocrystal electromagnetic radiation emitting and amplifying phase, and an electromagnetic radiation scattering phase, wherein said matrix phase, said electromagnetic radiation emitting and amplifying phase, and said electromagnetic radiation scattering phase are commingled within a volume of said gain medium.

Claim 15

Independent Claim 86 words

A device that outputs electromagnetic radiation within a first band of wavelengths when excited by electromagnetic radiation having wavelengths within a second band of wavelengths, the device comprising: a gain medium comprised of a matrix phase that is substantially transparent at wavelengths of interest, a doped semiconductor nanocrystal electromagnetic radiation emitting and amplifying phase, and an electromagnetic radiation scattering phase, wherein said matrix phase, said electromagnetic radiation emitting and amplifying phase, and said electromagnetic radiation scattering phase are commingled within a volume of said gain medium.

Claim 16

Dependent Claim 34 words

A device as set forth in claim 13, wherein at least one dimension of said gain medium is less than or on the order of a scattering length associated with the radiation scattering phase.

Claim 17

Dependent Claim 31 words

A device as set forth in claim 13 wherein said doped semiconductor nanocrystal electromagnetic radiation emitting and amplifying phase is comprised of semiconductor particles that are doped with a luminescent center.

Claim 18

Dependent Claim 31 words

A device as set forth in claim 13 wherein said doped semiconductor nanocrystal electromagnetic radiation emitting and amplifying phase is comprised of ZnS particles that are doped with Mn 2+ .

Claim 19

Dependent Claim 21 words

A device as set forth in claim 13 wherein said electromagnetic radiation scattering phase is comprised of particles of an oxide.

Claim 20

Dependent Claim 34 words

A device as set forth in claim 17 wherein said electromagnetic radiation scattering phase is comprised of an oxide selected from the group consisting essentially of TiO 2 and Al 2 O 3 .

Claim 21

Dependent Claim 23 words

A device as set forth in claim 13 wherein said electromagnetic radiation scattering phase is comprised of scattering centers within said matrix phase.

Claim 22

Dependent Claim 29 words

A device as set forth in claim 13 wherein said matrix phase is comprised of a material selected from the group consisting essentially of a glass and a polymer.

Claim 23

Dependent Claim 31 words

A device as set forth in claim 13, wherein said gain medium is embodied as one of: a monolithic structure, a coating, a layer, and a region within a host structure.

Claim 24

Independent Claim 103 words

A method of broadening and shifting a band of emission wavelengths from a plurality of doped semiconductor nanocrystals, comprising the steps of: providing a sample comprised of a plurality of the doped semiconductor nanocrystals in combination with (a) a plurality of scattering particles or sites and (b) a medium that is substantially transparent to the band of emission wavelengths; irradiating the sample with electromagnetic radiation having wavelengths suitable for generating an emission from the doped semiconductor nanocrystals; and broadening and shifting a band of emission wavelengths from the plurality of doped semiconductor nanocrystals by scattering the emission with the scattering particles or sites.

Claim 25

Independent Claim 103 words

A method of broadening and shifting a band of emission wavelengths from a plurality of doped semiconductor nanocrystals, comprising the steps of: providing a sample comprised of a plurality of the doped semiconductor nanocrystals in combination with (a) a plurality of scattering particles or sites and (b) a medium that is substantially transparent to the band of emission wavelengths; irradiating the sample with electromagnetic radiation having wavelengths suitable for generating an emission from the doped semiconductor nanocrystals; and broadening and shifting a band of emission wavelengths from the plurality of doped semiconductor nanocrystals by scattering the emission with the scattering particles or sites.

Claim 26

Dependent Claim 37 words

A method as set forth in claim 22, wherein at least one dimension of said sample is provided to be less than or on the order of a scattering length associated with the scattering particles or sites.

Claim 27

Dependent Claim 23 words

A method as set forth in claim 22, wherein the sample is comprised of semiconductor nanocrystals that are doped with a luminescent center.

Claim 28

Dependent Claim 30 words

A method as set forth in claim 22, wherein the sample is provided with doped semiconductor nanocrystals that are comprised of ZnS nanocrystals that are doped with Mn 2+ .

Claim 29

Independent Claim 84 words

A method for generating electromagnetic radiation, comprising the steps of: providing a sample comprised of a plurality of semiconductor nanocrystals that are doped with a selected dopant; irradiating the sample with electromagnetic radiation having energy suitable for raising electrons from a valence band to a conduction band of the doped semiconductor nanocrystals; and using the electromagnetic radiation to induce a Tyndall Resonance condition within at least some of the doped semiconductor nanocrystals such that a radiative decay rate of the selected dopant is increased.

Claim 30

Independent Claim 84 words

A method for generating electromagnetic radiation, comprising the steps of: providing a sample comprised of a plurality of semiconductor nanocrystals that are doped with a selected dopant; irradiating the sample with electromagnetic radiation having energy suitable for raising electrons from a valence band to a conduction band of the doped semiconductor nanocrystals; and using the electromagnetic radiation to induce a Tyndall Resonance condition within at least some of the doped semiconductor nanocrystals such that a radiative decay rate of the selected dopant is increased.

Claim 31

Dependent Claim 40 words

A method as set forth in claim 26, wherein the sample is also provided to have a plurality of scattering particles or sites and a medium that is substantially transparent to a band of emission wavelengths from the selected dopant.

Claim 32

Dependent Claim 37 words

A method as set forth in claim 27, wherein at least one dimension of said sample is provided to be less than or on the order of a scattering length associated with the scattering particles or sites.

Claim 33

Dependent Claim 81 words

A method as set forth in claim 26 wherein the semiconductor nanocrystals are provided to have a number of atoms of a selected dopant species that insures that a number of electrons in the conduction band is sufficient to form a plasma having an associated frequency ω plasma , divided by the square root of 3, that is approximately equal to a frequency ω dopant that is associated with the radiative decay emission from the atoms of the selected dopant species.

Claim 34

Dependent Claim 21 words

A method as set forth in claim 26 wherein the semiconductor nanocrystals are provided so as to have a passivated surface.

Claim 35

Dependent Claim 36 words

A method as set forth in claim 26 wherein the semiconductor nanocrystals are provided to have a diameter that is much less than a dimension of wavelengths associated with the electromagnetic radiation that irradiates the sample.

Claim 36

Dependent Claim 19 words

A method as set forth in claim 26 wherein the dopant is comprised of one or more isoelectronic atoms.

Claim 37

Dependent Claim 23 words

A method as set forth in claim 26, wherein the sample is comprised of semiconductor nanocrystals that are doped with a luminescent center.

Claim 38

Dependent Claim 25 words

A method as set forth in claim 26, wherein the sample is comprised of comprised of ZnS nanocrystals that are doped with Mn 2+ .

Claim 39

Dependent Claim 85 words

A display device, comprising: a substrate; and a plurality of display pixels formed upon or within a surface of said substrate, each of said display pixels comprising a gain medium comprised of a matrix phase that is substantially transparent at wavelengths of interest, a doped semiconductor nanocrystal electromagnetic radiation emitting and amplifying phase, and an electromagnetic radiation scattering phase, wherein said matrix phase, said electromagnetic radiation emitting and amplifying phase, and said electromagnetic radiation scattering phase are commingled within a volume of said gain medium.

Claim 40

Dependent Claim 85 words

A display device, comprising: a substrate; and a plurality of display pixels formed upon or within a surface of said substrate, each of said display pixels comprising a gain medium comprised of a matrix phase that is substantially transparent at wavelengths of interest, a doped semiconductor nanocrystal electromagnetic radiation emitting and amplifying phase, and an electromagnetic radiation scattering phase, wherein said matrix phase, said electromagnetic radiation emitting and amplifying phase, and said electromagnetic radiation scattering phase are commingled within a volume of said gain medium.

Claim 41

Dependent Claim 36 words

A display device as set forth in claim 35, wherein at least one dimension of each of said pixels is less than or on the order of a scattering length associated with the radiation scattering phase.

Claim 42

Dependent Claim 32 words

A display device as set forth in claim 35, wherein said doped semiconductor nanocrystal electromagnetic radiation emitting and amplifying phase is comprised of semiconductor particles that are doped with a luminescent center.

Claim 43

Dependent Claim 32 words

A display device as set forth in claim 35, wherein said doped semiconductor nanocrystal electromagnetic radiation emitting and amplifying phase is comprised of ZnS particles that are doped with Mn 2+ .

Claim 44

Dependent Claim 22 words

A display device as set forth in claim 35, wherein said electromagnetic radiation scattering phase is comprised of particles of an oxide.

Claim 45

Dependent Claim 27 words

A display device as set forth in claim 35, and further comprising means for irradiating said plurality of pixels with an optical beam or an electron beam.

Claim 46

Dependent Claim 107 words

An optical emitter comprising: a substrate; and a first thin film disposed over a surface of said substrate; wherein said first thin film is comprised of a first optical gain medium comprised of a first optical emitter in combination with a plurality of scattering centers for emitting, in response to excitation by a pulse of electromagnetic radiation having a first range of wavelengths centered about a first wavelength, a first temporally and spectrally collapsed pulse of electromagnetic radiation having a second range of wavelengths centered about a second wavelength, wherein said first optical emitter is comprised of first semiconductor particles that are doped with a luminescent center.

Claim 47

Dependent Claim 107 words

An optical emitter comprising: a substrate; and a first thin film disposed over a surface of said substrate; wherein said first thin film is comprised of a first optical gain medium comprised of a first optical emitter in combination with a plurality of scattering centers for emitting, in response to excitation by a pulse of electromagnetic radiation having a first range of wavelengths centered about a first wavelength, a first temporally and spectrally collapsed pulse of electromagnetic radiation having a second range of wavelengths centered about a second wavelength, wherein said first optical emitter is comprised of first semiconductor particles that are doped with a luminescent center.

Claim 48

Dependent Claim 123 words

An optical emitter as set forth in claim 41 and further comprising: a second thin film disposed over said surface of said substrate; wherein said second thin film is comprised of a second optical gain medium comprised of a second optical emitter in combination with a plurality of scattering centers for emitting, in response to excitation by said pulse of electromagnetic radiation having said first range of wavelengths centered about said first wavelength, a second temporally and spectrally collapsed pulse of electromagnetic radiation having a third range of wavelengths centered about a third wavelength, wherein said second wavelength is different than said third wavelength, and wherein said second optical emitter is comprised of second semiconductor particles that are doped with a luminescent center.

Claim 49

Dependent Claim 23 words

An optical emitter as set forth in claim 42, wherein surfaces of said first semiconductor particles and said second semiconductor particles are passivated.

Claim 50

Dependent Claim 49 words

An optical emitter as set forth in claim 42, and further comprising a first reflective region that is interposed between said first thin film and said surface of said substrate; and a second reflective region that is interposed between said second thin film and said surface of said substrate.

Annuity Stage	Window Opens	Payment Deadline	Surcharge Period Until	Estimated Fee	Status
3.5 Years (Year 4)	1998-07-17	1999-01-16	1999-07-18	$2000.00	Window Closed / Lapsed
7.5 Years (Year 8)	2002-07-17	2003-01-16	2003-07-18	$3760.00	Window Closed / Lapsed
11.5 Years (Year 12)	2006-07-17	2007-01-16	2007-07-18	$7700.00	Window Closed / Lapsed

Optical gain medium having doped nanocrystals of semiconductors and also optical scatterers

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