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Process for the preparation of 1-olefin polymers

Assignee: Targor GmbH
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Filing: 1991-08-22
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Granted: 1995-05-16
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Expires: 2011-08-22
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Abstract

Abstract In the case of Ziegler catalysts based on a metallocene as the transition metal component and an aluminoxane as the activator, preactivation of the metallocene with the aluminoxane results in a considerable increase in the activity of the catalyst system. Furthermore, 1-olefin polymers of a high degree of isotacticity and having compact, spherical particles, a very narrow particle size distribution and a high bulk density are obtained by means of a catalyst system of this type.

Inventors

  • 👤 Andreas Winter
  • 👤 Walter Spaleck

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-29 17:35
CPC Classifications
C; C08; C08F; C08F110/00; C08F110/04; C08F110/06; C07; C07F; C07F17/00; C08F10/00; C08F10/04; C08F10/06; C08F4/00; C08F4/42; C08F4/44; C08F4/60; C08F4/619; C08F4/6192; C08F4/61922; C08F4/61927; C08F4/62; C08F4/639; C08F4/63912; C08F4/6392; C08F4/63922; C08F4/63927; C08F4/64; C08F4/659; C08F4/65912; C08F4/6592; C08F4/65922; C08F4/65927; Y; Y10; Y10S; Y10S526/00; Y10S526/902; Y10S526/943

Claims Analysis

Total Claims: 8
Claim 1
Independent Claim 210 words
In a process for the preparation of a 1-olefin polymer by polymerizing a 1-olefin of the formula R--CH═CH 2 in which R is an alkyl group having 1 to 28 carbon atoms or copolymerizing these olefins together with ethylene at a temperature from -60° to 200° C., under a pressure of 0.5 to 60 bar, in solution, in suspension or in the gas phase and in the presence of a catalyst consisting essentially of a transition metal component containing metallocene and an aluminoxane of formulae IV or V as second component wherein the transition metal component has been preactivated in aluminoxane of the formula IV ##STR15## for the linear type and/or of the formula V ##STR16## for the cyclic type, R 17 in the formulae IV and V being a C 1 -C 6 -alkyl group and p being an integer from 2 to 50, the process comprising a) dissolving the metallocene in a solution of aluminoxane in an inert hydrocarbon to form a preactivation solution; b) allowing the preactivation solution to stand for 5 minutes to 100 hours at a temperature of -78° C. to 100° C.; and c) stirring the alminoxane together with the liquid phase in the polymerization before the metallocene is added to the polymerization system.
Claim 2
Dependent Claim 210 words
In a process for the preparation of a 1-olefin polymer by polymerizing a 1-olefin of the formula R--CH═CH 2 in which R is an alkyl group having 1 to 28 carbon atoms or copolymerizing these olefins together with ethylene at a temperature from -60° to 200° C., under a pressure of 0.5 to 60 bar, in solution, in suspension or in the gas phase and in the presence of a catalyst consisting essentially of a transition metal component containing metallocene and an aluminoxane of formulae IV or V as second component wherein the transition metal component has been preactivated in aluminoxane of the formula IV ##STR15## for the linear type and/or of the formula V ##STR16## for the cyclic type, R 17 in the formulae IV and V being a C 1 -C 6 -alkyl group and p being an integer from 2 to 50, the process comprising a) dissolving the metallocene in a solution of aluminoxane in an inert hydrocarbon to form a preactivation solution; b) allowing the preactivation solution to stand for 5 minutes to 100 hours at a temperature of -78° C. to 100° C.; and c) stirring the alminoxane together with the liquid phase in the polymerization before the metallocene is added to the polymerization system.
Claim 3
Dependent Claim 23 words
The process as claimed in claim 1, wherein a stereo-rigid, chiral metallocene is used for the preparation of a highly isotactic 1-olefin polymer.
Claim 4
Dependent Claim 122 words
The process as claimed in claim 1, wherein the metallocene has the formula (II) ##STR17## wherein Me 1 is a metal of group IVb or Vb of the periodic table; R 7 and R 8 are identical or different and denote a halogen atom, C 1 -C 10 -alkyl, C 6 -C 10 -aryl, C 2 -C 10 -alkenyl, C 7 -C 40 -arylalkyl, or C 7 -C 40 -alkylaryl or C 8 -C 40 -alkenylaryl; and R 9 and R 10 are identical or different and denote a substituted cyclopentadienyl radical, said radical containing one or more centers of chirality and having been formed by the reaction of an alkali metal cyclopentadienide with a sulfonic acid ester of a chiral alcohol.
Claim 5
Dependent Claim 14 words
The process as claimed in claim 3, wherein Me 1 is titanium or zirconium.
Claim 6
Dependent Claim 18 words
The process as claimed in claim 3, wherein R 7 and R 8 each denote a chlorine atom.
Claim 7
Dependent Claim 17 words
The process as claimed in claim 1, wherein polymerization is carried out in solution or in suspension.
Claim 8
Dependent Claim 22 words
The process as claimed in claim 1, wherein polymerization is carried out in suspension of the 1-olefin or the 1-olefin and ethylene.

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1998-05-15 1998-11-14 1999-05-16 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 2002-05-15 2002-11-14 2003-05-16 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2006-05-15 2006-11-14 2007-05-16 $7700.00 Window Closed / Lapsed

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